Sharif Digital Repository

The adhesion and mechanical properties of hydrogels used for vascular wound repair often deteriorate dramatically on wet surfaces, resulting in ineffective repair. In this work, a poly(N-isopropyl acrylamide-co-dopamine methacrylamide) nanogel with dopamine groups was synthesized and introduced into a polyacrylamide (PAAm) hydrogel to produce temperature-responsive hydrogels, which greatly improved mechanical and adhesive properties of PAAm hydrogels. Nanogel-reinforced PAAm (NR-PAAm hydrogel) can adhere to the surface of various solid materials and biological tissues through special physical interactions, which exhibited different mechanical and adhesion properties as temperature changes... 

Cu-based chalcogenide p-type semiconductors in the form of nanocrystals can be used to deposit low-temperature and stable hole-transport layers (HTL) for n-i-p perovskite solar cells (PSCs). In this study, the synthesis parameters are modified to improve the hole-extraction of CuIn0.75Ga0.25S2 (CIGS) layer. By optimizing the amount of oleylamine as the capping agent, the internal series resistance of PSCs decreases significantly while preventing aggregation of CIGS nanocrystals. Increasing the growth temperature from 220 °C to 275 °C leads to an increase in the size of CIGS nanocrystals. This results in an improvement in the open-circuit voltage of PSCs with... 

Accurate customer baseline load (CBL) estimation is critical for implementing incentive-based demand response (DR) programs. The increasing penetration of grid-tied distributed photovoltaic systems (DPVS) complicates customers’ load patterns, making the CBL estimation more difficult because the volatile actual load and the intermittent PV output power are coupled together. A PV-load decoupling framework is proposed in this paper to address the above issue. The basic idea is to decouple the actual load power and the PV output power, then estimate them separately. To this end, historical PV output power data of each individual DPVS is required. However, pure historical PV output power data is... 

In this paper, a multistage expansion planning model is proposed to address the joint expansion of distributed energy resources (DERs) as well as the distribution network assets taking into account the role of stakeholders and the uncertainty associated with their investment budgets. In this regard, the aims and techno-economic constraints of the distribution system operator (DSO) and distributed generator owners (DGOs) are modeled in the planning of a restructured active power distribution network. Furthermore, the uncertainty associated with the agents' investment budget is addressed through a stochastic model. Using linearization techniques, the resulting stochastic mixed integer linear... 

To study the mechanism of tsunami wave forces on round-ended piers and the force calculation method, a series of round-ended piers with different ratios of length to width (L/D, D is the diameter of the semicircle at both ends, L is the rectangular length between two end semicircles) are taken as the research object of this study. Firstly, a series of tsunami waves are experimentally generated over dry-bed and wet-beds with different water depths in a dam-break flume. Secondly, the pressure time histories on the outer sides of the round-ended piers are presented and explored. After that, the characteristics of the resultant force and moment at the pier bottom, the maximum force and moment as... 

Abstract We report the well-controlled preparation of WS2 nanosheets-CdS nanoparticle heterojunction for photoelectrochemical (PEC) water splitting application. The WS2 nanosheets with an average thickness of ~5 nm and lateral dimensions of ~200 nm were synthesized via liquid phase exfoliation of bulk WS2 in water/ethanol solution, followed by deposition onto ITO substrate via electrophoretic method. CdS nanoparticles were grown via facile successive ion layer absorption and reaction (SILAR) method. Using these two well-controlled methods, CdS/WS2/ITO and WS2/CdS/ITO systems were fabricated. The loading of WS2 nanosheets was... 

Traditional fluorescence switching molecules achieving the state change between on and off states commonly based on UV irradiation. However, it is worth noting that UV irradiation is harmful to both the cancer cells and the normal cells. To achieve fluorescence switching under visible wavelength and avoid complicate molecular design, a fluorophore of 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene (4CzIPN) and a quencher of diarylethene (DAE) were physically incorporated within the biocompatible block copolymer poly(lactic-co-glycolic acid)-b-poly(ethylene glycol) (PLGA-b-PEG) to form 4CzIPN-DAE nanoparticles (NPs) through flash nanoprecipitation (FNP). By using the FNP method, the NPs... 

Stimuli-responsive drug delivery carriers, particularly those exhibiting pH sensitivity, have attracted significant scholarly interest due to their promising potential in anticancer therapeutic applications. This phenomenon can primarily be ascribed to the inherently acidic nature of tumor microenvironments. However, pH-responsive carriers frequently require the incorporation of functional groups or materials sensitive to pH changes. Given the pH-sensitive characteristics of metal coordination with natural small-molecule drugs, organometallic supramolecules present a facile and effective strategy for integrating pH-responsive behavior into these systems. Meanwhile, utilizing the natural... 

Degenerative disc disease is one of the most common causes of low back pain instigating huge socioeconomic costs and posing an immense burden on healthcare systems worldwide. New therapeutic approaches to damaged intervertebral discs are therefore of great interest. Platelet-Rich Plasma (PRP) has been proposed for the repair and regeneration of degenerated discs, but there remains a knowledge gap regarding its effectiveness and influence on disc material properties. The objective of this study was to investigate and quantify the material properties of intact, denatured, and PRP treated discs. A systematic methodology was established in the process, where ex-vivo experiments were conducted... 

Rare earth oxides with a trivalent nature play a pivotal role in reinforcing the magneto-optical attributes of spinel ferrite nanoparticles by replacing Fe3+ ions. In this study, rare earth Gd oxide doped with CoFe2O4 NPs with a composition of Co1+xGdxFe2-2xO4 (x = 0, 0.05, 0.10, and 0.15) were synthesized using sol-gel auto-combustion. The outcome of Gd cations on the physical, magneto-optical and electrical characteristics of the cobalt ferrite NPs were reported. X-ray diffraction (XRD), and Fourier transform infrared (FTIR) investigations confirmed the single-phase cubic crystalline nature and metal ion stretching in the cobalt ferrite synthesized samples. Decreasing drift in the average... 

Rare earth oxides with a trivalent nature play a pivotal role in reinforcing the magneto-optical attributes of spinel ferrite nanoparticles by replacing Fe3+ ions. In this study, rare earth Gd oxide doped with CoFe2O4 NPs with a composition of Co1+xGdxFe2-2xO4 (x = 0, 0.05, 0.10, and 0.15) were synthesized using sol-gel auto-combustion. The outcome of Gd cations on the physical, magneto-optical and electrical characteristics of the cobalt ferrite NPs were reported. X-ray diffraction (XRD), and Fourier transform infrared (FTIR) investigations confirmed the single-phase cubic crystalline nature and metal ion stretching in the cobalt ferrite synthesized samples. Decreasing drift in the average... 

We report a simple synthetic approach to grow uniform CH3NH3PbI3 perovskite (PSK) layers free of pinholes via varied portions of silver iodide (AgI) added to the precursor solution. XRD/EDS elemental mapping experiments demonstrated nearly uniform Ag distribution inside the perovskite film. When the 1% AgI-assisted perovskite films were fabricated into a p-i-n planar device, the photovoltaic performance was enhanced by ∼30% (PCE increased from 9.5% to 12.0%) relative to the standard cell without added AgI. Measurement of electronic properties using a hall setup indicated that perovskite films show p-type character after Ag doping, whereas the film is n-type without Ag. Transients of... 

The effect of moisture on Shengli lignite breakage behavior and energy efficiency was studied experimentally using a standard Hardgrove mill fitted with a wattmeter. The grinding process concerned both the inputs, namely the occurrence and content of water and instantaneous energy consumption and the outputs, size-reduction and product fineness. Results show that the energy-size reduction process for grinding lignite is markedly influenced by moisture occurrence and content. Removing surface moisture from 37.90% to 16.61% (the air-dried condition) resulted in a slight increase of input energy by 0.04 kWh.t−1 per 10 s. However, with further drying inherent moisture to 0%, the consumed energy... 

Although the physiochemical merits of g-C3N4-based photocatalysts have garnered increasing interest in the fields of energy and environmental science, insufficient layer detachment has created a gap between fundamental research and practical applications. To unlock the intrinsic potential of g-C3N4, a bio-transformation of the ZnMn2O4 ((6)ZM) gel was employed to introduce highly-ordered modulation caused by steric hindrance during melamine pyrolysis. Phytomediated (6)ZM reorganized traditional carbon nitride into crossed C3N4 (CCN) monolayers, simultaneously engineering an auspicious Z-schematic system ((6)ZM/CCN). Phytoconverted (6)ZM retained the crystalline-amorphous configuration for... 

Recent advances in biomaterials, microfabrication, microfluidics, and cell biology have led to the development of organ-on-a-chip devices that can reproduce key functions of various organs. Such platforms promise to provide novel insights into various physiological events, including mechanisms of disease, and evaluate the effects of external interventions, such as drug administration. The neuroscience field is expected to benefit greatly from these innovative tools. Conventional ex vivo studies of the nervous system have been limited by the inability of cell culture to adequately mimic in vivo physiology. While animal models can be used, their relevance to human physiology is uncertain and... 

The earned value management (EVM) model is an essential technique for managing and forecasting project features such as scheduling and cost performances indexes. This paper presents a novel fuzzy earned-value model based on Z-number theory incorporating both the impreciseness of real life conditions and a degree of reliability through considering an expert judgment process. The latter factor has not been used by other researchers in the field. The proposed model provides a reliable assessment for the progress performance of a project and its 'at completion' cost in an uncertain environment. Finally, an illustrative case demonstrates the applicability of the proposed model in real life... 

This study proposes a multi-objective control algorithm for simultaneous process and quality control in non-Gaussian stochastic batch processes. The objective is to control a non-Gaussian process so that each batch is delivered within a pre-specified time. During each batch, the process is controlled by a fixed-parameter PI controller. Between any two adjacent batches the controller parameters are updated by a differential evolution algorithm so that the integral squared of tracking error, entropy of tracking error, integral of absolute processing time error and entropy of processing time error are minimised. the proposed algorithm is applied to a batch continuously stirred tank reactor... 

The aeroelastic flutter characteristics of a functionally graded carbon nanotube reinforced composite (FG-CNTRC) truncated conical shell under simultaneous actions of a hydrostatic pressure and yawed supersonic airflow are scrutinized. The nonlinearity in geometry of the conical shell is considered in Green–Lagrange sense and the model is derived according to the Novozhilov nonlinear shell theory. The aerodynamic pressure is modeled based on the quasi-steady Krumhaar's modified supersonic piston theory by considering the effect of the panel curvature and flow yaw angle. Parametric studies are conducted to investigate the effects of boundary conditions, semi-vertex angle, distribution and... 

The present research deals with bifurcation and vibration responses of a composite truncated conical shell with embedded single-walled carbon nanotubes (SWCNTs) subjected to an external pressure and axial compression simultaneously. The distribution of reinforcements through the thickness of the shell is assumed to be either uniform or functionally graded. The equations of motion are established using Green-Lagrange type nonlinear kinematics within the framework of Novozhilov nonlinear shell theory. Linear membrane prebuckling analysis is conducted to extract the prebuckling deformations. The stability equations are derived by applying the adjacent equilibrium criterion to the prebuckling... 

The Stochastic Distribution Control (SDC) problem is a generalised form of the minimum variance control problem where non-Gaussian noise distributions are encountered. The problem has been previously solved using two alternative approaches. When it is assumed that the output Probability Distribution Function (PDF) is measurable, then a parameterized controller is obtained. If on the other hand this assumption is removed (which corresponds to most practical cases), then the controller found is no longer parameterisable (i.e. it is a control action sequence). Both these approaches have thus far been solved using local Newtonian methods. In this paper a third alternative is presented which...