Sharif Digital Repository

In the current research, colloidal stability of two different types of coating on the surface of Superparamagnetic Iron Oxide nanoparticles (SPIONs) was studied. In the first triumph, a dual-layer coating was achieved by utilizing optimum amount of Dextran and different PEG (Poly(ethylene glycol)) concentrations which the weight ratios of iron oxide/PEG were 1/1, 2/1, 4/1, 8/1, and 16/1. Then, the presence of the coating was characterized by XRD, FT-IR, DLS and FE-SEM methods. These results together with the TGA ones revealed that as the concentration of PEG surfactant increases, the thickness of coating increases. Moreover, VSM test was performed to specify the effect of coating on the... 

Selective laser sintering is a technique which uses a laser as the power source to sintering some selected points at a bed of powder in order to create a solid structure. In this research the SLS mechanisms of powder deposition is simulated and surface smoothness and layer density created by each mechanism is computed. For this purpose roller, blade and hopper mechanisms are simulated. For this simulation, polyamide 12 (PA2200) which is a common material is used. In this simulation at first powder specifications are extracted according to the references and for particle shape instead of using the spherical particle shape we use a certain shape that is more close to reality which created by... 

This study was conducted to investigate a theoretical and experimental two-dimensional model of a floating fish cage in regular waves and uniform current. Due to the inefficiency of computational fluid dynamics (CFD) in solving such problems, developing a simple model to predict the results is highly advantageous. In this study, a simple mass-spring model was developed to simulate the problem. After validating the results of this simple model through a series of model tests in a wave tank, it was further utilized to extract additional results. Experiments were conducted at six different wave heights and four current velocities. In all experiments, wave steepness was maintained at a ratio of... 

Global energy consumption is on a trajectory to surge by 50% by 2050, primarily driven by prevailing energy consumption patterns. Consequently, the imperative to innovate and develop novel energy sources, such as the utilization of recycled waste heat, has become paramount for the foreseeable future. In light of this, this paper delves into the transformative potential of employing Phase Change Materials (PCMs) for cooling Thermoelectric Generators (TEGs) and harnessing waste heat for productive purposes. The research investigates three distinct configurations to evaluate the efficacy of PCMs in enhancing thermal management. Configuration 1 exclusively relies on an active cooling fan, while... 

Mechanical behavior of tissue engineering scaffolds plays a key role in their biological performance; however the effect of microstructural features on mechanical behavior of such scaffolds is still under investigation. The objective of this study was to investigate the influence of pore architecture and relative density on mechanical behavior of rapid prototyped scaffolds. In this regard, scaffolds with different cubic, hexagonal and trigonal unit cells were designed. These unit cells were repeated in different arrangements in 3D space to produce different nodal connectivities. The internal dimension of pores varied from 500 to 600 μm. Plastic models of scaffolds then fabricated by 3D... 

Today, the importance of scientific collaborations is due to the fact that researchers who jointly publish an article, research connections are formed between them, and as a result, professional learning is obtained. Each of these researchers brings a feature and advantage to the research team, such as mastering a particular topic and its subdivisions, team thinking, and division of labor between them. The importance of these collaborations is doubled when researchers collaborate with each other at the international level, because the networking of researchers through collaboration with colleagues from different countries, especially central and developed countries in science, in addition to... 

Considering the widespread applications of amides, synthesis of these compounds is of great importance. The one pot oxidative addition of amines to aldehydes is one of the most simple and appealing approaches to synthesis amides. With the aim of developing a mild and convenient approach towards preparation of amides, numerous methods have been reported for this important process over the past few decades. These improvements have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including diverse derivatives of aldehydes, and also design a novel and effective catalytic systems. Due to the various advantages of supported heterogeneous... 

In recent years, the widespread investigation on multi-transition metal oxides that with two or more transition metal oxides, have been increased rapidly for electrochemical application due to low cost, high conductivity and good electrochemical performance other than single metal oxides. In this project, CuCo2O4 nanoparticles were firstly fabricated by decomposing of CuCo-MOF as the template. The as prepared samples were used to synthesis a new nanocomposite of MoS2 and CuCo2O4. The best ratio of the two component were optimized to prepare the best electrocatalyst for Hydrogen evolution reaction (HER). The structure of prepared nanocomposite were investigated by various techniques such as... 

The integrative supply chain management is one of the main business processes between final consumer and supplier and it is formed by responsibilities such as production, services and information those have added value for customers and beneficiaries. Therefore and as the goal of a chain is maximization of gained value for the factors involved in chain, so, this goal can be more accessible by decreasing transportation (transportation method, tracking, …) and stock costs (conservation, ordering, …). As its purpose, this thesis intends to introduce and increase the options of goods transportation possibilities between retailers’ warehouses and evaluation of its effect on transportation and... 

Perovskite solar cells are the new generation of solar cells, and are mainly introduced in two types of structures.1) planer and 2) mesoscopic structure. The difference between these two structures derives from the absence of mesoporous layer in the planer structures. The mesoporous layer acts as an electron transporting layer, and is mainly a titanium dioxide semiconductor. To apply the mesoporous layer, the preparation of the TiO2 paste is needed.The synthesis of titanium dioxide nanopowder for the preparation of TiO2 paste requires high temperature heat treatment and is not desirable in terms of energy consumption.Another weakness of this layer is the presence of surface defects, which... 

In this thesis, a coarse-grained multi-scale method for 2D crystallyn solids based-on finite element consepts has presented. In this method, both scales are atomic scale and similar to what we see in non-local QC method, the entire atomic structure will be intact. Accordingly, calculations of potential functions and forces in the domain will have the atomic accuracy. In the presented method to reduce the domain’s degrees of freedom, the classical finite-element meshing concept to mesh the elastic linear areas in the domain is used and the MD calculations will done on the mesh nodes. Therefore, degrees of freedom in the system will reduce and consequently, the computational cost will reduce.... 

Peak Floor Acceleration (PFA) is a necessary requirement in Industrial Buildings for the design of equipment, piping, cable tray and ventilation duct supports. The seismic analysis of equipments needs the determination of PFA at the points where the equipments are fixed on the supporting structure. The classical spectral methods (SRSS, CQC) do not allow this determination which can be done in using the time integration method. This last approach needs to perform numerous calculations with various realizations of the seismic excitation. This thesis aims to present a method allowing calculating the response properties of a linear elastic shear building structure loaded by a transient... 

Dye-sensitized solar cells (DSSCs) are Photoelectrochemical cells using wide band gap nanoporous oxide semiconductors sensitized by dye molecules. For achieving high efficiency DSSCs preparation of photoanode electrode with high surface aea which leads to adequate dye absorption is necessary. In order to achieve proper morphology, thickness, particles size and porosity, producing a TiO2 nano-structured paste is required. TiO2 powder was prepared using sol-gel method. following a calcination process at 300 degrees, XRD patterns showed presence of anatase and brookite structures with average crystallite size of 9 nm. Additives such as diethylene glycol, acetylacetone and Triton X-100 were used... 

With development of nanotechnology in medicine, nanoparticles are used for detection of tumor and cancer biomarkers. Magnetic nanoparticles are widely used for therapeutic and diagnostic objectives, because of their biocompatibility, ease of preparation and strong magnetic properties. Genistein (C15H10O5) is a soy isoflavone which is used for its anti-cancer activities. It is used for inhibition of cell proliferation, cell growth, and tumor invasion. The aim of this study is to assess the impact of nano-conjugation of geinstein as chemotherapeutic agent against cancer. For preparation of typical iron oxide Nanoparticles, Magnetite nanoparticles were synthesized by coprecipitating iron (II)... 

The Mesoporous Titanium Dioxide film using Sol-Gel method and Evaporation-Induced Self-Assembly technique (EISA) was prepared. In this study, in order to employ the best coatings in anode electrode of dye-sensitized solar cell, different conditions of making this film, the effective parameters in final structure, and various methods of coating were analyzed. After optimizing the conditions of film creating, images of field emission scanning electron microscope (FESEM) proved the formation of a layer of mesoporous structure which thickness after three times of coating is about 1.5 micrometers. In order to increase the energy conversion efficiency of solar cells, a new formulation for... 

In this thesis, pure –known as T- and chromium doped titanium dioxide nanoparticles –known as -CTx- with different dopant atomic ratio (0.1 to 5 %at.) were synthesized using a facile, fast and efficient method. FESEM and XRD studies showed no morphologic and structural change via Cr doping of nanoparticles (size in the range of 20-30 nm). However, according to DRS analysis, Cr intrusion in TiO2 crystal structure, drastically reduced band gap energy of pure TiO2 from 3.14 eV to 1.81 eV for CT3 powder and improved absorption range of UV-Vis spectrum. Mott-Schottky plots indicated that, Cr doping, caused reduction in donor density of TiO2 and an upward shift in the conduction band edge.... 

Structure and morphology of titanium dioxide have an excessive effect on the photovoltaic properties of dye-sensitized solar cells (DSCs). Different approaches have been used to improve the efficiency of these cells. One is using a scattering layer. Studies have been shown that properties of scattering layer such as composition and morphology have great effect on photovoltaic properties of solar cell. In this project, the effect of cubic morphology of TiO2 as a scattering agent in photoanode of DSCs is studied. Titanium dioxide with various morphologies including nanoparticles, solid and hollow cubic structures have been synthesized by solvothermal and hydrothermal methods, respectively. The... 

In present work, hydroxyapatite nano-rods are synthesized using a simple sol-gel method with calcium nitrate and potassium dihydrogenphosphate as calcium and phosphorus precursors respectively and ammonia was used for adjusting the pH=9. To obtain rod shape hydroxyapaite powder, multi wall carbon nanotubes were added to the solution, nHA powder was calcinated at 60 and 450 ℃. In second step, chitosan-gelatin/nanoHA solution were prepared by blending chitosan and gelatin in different concentrations with nanoHA powder, then the solution was freeze dried to maintain a composite scaffold. The prepared HA powder and bio-composite scaffold were characterized by X-ray diffraction (XRD), field... 

Dye-sensitized solar cell (DSSCS) is the third-generation of solar cells based on semiconductors formed between a photo sensitized anode and counter cathode which make a photo electrochemical system. They haven’t been commercially marketed due to their lower efficiency than the previous generations. In order to achieve the higher efficiency, the electron injection and light absorption must be increased. One way to increase electron injection is doping the semiconductor with an external ion to reduce lattice band gap. In this work, we made powder and Nano-structured film of titanium dioxide doped with various molar ratios of Mg by the sol-gel process. The effect of Mg:Ti molar ratio on... 

In this study, application of a Magnetic Nanofluid consisting of Magnetite as Nanoparticle and Water as base fluid in DASC systems is investigated. The DASC system is modeled theoretically and behavior of such system is predicted.In this study a comparison between magnetite Nanofluid and some other common Nanofluids is conducted. The study shows that Magnetite Nanofluid has a better performance and efficiency than Water, Al2O3 Nanofluid and SiO2 Nanofluid. Also magnetite Nanofluid and TiO2 Nanofluid function are almost similar.Also effect of external magnetic field on the performance of magnetite Nanofluid is investigated. It is showed that when the magnetic Nanofluid is subjected to an...