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A developed novel Hal′@MIL-PMA triple composite utilized as a robust photocatalyst for activated removal of antibiotic contaminants: A new chemical mechanism for Tetracycline degradation

Mohammadi, A ; Sharif University of Technology | 2024

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  1. Type of Document: Article
  2. DOI: 10.1016/j.jece.2024.112941
  3. Publisher: 2024
  4. Abstract:
  5. In this research, an appreciable Hal′@MIL-PMA photocatalyst was prepared through a hydrothermal approach to photo-oxidize Tetracycline. The as-fabricated composite was diagnosed by multiple catalyst characterization tests, including XRD, FTIR, FESEM, PL, EIS, EDS, TGA, BET, and DRS techniques. Under optimized conditions (i.e.; a 1 g/L dosage of photocatalyst, antibiotic concentration of 40 mg/L, pH = 7 and at ambient temperature), 97.11% of Tetracycline elimination was achieved by the pristine Hal′@MIL-PMA photocatalyst. Kinetics computation revealed that the photo-degradation rate of Tetracycline obeys the pseudo-first-order model. Tests on radical trapping manifested that hydroxyl radical was a predominant oxidating reactive agent during the photocatalysis process. The mechanistic decontamination route of Tetracycline was deduced on the basis of the detected transformation products. The decay rate of TOC (63.23%) displayed that the Tetracycline was transferred to H2O, CO2, and simple degradable substances during the photocatalysis procedure. Additionally, the photocatalytic mechanism of Tetracycline degradation over the Hal′@MIL-PMA heterojunction photocatalyst was presented. The as-fabricated photocatalyst displayed significant oxidation efficiency in degrading multiple antibiotics, such as Rifampicin (90.87%) and Sulfasalazine (95.31%) under the above determined optimized conditions. Besides, the photocatalytic rate of Hal′@MIL-PMA heterostructured composite had no remarkable diminish even after five consecutive cycles. On the whole, this investigation evinces that Hal′@MIL-PMA composite can be regarded as a sustainable and promising photocatalyst for decontaminating non-biodegradable and tenacious substances from aqueous environments. © 2024 Elsevier Ltd
  6. Keywords:
  7. Antibiotics Contaminants ; Halloysite ; Metal-Organic Framework ; Photocatalysis ; Decay (organic) ; Degradation ; Heterojunctions ; Kaolinite ; Organometallics ; Oxidation ; Antibiotic contaminants ; Catalyst characterization ; Characterization tests ; Chemical mechanism ; FTIR ; Metalorganic frameworks (MOFs) ; Optimized conditions ; Phosphomolybdic acid ; XRD ; Antibiotics
  8. Source: Journal of Environmental Chemical Engineering ; Volume 12, Issue 3 , 2024 ; 22133437 (ISSN)
  9. URL: https://www.sciencedirect.com/science/article/abs/pii/S2213343724010716