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Highly regioselective ring opening of epoxides with thiols catalyzed by SbCl3 under solvent-free conditions

Ghazanfari, D ; Sharif University of Technology | 2008

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  1. Type of Document: Article
  2. DOI: 10.1080/10426500802053201
  3. Publisher: 2008
  4. Abstract:
  5. The ring-opening reaction of epoxides with thiols by SbCl3 supported on Kieselguhr under solvent-free conditions, afforded high yields of β-hydroxy sulfides. Nucleophilic attack of the thiols occurs regioselectively at the less hindered side of the epoxides. Copyright © Taylor & Francis Group, LLC
  6. Keywords:
  7. Epoxy compounds ; Aminolysis ; Amino alcohols
  8. Source: Phosphorus, Sulfur and Silicon and the Related Elements ; Volume 183, Issue 12 , 2008 , Pages 3018-3022 ; 10426507 (ISSN)
  9. URL: https://www.tandfonline.com/doi/abs/10.1080/10426500802053201