Sharif Digital Repository

A very efficient and mild procedure for the trimethylsilylation of a wide variety of alcohols, including primary, allylic, benzylic, secondary, hindered secondary, tertiary, and phenols with hexamethyldisilazane on the surface of silica gel dispersed with LiClO4 in room temperature at few minutes in excellent yields under neutral conditions is reported. This procedure also allows the excellent selectivity under LP-SiO2 system for silylation of alcohols in the presence of amine and phenolic hydroxy groups  

Enzymatic decolorization of the monoazo dye, acid orange 7 (AO7) by the fungal peroxidase from Coprinus cinereus NBRC 30628 is a complex system, which is greatly affected by temperature, pH, enzyme activity and the concentrations of H2O2 and dye concentration. The study of these factors and investigating the combined interactions between them by applying one-factor-at-a-time (OFAT) method and two other statistical methods including 2-factorial method and response surface methodology (RSM) were aimed in this work. Through OFAT analysis the optimized conditions were a temperature of 25 °C, pH 9.0 with H2O2 concentration of about 3.9 mM and AO7 concentration of 40 mg/l. A complete... 

Robotic devices are traditionally actuated by hydraulic systems or electric motors. However, in compact robotic systems, new actuator technologies are required. Ionic Polymer-Metal Composites (IPMCs) are attractive electroactivc polymer actuators because of their characteristics of large electrically induced bending, mechanical flexibility, low excitation voltage, low density, and ease of fabrication. A dynamic analytical model of IPMC is developed in this study. An RC model is employed based on time response results of a typical silver deposited IPMC. Results show that the electrical model is a suitable presentation of IPMC actuators. The model is tested with two experimental data of IPMC... 

Coprinus cinereus (NBRC 30628) peroxidase was implemented to eliminate the diazo dye of reactive black 5 (RB5). The optimization was conducted in batch mode using three approaches, i.e., the one-factor-at-a-time (OFAT), factorial design, and response surface methodology (RSM). Based on the results of the OFAT method, the optimum conditions for decolorization of RB5 dye were at a temperature of 30°C, a pH of 9-10, an H2O2 concentration of 3.9 mM, and an RB5 concentration of 40 mg/L. In the first stage of statistical optimization, these factors plus enzyme activity were screened by the 2-factorial design, wherein enzyme activity, temperature, and hydrogen peroxide concentration were... 

Ornamental stone sawability is important in predicting the prime cost of production and planning of the stone quarries and factories. Ornamental stone sawability with two standard methods, wire and circular sawing, is dependent on many parameters including; the stone that be sawn and machine characteristics and saw operating characteristic. The investigation of these parameters and the determination of the optimum working conditions for sawing machines in the stone industry is significant for establishing the most suitable and economic usage of the sawing method in the future. Up to now, various attempts have been made to determine these parameters. In this review paper, the important... 

A new predictive model for evaluating the vibration of a sawing machine was developed using a new rock classification system. The predictors are machine parameters and a rock sawability index. The new rock classification system includes four major parameters of the rock: uniaxial compressive strength, abrasivity index, mean Moh's hardness, and Young's modulus. The FAHP approach was used when determining the weights of these parameters by six decision makers. Two groups of carbonate rocks were sawn using a fully-instrumented laboratory sawing rig at different feed rates and depths of cut. During the sawing trials system vibration was monitored as a measure of saw performance. Then, a new... 

The prediction of production rate in ornamental stones sawing is very important in cost estimation and process planning of the rock sawing plants. The main aim of this paper is finding a mathematical correlation between production rate and rock brittleness indexes. The utilized data have been collected from several stone factories in Iran. Seventeen different granite and carbonate rocks have been experienced sawing conditions with large-diameter circular saws. The laboratory tests such as uniaxial compressive strength and tensile strength, were carried out on the rock samples which were collected from these factories. The ratio of compressive strength to tensile strength (B1), the ratio of... 

The application of sensor system is becoming more commonplace in improving productivity and reliability. Although measuring force signal have been widely used for monitoring of metal machining process that their application to stone cutting has not been well investigated. In this paper, the effect of machining parameter on force signal and tool wear was investigated. The result indicate that increasing of the depth of cut and spindle speed will increase the force and tool wear while increasing feed rate will increase force and decrease tool wear  

In this study a hydractive suspension system is designed for a passenger car. By using a mathematical validated model with eight degrees of freedom for a vehicle which is equipped with hydractive suspension, optimal damping forces derived for suspension system on the base of optimal control theory which uses linear quadratic regulators for improving ride comfort of vehicle and saves vehicles stability at the same time. Existing limitations for applying damping forces and time lag of controlling component are considered. The results are being derived according to a bump excitation and nonlinearity effects of the hydractive suspension components. Simulation results for the hydractive optimal... 

Auto-Exposure detection is a key feature in digital cameras and smart-phones. The image information can be used to detect scene over and under exposure passively. This paper introduces an effective optimal exposure detection function based on joint probability density function of the pixels in the scene  

Burr in drilling plays an important role on product quality, so analysis the burr height is essential at the final production. This paper presents the application of Taguchi method for survey the burr height by adding ultrasonic vibration to the process. In this paper L18 orthogonal array based on Taguchi techniques was used in the design of experiments. Analysis of Variance (ANOVA) was used to determination the effect of drilling parameter on burr formation. Influence of spindle speed, feed rate and percentage of SiC particle was investigated in with and without ultrasonic assisted drilling. In this paper drilling of Al/SiCp MMCs with 5, 15 and 20 wt% of particulate SiC in dry drilling... 

Data aggregation is a technique that is used to decrease extra and repetitive data in cluster based routing protocols. As we know SPEED routing algorithm is based on service quality and dose not perform data aggregation. In this article, we try to add an data aggregation technique to the available techniques without interfering with the functions of previous ones. The idea involves virtual configuration of sensors and specification of an individual ID to the created data by the sensors in each region, then data aggregation in relay node is done by this ID, resulting in less energy consumption, lower traffic and repeated data, an increase in network lifetime and better quality of service  

In this study two-dimensional finite element models of Al/SiC metal matrix composites (MMC) by using of ABAQUS Explicit software are investigated. Chip formations and machining forces for three types of MMC with 5, 15 and 20% of SiC reinforcement particles were studied and compared with experimental data. The resulted chips in simulation and the generated chips in experiments have both continuous and saw tooth in appearance. On the other hand, the variation of the cutting forces with the cutting time in simulation and experiment have fluctuating diagram. This is due to the interaction between cutting tool and SiC particles during chip formation. ABAQUS explicit software was used for... 

The aim of this study is to investigate the effect of the rock brittleness indexes on the specific ampere draw of the circular diamond saws. In this study, twelve rock types belonging to granite and carbonate rock were cut with two different types of circular diamond saws on a fully instrumented laboratory-sawing rig at different feed rate and depths of cut. Rock samples were collected from factories from Iran for laboratory tests and uniaxial compressive strength and tensile strength were determined. The brittleness of B 1 (the ratio of compressive strength to tensile strength), B 2 (the ratio of compressive strength minus tensile strength to compressive strength plus tensile strength), and... 

The bioinertness makes surface treatments essential to improve the bioactivity of porous titanium scaffold, and surface treatment might affect their mechanical properties. So finding an optimum condition lying between bioactivity and mechanical properties seems to be curial. In this research, the effect of the time of the thermal oxidation at 600 °C on apatite formation and mechanical properties of the porous titanium scaffold was studied. The results of thin film X-ray diffraction and Raman spectroscopy indicated that the surface of heat treated samples up to 480 min was mainly covered by rutile. Also, wettability measurement and in vitro apatite formation ability assessment indicated that... 

The aim of the present study is to improve the efficiency of a rotor bearing system for passing through critical speed. The current study assesses the influences of support parameters on the cracked rotor response for passing through critical speeds. The actual breathing mechanism of the transverse crack is addressed herein. The Finite element model is developed for more realistic analysis. The Newmark-β method to solve the nonlinear lateral vibration of rotor-bearing systems is approached and the effects of various parameters are shown. © 2024, The Author(s), under exclusive license to Springer Nature Switzerland AG  

Ce-doped ZnO nanocomposite thin films with Ce/Zn ratio fixed at optimum value (10 at.%) have been prepared via sol-gel method at different annealing temperatures varied from 180 to 500 °C. The synthesized samples were characterized employing atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) techniques. According to AFM analysis, the average grain size increased from about 70 nm to 150 nm by increasing the annealing temperature from 300 to 500 °C. Moreover, based on the XPS data analysis, it was found that three major metal ions namely Ce 3+, Ce4+, and Zn2+ coexist on the surface of the nanocomposite films. XPS data analysis also revealed that... 

Ce-doped ZnO and pure ZnO nanocomposite thin films with different Ce/Zn ratios (0, 2, 5, 10, 15, 20, and 30 at.%) have been prepared by sol-gel method at optimum annealing temperature of 500 °C. The synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-vis spectrophotometry. According to our XPS data analysis, there are three major metal ions namely Ce3+, Ce4+ and Zn 2+ that coexist on the surface. The XRD measurements indicate that the ZnO thin films have a hexagonal wurtzite structure, and CeO2 crystallites formed in the Ce-doped ZnO nanocomposite thin films. Photoelectrochemical property of the samples was studied by three... 

Feature coding has received great attention in recent years as a building block of many image processing algorithms. In particular, the importance of the locality assumption in coding approaches has been studied in many previous works. We review this assumption and claim that using the similarity of data points to a more global set of anchor points does not necessarily weaken the coding method, as long as the underlying structure of the anchor points is considered. We propose to capture the underlying structure by assuming a random walker over the anchor points. We also show that our method is a fast approximation to the diffusion map kernel. Experiments on various data sets show that with a... 

We study the effect of boron (B) and phosphorous (P) doping and B/P codoping on electronic and optical properties of graphitic carbon nitride (g-C3N4 or GCN) monolayers using density functional simulations. The energy band structure indicates that the incorporation of both B and P into a hexagonal lattice of GCN reduces the energy band gap from 3.1 for pristine GCN to 1.9 eV, thus extending light absorption toward the visible region. Moreover, on the basis of calculating absorption spectra and dielectric function, the codoped system exhibits an improved absorption intensity in the visible region and more electronic transitions, which named π∗ electronic transitions that occurred and were...