Sharif Digital Repository

Despite the benefits of chemotherapy, radiotherapy, and surgical resection in cancer treatment, the efficiency of these techniques is insufficient. The development of nanocarriers enabling combined diagnosis and therapy is progressive but still is limited. In this paper, we developed bandgap-modified Fe3O4@Ag@CuS nanoparticles conjugated with AS1411 DNA aptamer (aptaNPs) for photothermal therapy (PTT) and dual magnetic resonance (MR) and infrared (IR) imaging. It is shown that the developed nanoparticles induce localized surface plasmon resonance (LSPR) to promote the efficiency of photothermal therapy. In vitro and in vivo studies demonstrate that aptaNPs are highly specific against 4T1... 

High Voltage Direct Current (HVDC) transmission poses stern threats to insulators due to unidirectional high voltages. Room temperature vulcanized (RTV) silicone rubber (SiR) coatings are highly preferred to cope with flashovers. In this work, RTV-SiR coating co-filled with silica (SiO2) and alumina trihydrate (ATH) fillers underwent prolonged accelerated weathering under bipolar direct current (DC) for an extended aging period of 10,000 hours. The results revealed that samples containing nano SiO2, and micron-ATH displayed enhanced hydrophobic recovery, leading to improved suppression of leakage current, whereas ATH-filled composites demonstrated better performance in surface resistivity... 

This research examines the complex interplay between the carbon nanotubes' length and radius and how that affects flow patterns, heat transfer properties, and entropy creation in both convergent and divergent channels. Our research elucidates the mechanisms at play by revealing a crucial link between carbon nanotube dimensions and the efficacy of heat transfer processes. In particular, carbon nanotubes with a longer length have better heat transmission properties, while carbon nanotubes with a smaller radius generate less entropy. From microfluidics to energy-efficient materials, these results show significant promise for optimizing thermal systems and improving performance. This research... 

In this study, an enzymatic pathway has been developed to replicate the Calvin Cycle by creating the individual steps of the carbon cycle in a bioreactor. The technology known as “artificial photosynthesis” converts CO2 emissions into a variety of intermediates that serve as precursors to high-value products. CO2, light, water, and electricity were used as feedstock. An electrochemical reactor was also studied for the regeneration of active NADH operating at constant electrode potential. Initially, a batch electrochemical reactor containing 80 mL of 0.2 mM NAD+ in Tris-buffer (pH 7.40) was used to evaluate the electrode material operating at normal temperature and pressure. The results... 

Thermal engineering and industrial processes see various multidisciplinary applications due to the enhanced thermal performances of nanomaterials. The nanomaterials preserve a profound breakthrough in enhancing the heat transfer phenomenon. The objective of the current investigation is to address the thermal applications of couples-stress nanofluid in the presence of triple diffusion effects. The analysis is subject to the bioconvective significance of the suspension of microbes. The viscosity and thermal conductivity of a couple stress fluids are assumed to be variable. Moreover, we endorse linear thermal radiation effects and approach the problem with an effective Prandtl number. The... 

The integration of artificial intelligence in industry and the adoption of green finance emphasizing environmental sustainability through technology has become increasingly prominent. This article scrutinizes the asymmetric nexus between industrial artificial intelligence and green finance in the top ten countries leading in industrial artificial intelligence (China, USA, South Korea, Germany, Japan, Canada, UK, Australia, France, and Italy). Preceding studies applied panel data approaches to examine the industrial artificial intelligence-green finance nexus without considering that not all countries had established such a connection autonomously. Conversely, this paper implements a... 

This research work was conducted to investigate the anatomical and antioxidant studies of some ethnoveterinary grasses (Cenchrus pennisetiformis and Dichanthium annulatum). The anatomical characteristics (compact epidermal layer, large cortical cells, thickened sclerenchyma, central and scattered vascular bundles, large metaxylem, small protoxylem, and centrally located pith) were observed. For the antioxidant activity studies, the crude methanol extract was prepared by maceration techniques and different fractions were prepared (n-hexane, chloroform, and aqueous solution). The maximum antioxidant potential in DPPH was shown by C. pennisetiformis at a concentration of 250 µL in the... 

Application, Purpose, and Methodology: The Soret and Dufour effects, which are also referred to as cross-diffusion gradients, are advantageous to the manufacturing of binary alloys, the transmission of groundwater contamination, the extraction of oil, and the separation of gas. These are an example of a gradient, which occurs when substances diffuse over one another. The Dufour effect is responsible for the transfer of heat, whereas the Soret effect is concerned with the movement of materials. Both effects are caused by differences in concentration. Temperature differences are the link between the two effects. The Soret and Dufour statistics, in conjunction with the joule heating process,... 

Sustainable agriculture is a pivotal driver of a nation’s economic growth, especially considering the challenge of providing food for the world’s expanding population. Agriculture remains a cornerstone of many nations’ economies, so the need for intelligent, sustainable farming practices has never been greater. Agricultural industries worldwide require sophisticated systems that empower farmers to manage their crops efficiently, reduce water wastage, and optimize yield quality. Yearly, substantial crop losses occur due to unpredictable environmental changes, with improper irrigation practices being a leading cause. In this paper, we introduce an innovative irrigation time control system for... 

This study focuses on a forward looking approach in which deep eutectic solvents (DESs), a new class of designer solvents, were impregnated into micro porous polyvinylidene fluoride (PVDF) membrane for the separation of CO2 from CH4. Three types of DESs were prepared by mixing and heating of hydrogen bond acceptor (choline chloride) with either malic acid, tartaric acid or oxalic acid as hydrogen bond donor. The Fourier transform infrared spectroscopy confirmed the hydrogen bond interactions in the resulting DES. Thermal gravimetric analysis (TGA) was used to evaluate the thermal stability of the prepared membranes. The DES based supported liquid membranes were investigated systematically to... 

Ca-doped Ni–Mg–Mn spinel ferrites with compositions of Ni0·5Mg0·3Mn0.2CaxFe2-xO4 (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) were prepared via sol-gel auto-ignition technique. TGA/DTA, FTIR, XRD, FESEM, and VSM were employed to evaluate the thermal, spectral, structural, morphological, and magnetic features of Ca-doped Ni–Mg–Mn spinel ferrites. TGA/DTA curves show the weight loss in the sample. This weight loss was attributed to the oxidation and decomposition of the sample contents at a temperature of 500 °C. XRD reveals a single-phase structure of the Ni–Mg–Mn nano ferrites. A single-phase orthorhombic structure was confirmed for Ca-doped Ni–Mg–Mn ferrites. Structural parameters such as lattice... 

Global indicators have warned of freshwater scarcity in Asia. However, the utilization of freshwater resources has skyrocketed for commercial and industrial purposes without any strategy for recycling and reuse. The power plant’s wastewater/reject mainly consisted of cooling tower blowdown water and reverse osmosis (RO) plant reject water. Due to the high turbid nature of reject water, pretreatment was carried out to achieve SDI15 <3 by employing multimedia filters (MMF), activated carbon filters (ACF) and ultrafiltration (UF). Operational parameters of RO membranes were optimized (11.5 bar, 29 °C) to achieve maximum water recovery along with higher rejection rates of critical scale forming... 

Trichloroethylene (TCE) is known for its carcinogenic properties and limited environmental degradation. Therefore, TCE degradation was carried out using a catalyzed system, i.e., an advanced oxidation process (AOP) for an aqueous solution. This study focuses on activating sodium persulfate (PS) by laboratory-synthesized iron sulfide nanoparticles (FeS-NPs) with a particle size of 115.17 nm for enhanced TCE degradation. Field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), and Brunauer-Emmett-Teller (BET) analyses were employed to investigate physio-chemical properties and... 

This article presents the variation of structural, electronic, thermal and optical properties of a halide perovskite CsYbBr3with increasing pressure, employing density functional theory. The pressure effect was determined in range of 0-15 GPa. In which stability of CsYbBr3remains valid, as, verified from negative values of enthalpy of formation and phonon dispersion curves. A significant change was observed in lattice constant, bond lengths, bulk modulus and its pressure derivative, volume and ground state energy, with increasing pressure. The calculated electronic properties presented CsYbBr3as a semiconductor with direct band gap of 3.61 eV. However, pressure rise shift the Yb-d states... 

Mango fruit borer (MFB) is a significant pest that damages mango fruits and leaves. This study explores farmers’ perceptions of the mango fruit borer and evaluates management practices. Survey findings indicated that 48% of mango growers believed MFB attacks occur during April-May, while 30% identified May-June as the peak season. Additionally, 84% of mango growers believed MFB affects fruits, while only 2% think it also targeted leaves. Most mango growers (78%) preferred chemical methods to manage MFB, with 40% using bifenthrin, 28% using emamectin benzoate, and only 8% applying imidacloprid. Experiments evaluating MFB’s preference for different mango varieties revealed that nearly all... 

This article explores the dynamics of nanofluids consisting of copper (TiO2) nanoparticles suspended in water, as they interact with sensor surfaces between two parallel squeezing plates with porous characteristics. This research specifically targets applications involving enhanced heat transfer and magnetohydrodynamic (MHD) control in nanofluid systems. The primary aim is to analyze the effects of nanoparticle aggregation and non-aggregation on sensor surfaces, considering MHD formations and heat transfer in the energy and momentum equations. The research adopts a steady-state fluid condition and utilizes similarity transformations to convert partial differential equations into more... 

Heat transfer study influenced by various physical effects like thermal radiations, convective heat condition and thermal slip is one of the influential research domain specifically in applied thermal and chemical engineering. Therefore, the key purpose of this is to develop and discuss the heat performance of ternary nanofluid model including the effects of above mentioned parameters. The model is developed for laminar flow of ternary nanofluid about stagnation point over a cylinder's surface. Use of similarity transforms, properties of ternary nanofluids and ternary particles are exercised to obtain final model. Then, the RK-scheme is implemented for demonstration of the physical results... 

In response to environmental concerns at the global level, there is considerable momentum in the exploration of materials derived from waste that are both sustainable and eco-friendly. In this study, CS-Fe (carbon, silica, and iron) composite was synthesized from coal gasification slag (CGS) and innovatively applied as a catalyst to activate PS (persulfate) for the degradation of trichloroethylene (TCE) in water. Scanning electron microscope (SEM), fourier transmission infrared spectroscopy (FTIR), energy dispersive x-ray spectroscopy (EDS), brunauer, emmet, and teller (BET) technique, and x-ray diffractometer (XRD) spectra were employed to investigate the surface morphology and... 

In the current study, we focus on the Magneto-Marangoni convective flow of dusty tangent hyperbolic nanofluid (TiO2 – kerosene oil) over a sheet in the presence of thermophoresis particles deposition and gyrotactic microorganisms. Along with activation energy, heat source, variable viscosity, and thermal conductivity, the Dufour-Soret effects are taken into consideration. Variable surface tension gradients are used to identify Marangoni convection. Melting of drying wafers, coating flow technology, wielding, crystals, soap film stabilization, and microfluidics all depend on Marangoni driven flow. This study’s major objective is to ascertain the thermal mobility of nanoparticles in a fluid... 

The productive and straightforward strategy was developed to fabricate graphene based NiFe2O4 doped rare-earth (RE) ions nanocomposites for enhancing the magnetic and structural characteristics of ferrites. RE nanoparticles (NPs) such as Yb3+, Gd3+ and Sm3+ were doped in NiFe2O4 ferrite structure via sol-gel auto-combustion method and hydrothermal method was utilized to fabricate their graphene-based nanocomposites. The weight loss and decomposition of the nanocomposites were determined using temperature-dependent thermo gravimetric analysis (TGA/DTA). The single-phase structure of the NiFe2O4, NiFe2O4/G, Yb doped NiFe2O4/G, Gd doped NiFe2O4/G, and Sm doped NiFe2O4/G nanocomposites was...