Sharif Digital Repository

Atom transfer radical polymerization (ATRP) is a convenient approach to synthesis of polymer with narrow molecular weight distribution. ATRP of acrylamide (AAm) is taken into consideration because of the intrinsic properties of acrylamide such as water solubility and biocompatibility. As reported in many recent works, polymerization of acrylamide by this method didn’t provide monomodal molecular weight distributions. In best condition with strong ligands such as Me4Cyclam, polymerization was carried out in a short time with high yield but polymerization was not highly controlled. It was shown that polymerization of acrylamide under typical ATRP condition displayed a much lower ATRP... 

In recent years, autonomous unmanned aerial vehicles (UAVs) have attracted considerable amount of interest because of a wide area of applications and a lot of advantages. UAVs have been extensively used for military operations that include tracking, surveillance, active engagement with weapons and airborne data acquisition. UAVs are also in demand commercially due to their advantages in comparison to manned vehicles. These advantages include lower manufacturing and operating costs, flexibility in configuration depending on customer request and not risking the pilot on demanding missions. Safety and efficiency are crucial factors in drones, so in this thesis, these issues are considered. Wind... 

This project aims to design a drug to fight leukemia and some autoimmune diseases having few side effects. These drugs are composed of natural sugar and amino acid structures. Among the various treatments available, drug structures as inhibitors of enzymes involved in cancer-related cellular processes is an important treatment. Methotrexate is one of the most widely used anticancer drugs in the last half-century and treats leukemia and many autoimmune diseases such as psoriasis. It is a derivative of folic acid (vitamin B9) and one of the drugs with specific properties. It is an anti-folate whose anti-metabolic effects can help kill cancer cells. One of the problems with using this drug to... 

Entrepreneurship is a process that requires high motivation for success. Self-efficacy is to believe the person's ability to organize and carry out certain types of activities to produce specific outcomes. Thus helping to increase self-efficacy beliefs in people who have attempted to entrepreneurship can increase their chances of success. On the other hand Self-leadership has been defined as “the process” of influencing oneself to establish the self-direction and self-motivation needed to perform. And include three major strategies named Behavioral focused strategies, Intrinsic motivation (Natural Reward) strategies, Constructive thought pattern strategies and some specific behaviors in each... 

In this study, a structural health monitoring method called the Sensor Network Frequency-Based (SNFB) method is presented, which uses the structure’s frequency response function to identify multiple damage locations. This method is not only accurate but also simple and cost-effective, making it suitable for preliminary structural health monitoring. Due to limitations in the existing technical literature, comprehensive experimental and numerical studies were conducted on steel beams with various damage scenarios. In the experimental study, beam specimens were excited using a modal hammer, and the structural response was recorded by a sensor network. To determine the damage locations, the... 

With the increasing development of Internet of Things (IoT) devices, issues such as establishing effective communication, optimizing energy consumption, ensuring reliability and improving the quality of services provided by these devices become more and more complex and critical challenges. With the introduction of fog computing model by Cisco in 2012, some of these challenges were successfully managed. Fog computing is a distributed computing paradigm that acts as a middle layer between cloud data centers and IoT-based devices/sensors. By distributing computing resources closer to edge devices, fog computing enables real-time data processing and analysis. However, one of the key aspects in... 

This study aims to synthesis and fabricate polyacrylonitrile (PAN) polymeric nanofibers via electrospinning, grow zinc oxide (ZnO) nanorods on this flexible substrate, and subsequently activate the system under visible-light irradiation through the deposition of silver (Ag) nanoparticles. The resulting hierarchical structure was investigated for its application in the photocatalytic degradation of organic pollutants under various light sources, with particular emphasis on natural sunlight, as well as for elucidating the underlying photodegradation mechanisms. One of the major challenges associated with heterogeneous photocatalysts in practical applications is their difficult separation from... 

The airport terminal is difficult to plan and design due to the different components and the intricate complexity of its parts. At the airport terminal, we face a queue system which simulation is always a good way to analyze. In addition, computer simulation using modern softwares with the capability to model different types of systems, including the airport terminal, while being less realistic than analytical models, is less costly than operational Exercise.In this study, a supportive approach for better and specific management of Iranian airport terminal buildings with discrete-event simulation is proposed, considering the need for managing the airport terminals building in the country and... 

Limited water resources in Iran have made dams an important part of the country’s infrastructure. As a result of the large number of in-progress and expected dam projects in the country, consideration of sustainability factors during planning, construction and operation phases of dam projects can create significant economical, social and environmental impacts in the long term. To come up with an inclusive sustainable development, new sustainability assessment approaches seek for sustainable development at the entire project’s life-cycle; they are looking for sustainable development at all design, construction, operation, maintenance and even demolition phases. In this research we have... 

Despite of many advantages, electro submersible pumps (ESP) have very high costs in maintenance. Since ESP usually operates in deep wells, it should be transported to the surface in order to malfunction. In addition, the state of ESP equipment cannot be determined because of unavailability of vibration measurement on the site. Thus, this equipment fails suddenly. This process costs a lot on country’s oil and water & wastewater industry. so in this thesis, at first, the potential failure modes (PFM) of ESPs are investigated, then proper methods are presented for condition monitoring. Finally, the presented methods are verified by experimental tests and wavelet analysis. The results show that... 

In this thesis its considered the characterization of an ultrasound wave in a medium with some obstacles. Derivation of speed of molecules and pressure of the wave is carried out in the Cartesian coordinates system. Simulation is carried out to prove the dependency of wave speed to set up parameters such as the target point (x,y,z) at which the speed value is obtained, the location of the obstacles, the amplitude of original wave emitting from the source, and the propagation speed in different layers of the medium. From the numerical results, it is apparent that the amplitude of the speed wave gets degraded as the wave travels through the medium which is a function of reflection and... 

Carl Jung's analytical psychology is a psychoanalytic theory that has been established with the assumption of the existence of a collective and inheritable unconscious containing archetypes. The archetypes are psychic patterns that have evolved throughout human history and are inherited by human infants. Repressing these innate and universal properties can cause psychic problems for humans. Those repressed innate properties could emerge indirectly to keep the mental balance, but this may cause problems due to being out of conscious control of the individual. According to Jung's claim, remembering and accepting these repressed identities and then integrating the conscious and unconscious...