Sharif Digital Repository

A comparative investigation has been developed for the stability constants of several amino acid complexes with divalent metal ions, which have been determined by potentiometric pH titration. Depending on the metal ion-binding properties, vital differences in the building complexes were observed. The present study indicates that in some M(L) complexes, metal ions are arranged in carboxyl groups, but in other M(L)complexes, some metal ions are able to build chelate over amine groups. The results mentioned-above demonstrate that for some M(L) complexes, the stability constants are also largely determined by the affinity of metal ions for amine group. This leads to a kind of selectivity of... 

The acidity and stability constants of M-Met (M: M2+; Met 1: L-methionine) complexes, determined by potentiometric pH titrations, were used to make a comparative investigation with L-cysteine (Cys). It is shown that regarding to M ion - binding properties vital differences on complex bilding were considered. It is demonstrated, that in M-Met complexes, M ion is coordinated to the carboxyl group, M ion is also able to build macrochelate over amine group. The upmentioned results demonstrate that for M-Met complex the stability constants is also largly determined by the affinity of Cu2+ for amino group but in opposite to Met, some metal ions such as Co2+, Cu2+, and Zn2+ build with Cys 2... 

Waste water from ore plant layout central Alborz's coal has been investigated and analyzed. Studies showed that because of acidic character, the waste water contains heavy metals including Cu, Cr, Ba, Zn, V, Sr, Pb, Ni. Considering the importance of this topic for outgoing acidic waste waters which is hazardous for the environment, i.e. heavy metals, the same should not be transferred into the environment. Since their waste water is transferred into nearby agricultural ground, it was developed a method, so that waste water is primarily directed into a slug pond for sedimentation. In the second stage in another pond, the outflow of waste water was treated with chemicals. Also the pH was... 

Despite complex fluctuations, missing data, and maintenance costs of detectors, traffic volume forecasting at intersections is still a challenge. Moreover, most existing forecasting methods consider an isolated intersection instead of multiple adjacent ones. By accurately forecasting the volume of short-term traffic, a low-cost method can be provided to solve the problems of congestion, delay, and breakdown of detectors in the road transport system. This paper outlines a novel hybrid method based on deep learning to estimate short-term traffic volume at three adjacent intersections. The gated recurrent unit (GRU) and long short-term memory (LSTM) bilayer network with wavelet transform (WL)... 

In the past two decades, microfluidic systems have become more appealing due to their wide applications in many areas, such as electronics, biotechnology, medicine, etc. Recently, the advantages of using the bubble growth phenomenon as a robust actuator in microfluidic devices have directed research interests towards the investigation of various applications. In this research, a new transient thermo-hydraulic model has been developed for bubble growth in confined volumes. The present model has been used to describe the pumping effect produced by the bubble growth and collapse phenomenon in microchannels. The results show relatively good agreement with experimental data. This study is useful... 

Rehabilitation is the best approach for patients who suffer physical disability of their upper-limbs. Maintaining the intensity of exercise during treatment is the main factor that makes the robots suitable for rehabilitation since robots do not get tired and do the exercises with constant intensity under supervision of the doctor. Two main categories of rehabilitation robots are End-Effector based robots and wearable robots. According to the fact that most problems occur in need of rehabilitation for hand wrist area, in this paper a wearable rehabilitation robot has been developed for the wrist. Nowadays, wearable robots attract more attention than the other group. Wearable robots are... 

The potential utilization of encapsulation techniques in food, pharmaceutical and agricultural products preparation, presents a new alternative for complementary technologies such as targeting delivery vehicles and carriers for active food ingredients. Encapsulation could be accomplished by different techniques like: simple or complex coacervation, emulsification technique, phase separation, spray drying, spray chilling or spray cooling, extrusion coating, freeze drying, fluidized-bed coating, liposomal entrapment, centrifugal suspension separation, co-crystallization and molecular inclusion complexation. Encapsulation is a method by which one bioactive material or mixture of materials is... 

Nowadays, as the oil reservoirs reaching their half-life, using enhanced oil recovery methods is more necessary and more common. Simulations are the synthetic process of real systems. In this study, simulation of water and surfactant injection into a porous media containing oil (two-phase) was performed using the computational fluid dynamics method on the image of a real micro-model. Also, the selected anionic surfactant is sodium dodecyl sulfate, which is more effective in sand reservoirs. The effect of using surfactant depends on its concentration. This dependence on concentration in using injection compounds is referred to as critical micelle concentration (CMC). In this study, an... 

In this article, the induced airflow and the resultant particles resuspension due to a disk falling freely under the effect of gravity is studied using numerical and experimental approaches. The results showed that an axisymmetric vortex is generated on the disk tip as the disk falls and sheds after impacting the floor. While the effect of this ring vortex on the particles detachment from the floor is small, it has considerable influence on the dispersion of resuspended particles. The simulation results indicated that particles are mainly resuspended from an annular area beneath the disk tip where the generated wall shear is sufficiently high. As particles detachment is mainly controlled by... 

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 and N2 gas atmosphere from 25 to 600 °C, the thermal behavior of chromium(VI) oxide CrO3 was investigated. The identity of products at different decomposition steps was confirmed by XRD technique. Both techniques produced similar results supporting the same steps for the compound. The received products were investigated by SEM electron microscope. The form and the size of crystals were investigated. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported  

With regards to the global continuous growth in consumption of base metals such as antimony (Sb), mining companies are currently looking to improve the productivity and extraction of Sb from low grade ore in order to economically process it. With this aim, in this study, an efficient protocol was developed to recover metallic Sb from the low grade Fe3Si2O5(OH)4. Sb3O6(OH). Sb2O3 ore of the Sefid-Abe mine in Zahedan province, Iran, utilizing selective acidic or alkaline leaching followed by Sb electrowinning. A process was developed to recover antimony from an Sb2O3 ore source, using selective acidic or alkaline leaching followed by antimony electrowinning. Sb could be leached with an... 

During the recent decade, high induction diffusers have become more appealing in applications which require relatively high ventilation airflow rates, such as clean rooms. In this research, the effect of geometric parameters on the performance of a specific type of swirling air diffuser is investigated numerically. The results show that although the diffuser slots geometry, namely their angle and aspect ratio, is impressive on the diffuser performance, it is not as important as the swirling blade angle and the performance is almost constant in a wide range of slots specifications. The results also demonstrate that the diffuser performance and the resultant indoor airflow distribution highly... 

Surgical site infection (SSI) is one of the important infectious problems in hospitals. It is well known that appropriate ventilation strategy is most effective way to control bacteria-carrying airborne particles responsible for SSI. With considerable improvement in the computational capacity of computers, computational fluid dynamics (CFD) technique has been widely used to study the indoor airflow and contaminant dispersion over the enclosures. In this research, the effect of inlet air velocity on the ultra-clean ventilation system performance is investigated Eulerian-Lagrangian numerical approach. The results show that surgical wound contamination may be highly affected by inlet velocity.... 

Increasing concerns about global warming and environmental pollution control has pushed the relevant organizations to set regulations and to develop programs for energy saving. In addition, for many high energy using appliances, energy labeling provides the end user with important data to select energy-efficient equipments and encourage the manufacturers to enhance the performance of their productions. In this research, a new energy-saving program for wet cooling towers has been developed. Considering a thermo-hydraulic analysis, a novel Energy Index (IE) has been extracted which takes all aspects of the problem into account. The present index can be used as a proper criterion for energy... 

The primary source of surgical site infection is the deposition of flakes released from the exposed skin of surgical staff or the patient on the exposed surgical wound. In this study, a computational model for simulating air ow and thermal conditions in an operating room is developed, and transport and deposition of particulate contaminants near the wound are analyzed. The results show the formation of a thermal plume over the wound tissue, which is typically at a higher temperature than the surrounding. The thermal plume protects the wound from the deposition of contaminants. In addition, the computational model predicts an optimum value for the inlet air velocity that is mainly maintaining... 

Social norms are a core concept in social sciences and play a critical role in regulating a society's behavior. Organizations and even governmental bodies use this social component to tackle varying challenges in the society, as it is a less costly alternative to establishing new laws and regulations. Social networks are an important and effective infrastructure in which social norms can evolve. Therefore, there is a need for theoretical models for studying the spread of social norms in social networks. In this paper, by using the intrinsic properties of norms, we redefine and tune the Rescorla-Wagner conditioning model in order to obtain an effective model for the spread of social norms. We... 

PbCO 3·PbO and PbCO 3·2PbO compounds were prepared by thermal methods. The structure of each compound was determined by using XRD technique, and their purity was confirmed by analytical methods (98%). Also the thermal characteristics of each compound were investigated by thermogravimetry. At 600°C both compounds decompose completely and produce lead(II) oxide. © 2006 Nauka/Interperiodica  

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 gas atmosphere from 25 to 600°C, the thermal behavior of laboratory-produced compound lead(IV) oxide α-PbO2 was investigated. The identity of products at different stages were confirmed by XRD technique. Both techniques produced similar results supporting the same decomposition stages for the compound. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported. © 2008 Springer Science+Business Media, LLC  

The compound, alkaline lead acetate, Pb(CH3COO)2·PbO·H2O (ALA), was purchased from the Fluka Company. The X-ray diffraction film and SEM electron microgaph of this compound were obtained and reported in this paper for the first time. The thermal behavior of alkaline lead acetate (ALA) was studied using thermogravimetery (TGA) and Differential Scanning Calorimetery (DSC) techniques under an O2 gas atmosphere from 25 to 600°C. Four distinct energy changes associated with weight changes were observed, all of them being exothermic in the DSC results. The amount of ΔH for each peak is reported. © Sharif University of Technology  

The compound, lead hydroxide Pb6O4(OH)4, was prepared by a method used for the first time in the authors laboratory. The compound was identified by XRD and it's purity was determined by analytical methods (100%). The thermal characteristics of this compound were investigated by using a thermogravimetry (TGA). This compound was found to be stable at room temperature and at 160°C will decompose completely to produce lead (II) oxide. © Sharif University of Technology, April 2007