Sharif Digital Repository

In this study, the influence of CO2 and CH4 on the performance and selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of these gases (0-20 vol.% of feed) to the feed stream. The effect of temperature and feed flow rate are also inspected. The results show that low amounts of CO2 in the feed stream do not change the catalyst activity, but increasing the amount of CO2 (more than 10 vol.%), causes the CO conversion to decrease and the selectivity of heavy components to increase. Methane acts as an inert gas and does not affect the catalyst performance. Increasing feed flow rate has a negative effect on both CO conversion and heavy component selectivity. By raising the temperature,... 

Drying of green peas in a Fluidized Bed Dryer (FBD) with inert particle, heated by combined sources of hot air and InfraRed (IR) radiation, has been experimentally and theoretically studied. For this purpose, an experimental set up was constructed. This setup was composed of a cylindrical bed dryer containing some inert particles which are fluidized by hot air. Some infrared lamps were also placed around the bed for heating assistance. A sample of green pea was hung in the fluidized bed and its moisture content, surface and central temperature were measured with time. A mathematical model, based on the two layers concept of penetration and conduction was also proposed for this process. The... 

Nowadays, fluidized bed plays an important part in industry. The design of this kind of reactor requires knowing the interfacial area between two phases and this interfacial area leads to calculate the solid holdup in the bed. Consequently achieving interfacial area between gas and solid in the bed experimentally is so significant. On interfacial area measurement in fluidized bed with gas has been worked, but light transmission technique has been used less. Therefore, in the current research the possibility of using of this technique and its accuracy are investigated. Measuring, a fluidized bed was designed and the problems were averted as far as possible. By using fine solid with equal... 

The adsorptive removal of terephthalic acid (TPA) and p-toluic acid (p-tol) by metal organic frameworks (MOF) of Cu-BTC, Fe-BTC, MIL-101(Cr) and MIL-53(Al) was investigated in this study. The influence of various factors including solution pH, contact time, and initial concentration of TPA and p-tol solutions on the adsorption behavior was evaluated. Different adsorption isotherms and kinetic models were used to fit experimental adsorption data. It was found that the Langmuir and Redlich-Peterson adsorption isotherms were adequate to represent the experimental data (R2 > 0.97) and that the adsorption kinetics was well-represented by a pseudo-second-order kinetic model (R2 > 0.98). The zeta... 

To investigate the gas–solid flow pattern of a combustor-style fluid catalytic cracking regenerator, a laboratory-scale regenerator was designed. In scaling down from an actual regenerator, large-diameter hydrodynamic effects were taken into consideration. These considerations are the novelties of the present study. Applying the Eulerian–Eulerian approach, a three-dimensional computational fluid dynamics (CFD) model of the regenerator was developed. Using this model, various aspects of the hydrodynamic behavior that are potentially effective in catalyst regeneration were investigated. The CFD simulation results show that at various sections the gas–solid flow patterns exhibit different... 

Palladium catalysts supported on functionalized multi-wall carbon nanotubes were synthesized for hydro-purification of crude terephthalic acid containing 2100ppm 4-carboxybenzaldehyde (4-CBA) as impurity. PdCl2 and Pd(OAc)2 were used as precursors. Palladium loadings were 0.05 to 0.6wt.% with catalysts reduced at 200 to 400°C. Catalysts prepared from both precursors with least 0.3wt.% palladium resulted in 99%+ removal of 4-CBA. The most desired selectivity was obtained for the catalyst with PdCl2 as precursor, reduction temperature of 300°C, and palladium loading of 0.3wt.%. This catalyst had slightly better performance than the commercial catalyst (0.5wt.% of palladium on activated carbon)... 

The solubility of hydrogen sulfide gas in ionic liquids (ILs) 1-ethyl-3-methylimidazolium hexafluorophosphate ([emim][PF6]) at temperatures from (333.15 to 363.15) K and 1-ethyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide ([emim][Tf2N]) at temperatures ranging from (303.15 to 353.15) K and pressures up to about 2.0 MPa was measured using a volumetric based static apparatus. The solubility data were correlated using two models: the Krichevsky - Kasarnovsky (KK) equation, and the extended Henry's law combined with the Pitzer's virial expansion for the excess Gibbs energy. Henry's law constants (at zero pressure) were obtained at different temperatures from the obtained experimental... 

Palladium catalysts supported on functionalized multi-wall carbon nanotubes were synthesized for hydro-purification of crude terephthalic acid containing 2100ppm 4-carboxybenzaldehyde (4-CBA) as impurity. PdCl2 and Pd(OAc)2 were used as precursors. Palladium loadings were 0.05 to 0.6wt.% with catalysts reduced at 200 to 400°C. Catalysts prepared from both precursors with least 0.3wt.% palladium resulted in 99%+ removal of 4-CBA. The most desired selectivity was obtained for the catalyst with PdCl2 as precursor, reduction temperature of 300°C, and palladium loading of 0.3wt.%. This catalyst had slightly better performance than the commercial catalyst (0.5wt.%... 

Several corrosion inhibitors, such as, HEDP, sodium molybdate and zinc ions, were added to an aqueous corrosive media containing different concentrations chloride ions, and the corrosion rates (CRs) of carbon steel were measured at various temperatures. It was shown that, in the presence of more than 1,200 ppm of chloride ions, and temperatures greater than or equal to 42.5°C, the combination of HEDP, molybdate and zinc could not control the corrosion in a cooling water system. Then four different models were designed to represent the CR of carbon steel in presence of various corrosive parameters  

1-(2-Hydroxyethyl)-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ionic liquid ([hemim][NTf2]) was synthesized as a new functionalized ionic liquid to study the effect of addition of the hydroxyl group to the imidazolium cation on aliphatic/aromatic separations. For this purpose, liquid-liquid equilibrium (LLE) data for {heptane + toluene or benzene + 1-(2-hydroxyethyl)-3-methylimidazolium bis (trifluoromethylsulfonyl)imide ([hemim][NTf2])} systems were measured at 313.2 K and atmospheric pressure. The measured LLE data were correlated using three basically distinct thermodynamic models; that is, nonrandom two-liquid (NRTL), Othmer-Tobias, and Hand correlations. Results show that... 

The solubility of hydrogen sulfide in a series of 1-(2-hydroxyethyl)-3-methylimidazolium ([HOemim]+)-based ionic liquids (ILs) containing different anions, viz. hexafluorophosphate ([PF6]-), trifluoromethanesulfonate ([OTf]-), and bis-(trifluoromethyl)sulfonylimide ([Tf2N]-) at temperatures ranging from 303.15 to 353.15K and pressures of up to about 1.8MPa was measured by a volumetric based static apparatus. The solubility data were correlated using two models: (1) the Krichevsky-Kasarnovsky equation and (2) the extended Henry's law combined with the Pitzer's virial expansion for the excess Gibbs energy. Henry's law constants (at zero pressure) in mole-fraction and molality scales were... 

The present study aims to convert waste cooking oil (WCO) into biodiesel via phosphomolybdic acid (H3PMo12O40, PMA) supported on Clinoptilolite as a novel green acid catalyst through an electrolysis procedure. The prepared catalysts were characterized by XRD, FTIR, FESEM, EDS, Elemental map, and TEM analyses. The effect of four independent variables on biodiesel yield including methanol to oil molar ratio (6:1–14:1), catalyst weight (2–5 wt%), time (3–5 h), and voltage (15–35 V) was optimized and evaluated by the response surface methodology (RSM) employing central composite design (CCD). The maximum value of biodiesel yield was 96% under the optimal conditions, including the methanol to oil... 

During the past decades, a significant increase occurred in accidental oil spill in the aquatic environments. In this regard, oil spill in Marine freshwater is still considered as a major environmental hazard. In this research, the experimental data on the sorption capacity of expanded perlite to crude oil were correlated with the equilibrium isotherm of Langmuir, Freudlich, Tempkin and the three parameter Redlich-Peterson isotherms. The results obtained from each specified isotherms were compared and accuracy of the models were favorably discussed. Accuracy of each model using the error function were evaluated. Moreover, the effect of type of objective function on the final results was... 

Volatile organic compounds are a major cause of air pollution; therefore, VOCs are a serious fulmination for the environment. According to studies, adsorption processes have a high performance for the removal of pollutants that by selecting the proper absorbent, efficiency will be improved. In this work performance of two metal organic frameworks are studied so porous materials named MIL-101(Cr) and MIL-53(Fe) as an adsorbent for the removal of ethylbenzene have been synthesized hydrothermally. The materials were characterized by Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) analysis, adsorption of ethylbenzene, field emission scanning electron microscopy (FESEM),... 

Some physical and aerodynamic properties of pistachio nut and its kernel were determined in order to design processing equipment and facilities. In this study, several physical properties of pistachio nut and its kernel were evaluated as a function of moisture content in the range of 4.10-38.10% (w.b.). The length, width, height, shell splitting and unit mass of pistachio nut ranged from 16.07 to 17.25 mm, 12.41 to 12.75 mm, 10.98 to 12.24 mm, 3.59 to 4.47 mm and 0.90 to 1.30 g respectively as the moisture content increased. The respected value for pistachio kernel varied from 15.21 to 16.22 mm, 9.11 to 10.53 mm, 8.73 to 9.66 mm and 0.51 to 0.80 g, respectively. In pistachio nut, the... 

Nucleate pool boiling heat transfer coefficient have been experimentally measured on a horizontal rod heater for various liquid binary mixtures. Measurements are based on more than three hundred data points on a wide range of concentrations and heat fluxes. In this investigation, it has been confirmed that the heat transfer coefficient in boiling solutions are regularly less than those in pure component liquids with same physical properties. Several reasons should be responsible for this phenomenon, but mainly it could be related to preferential evaporation of the more volatile component(s) during bubble formation. In this article, the performances of major existing correlations to the... 

Thin-layer drying characteristics of pistachio nuts were determined experimentally as a function of temperature, relative humidity and air velocity. Six mathematical models (Page model, modified Page model, exponential model, diffusion model, two term exponential model and Thompson model) for describing the thin-layer drying behavior of pistachio nuts were investigated. Tests were conducted using four air temperatures (25, 40, 55 and 70 °C), three air velocities (0.5, 1.0 and 1.5 m/s) and two levels of relative humidity (5% and 20%) and three replications for each treatment. Out of the six models considered, Page model was found to be the most suitable for describing the drying behavior of... 

In industrial scale of Gas to Liquid (GTL) process in Fischer-Tropsch (FT) synthesis, a part of reactor outlet gases such as CO2 and CH4 as side reaction products, is usually recycled. In this study, the influence of CO2 and CH4 on the performance and selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of these gases (0-20 vol. % of feed) to the feed stream. The effect of temperature and feed flow rate, are also inspected. The results show that low amounts of CO2 in the feed stream, doesn't change the catalyst activity significantly but increasing the amount of CO2 (more than 10 vol. %) cause the CO conversion to decrease and the selectivity of heavy components to increase.... 

Paenibacillus polymyxa ATCC 21830 was used for the production of curdlan gum for first time. A Box-Behnken experimental design was applied to optimize six variables of batch fermentation culture each at three levels. Statistical analyses were employed to investigate the direct and interactive effects of variables on curdlan production. Optimum cultural conditions were temperature (50. °C), pH (7), fermentation time (96. h), glucose (100. g/L), yeast extract (3. g/L) and agitation speed (150. rpm). The yield of curdlan production was 6.89. g/L at optimum condition medium. Response surface methodology (RSM) and artificial neural network (ANN) were used to model cultural conditions of curdlan... 

Dissolution pressure and nozzle temperature effects on particle size and distribution were investigated for RESS (Rapid Expansion of Supercritical Solution) process. Supercritical CO2 was used as solvent and Ibuprofen was applied as the model component in all runs. The resulting Ibuprofen nano-particles (about 50 nm in optimized runs) were analyzed by SEM and laser diffraction particle size analyzer systems. Results show that in low supercritical pressure ranges, depending on the solvent and solid component properties (Lower than 105 bar for Ibuprofen-CO2 system), nozzle temperature should be as low as possible (80-90 °C for Ibuprofen-CO2 system). In the other hand in high supercritical...