Sharif Digital Repository

Two mononuclear coordination complexes of fullerene[60] with Pd(dba)2 (dba = dibenzylideneacetone), [(η2-C60)Pd(Ph2P(CH2)2PPh2C(H)C(O)R)2] (R = C10H7 (1), C6H4Cl (2)), have been prepared using a simple procedure to explore new directions in palladium catalysis and nanocarbon chemistry. The palladium(0)-[60]fullerene complexes incorporating unsymmetrical phosphorus ylides have been characterized by 1H, 13C and 31P NMR spectroscopic methods and other conventional techniques such as IR, TGA, SEM, ICP-OES, EDX and TEM analysis. Attributed to the enhanced dispersity and uniform size of the Pd nanoparticles with phosphine-functionalized fullerenes, the prepared catalysts exhibited comparable... 

Demand response (DR) is known as a key solution in modern power systems and electricity markets for mitigating wind power uncertainties. However, effective incorporation of DR into power system operation scheduling needs knowledge of the price–elastic demand curve that relies on several factors such as estimation of a customer’s elasticity as well as their participation level in DR programs. To overcome this challenge, this paper proposes a novel autonomous DR scheme without prediction of the price–elastic demand curve so that the DR providers apply their selected load profiles ranked in the high priority to the independent system operator (ISO). The energy and reserve markets clearing... 

In this paper, we analyze the worst-case delay performance of a network of fair queuing servers in case of multiple-paths between source-destination pairs. In order to develop worst-case delay analysis for the multiple-path scenario, two challenging events should be addressed: merging different sub-streams of a session as well as distributing a traffic stream among different paths (traffic partitioning). Specifically, we propose to merge incoming sub-streams of a session to a node according to a limited rate Fair Queuing (FQ) scheme. Although the merged stream is treated as a unity, this approach results in a guaranteed level of service to each sub-stream. In addition, an algorithm is... 

The unsymmetrical Schiff base 1′-hydroxy-2′-acetonaphthoneacetylacetone-ethylendiimine (Hhan)(Hacac)en and its complexes with some transition metals have been synthesized and characterized by elemental analyses, conductometric measurements, infrared and electronic absorption, NMR and mass spectroscopy  

This paper presents a comprehensive study on the Full-Rate and Linear-Receiver (FRLR) STBC proposed as a newly coding scheme with the low decoding complexity for a 2×2 MIMO system. It is shown that the FRLR code suffers from the lack of the non-vanishing determinant (NVD) property that is a key parameter in designing a full-rate STBC with a good performance in higher data rates, across QAM constellation. To overcome this drawback, we show that the existence of the NVD feature for the FRLR code depends on the type of the modulation. In particular, it is analytically proved that the FRLR code fulfills the NVD property across the PAM constellation but not for the QAM scheme. Simulation results... 

In this work, we find upper and lower bounds on the maximum fractional forcing number of the Cartesian power of even cycles. Our result can extend the result of [3] about the maximum forcing number of C2n□C2n to that of the product of an arbitrary number of even cycles of the same lengths. © 2023 Global-Science Press  

Geothermal energy is a type of renewable energy with high availability and independence from climatic and atmospheric conditions. It has been shown that geothermal energy is technically, economically and environmentally more suitable for hydrogen production than other renewable sources. Hydrogen has wide applications in many fields including cooling, oil, gas, petrochemical, nuclear, and energy industries. Afghanistan has significant potential in geothermal power generation and also several hydrogen-consuming industries that provide opportunities for geothermal-based hydrogen production. This study attempted to find suitable locations for the construction of geothermal power plant for... 

Airborne hexavalent chromium is a known human respiratory carcinogen and allergen. Many workers are exposed to hexavalent chromium in various processes which chromium electroplating plants are the most common. In this study, the feasibility of a new control approach to remove this pollutant using chitosan beads as a biosorbent was investigated. Hexavalent chromium sorption was studied relative to pH, pollution concentration, sorbent concentration, temperature, and air velocity using one factor at a time approach and Taguchi experimental design. Polluted air with different chromium mist concentrations (10-5000 μg/m3) was contacted to chitosan beads (3.3-20 g/L), floating in distilled water... 

With the decline in oil discoveries over recent decades, it is believed that enhanced oil recovery (EOR) technologies will play a key role to meet energy demand in the coming years. Polymer flooding is used commonly worldwide as an EOR process. In this work, we propose the synthesis of protected polyacrylamide (PAM) nanoparticles (PPNs) with a hydrophobic polystyrene (PSt) shell by one-pot two-step inverse emulsion polymerization, in which the PSt shell was created by surface polymerization. The shell protects the active PAM chains from premature degradation caused by the harsh environment in the reservoirs, controls the release of the chains as rheological modifiers, and additionally, it... 

Abstract original image Smart Enhanced Oil Recovery Process using Core–Shell Nanoparticles: The cover image denotes schematically the enhanced oil recovery process by flooding using an aqueous dispersion of core–shell nanoparticles made up of protected polyacrylamide nanostructures (PPNs). Y. Tamsilian and his colleagues at Sharif University of Technology (Iran) and the Institute for Polymer Material (POLYMAT, Spain) demonstrated the synthesis of polyacrylamide nanoparticles protected with a hydrophobic polystyrene shell by using a one-pot, two-step inverse emulsion polymerization technique, where the polystyrene shell was created by surface polymerization. The presence of the hydrophobic... 

Recent challenges have brought about an inevitable tendency for enterprises to lunge towards organizing their information activities in a comprehensive way. In this respect, Enterprise Architecture (EA) has proven to be the leading option for development and maintenance of information systems. EA clearly provides a thorough outline of the whole information system comprising an enterprise. To establish such an outline, a logical framework needs to be laid upon the entire information system. Zachman framework (ZF) has been widely accepted as a standard scheme for identifying and organizing descriptive representations that have critical roles in enterprise management and system development. In... 

The unsaturated small strain shear modulus, Gmax, is a key reference value in predicting relationships between dynamic shear modulus and shear strain amplitude and is thus a key quantity to properly model the behavior of dynamically-loaded geotechnical systems such as pavements, rail beds, and machine foundations. From the interpretation of the experimental Gmax results for unsaturated soils, different definitions of trends between Gmax and the stress state of the unsaturated soils and material properties are proposed. However, in most of trends, the relationship between the stress state and void ratio is considered and the effect of void ratio on the unsaturated small strain shear modulus... 

Production of sand is a common issue in oil and gas fields causing various production problems. However, as a result of sand production, rock permeability can also be increased at near-wellbore areas, which is considered to be an advantage of solid particles production. Therefore, this study aims to investigate sand production behavior and permeability changes during sand production experimentally. To do so, a specific core flooding system capable of applying different radial and axial stresses has been designed which is equipped with a special fluid distributer at the outlet to prevent any sand particle blockage during fluid production. As part of this study, eleven unconsolidated synthetic... 

Hydrogen generation from renewable energy resources is considered as a suitable solution to solve the problems related to the energy sector and the reduction of greenhouse gases. The aim of this study is to provide an integrated framework for identifying suitable areas for the construction of wind farms to produce hydrogen. For this purpose, a combined method of Geographic Information System (GIS) and multi-criteria decision making (MCDM) has been used to locate the power plant in Yazd province. The GIS method in the present study consisted of two parts: constraints and criteria. The constraint section included areas that were unsuitable for the construction of wind farms to produce power... 

Tributhyl phosphate (TBP) decomposition in supercritical water oxidation (SCWO) was performed with and without catalyst, at different temperatures ranging from 370 to 480 °C, and different reaction times. Ag2O, CuO, Fe2O3, MgO, and ZnO synthesized by supercritical water were examined in TBP decomposition as the catalyst. TBP structure decomposed under the non-catalytic reaction; nevertheless, the results indicated that the use of catalysts improved the reaction efficiency, which calculated based on total organic carbon (TOC) removal, by far. However, TOC removal using Fe2O3 was 20% higher than the non-catalytic reaction. Having the ability in completion of the redox cycle, iron oxide... 

Due to the devastating ecological effects and constrained reserves of fossil fuels, renewable energies are now globally accepted as viable alternative sources of energy. Among renewable energy sources, wind energy has become globally popular, primarily because wind farms can be rapidly built and easily maintained at a relatively low cost. Wind-powered hydrogen production is an effective solution for storing the excess energy output of wind farms. The hydrogen produced in this way can be used not only in fuel cells but also in cooling, oil, gas, and petrochemical fields. As a country devastated by war and instability, Afghanistan has major energy generation challenges and a substantially... 

Integrated transmission expansion planning (TEP) and generation expansion planning (GEP) with Wind Farms (WFs) is addressed in this paper. The optimal number of expanded lines, the optimal capacity of WFs installed capacity, and the optimal capacity of wind farms lines (WFLs) are determined through a new TEP optimization model. Furthermore, the optimum capacity additions including conventional generating units is obtained in the proposed model. The Benders decomposition approach is used for solving the optimization problem, including a master problem and two sub-problems with internal scenario analysis. In order to reduce the computational burden of the multi-year and multi-objective... 

High temperature proton exchange membrane fuel cells (HT-PEMFC) are polymeric fuel cells that can operate at 120°-200°C). Preparation of new heat-resistant HT-PEMFC materials, e.g., membrane and electrodes, is the most challenging problem for these kinds of fuel cells. A discussion covers the benefits of HT-PEMFC; challenges in developing novel materials for membranes preparation; polymeric membranes of HT-PEMFC; improvement of high temperature membranes; high temperature membranes characteristics and types; and importance of electrodes porosity for HT-PEMFC. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering (Prague, Czech... 

Solar heater has been known as an application of the solar thermal energy that is commonly employed for water heating. Purpose of this research is to introduce a conceptual model for employing solar water heaters (SWHs) in Yazd, Iran. Moreover, structural equation modeling (SEM) is used for assessing effect(s) of the available parameters on the suggested model. Political-cultural-social issues, economic issues, financial support, geographic location, infrastructure, and interactions were assessed as the independent variables of the study. AMOS was used to implement the processes and design the research questionnaire. According to SEM, the dependent variable “interaction” via “economic... 

The global demand for renewable energy sources has arisen significant research interests in marine hydrokinetic energy harvesting from flow induced vibrations. The current study deals with the hydrokinetic energy harvesting potentials of diamond and square oscillators at various inline configurations. Both the sharp edge sections and the wake induced vibrations in tandem arrangement can lead to galloping type of instability with high energy efficiency ratios. The present in-water towing tank experiments comprise 1DoF vibrating systems at Re ranging from 2 × 103 to 4.8 × 104. The results show that the upstream wake generally enhances the system efficiency and the mechanical work done by the...