Sharif Digital Repository

Absorptive characteristics of polyaniline synthesized in different solvents were studied. Water and mixture of water with other solvents were implemented for polyaniline synthesis. Synthesized polyanilines in powder shape is used as an adsorbent to remove toxic hexavalent chromium from aqueous solutions. Experiments were conducted in batch mode. Removal mechanism involving polyaniline is the combination of surface adsorption and reduction. The kind of solvent used at synthesizing stage can affect the capacity of produced polyanilines for removal of heavy metals including chromium. Synthesized polyaniline in water had the maximum chromium removal efficiency. The morphology study of... 

The adsorption of chromium compounds from solutions by a composite of polyaniline/poly ethylene glycol (PANi/PEG) was investigated in this study. Experiments were conducted in batch mode under various operational conditions including agitation time, solution pH, PANi/PEG dose and initial concentration of chromium salts. Results showed that concentration of PEG at synthesizing stage has a significant effect on the capacity of produced composite for removal of chromium. Morphologically, PANi/PEG composite is closely dependent on the concentration of PEG. Maximum removal of hexavalent chromium was experienced when 2. g/L of PEG was used in synthesis of PANi/PEG. Removal of hexavalent chromium... 

Different factors cause vibration. These vibrations make the voyages difficult and reduce comfort and convenience in passenger ships. In this paper, the creating factors of vibration have discussed first, then with mathematical modelling it will be attempted to minimize the vibration over the crew's seat. The modelling consists of a system with two degrees of freedom and by using vibration visolation with passive method of Tuned Mass Damper (TMD) it will be tried to reduce the vibration over personnel. Moreover using active control systems will be compared with passive systems  

In this work, the parametric study of a vapor compression refrigeration system integrated with a PCM storage tank for increasing the condenser sub-cooled temperature has been conducted based on the hottest day in Tehran city. The effects of various parameters such as comfort zone temperature, condenser and evaporator temperatures, and changes in heat transfer coefficient relative to the thickness of the ice formation in the PCM tank have been considered for simulating the desired system in the EES software. The focus of this study is to figure out the system's performance according to the changes in the effective parameters of the PCM storage tank. The results indicate that adding the PCM... 

In this study, the combination of a vapor compression cycle with a phase change material (PCM) storage tank has been assessed experimentally during the hottest day based on Tehran city climatic conditions. The temperature conditions for outdoor (condenser, compressor, etc.) and indoor (evaporator) air conditioning (AC) units are provided with the help of two separate test chambers and a controller system. The desired system has been surveyed based on two scenarios. In each scenario, the system is evaluated for the conventional AC system (with no PCM involved) and the AC plus PCM unit (conventional AC + PCM storage tank). Based on scenario 1 operating strategy, the results show that adding... 

In this study, a vapor compression refrigeration cycle integrated with a phase change material (PCM) storage tank has been dynamically simulated over a 24-h period. The primary objective of this system is to reduce electric energy consumption during on-peak hours (12:00–19:00) and shift it to off-peak hours (1:00–10:00). During off-peak hours, the vapor compression refrigeration system stores cooling energy in the PCM storage tank. The stored cooling energy is then reused during on-peak hours to pre-cool the condenser inlet refrigerant, enhancing the cooling system's performance and reducing electric consumption during on-peak hours. Oleic acid, eutectic mixtures of 45 % capric acid and 55 %... 

Depending on the type of dopant metal, many kinds of zircon based pigments are produced and blue vanadium pigment is the most important one of them. In this study, blue zircon ceramic pigments were synthesized from intermediate product, resulting from decomposition of zircon sand with NaOH. In this regard, various amounts of sulfuric acid, water, NH4VO3 as colorant, NaF as mineralizer and extra quartz were added to the prepared Na 2ZrSiO5. Role of quartz was to omit the repercussions of presence of free zirconia in the composition. The main objective of this work is to assess various reactions at different temperatures during blue pigment synthesis. Phase analysis was done by X ray... 

The primary objective of this investigation is to empirically assess a new vapor compression cycle while employing phase change material (PCM) energy storage. During off-peak periods, the PCM undergoes charging, and during on-peak hours, it is discharged to cool the refrigerant entering the condenser, thereby enhancing the condenser's overall performance. In contrast to previous studies that exclusively examined the charging or discharging processes of air conditioning (AC) units, this research delves into the entire 24-h charge and discharge cycle. The proposed system is subjected to testing under identical conditions, both without PCM (conventional mode) and with a PCM storage tank,... 

Free surface vortex and air entrainment are not favorable experiences in hydropower and pumping projects. While complete omission of vortex and air entrainment is not always cost effective, partially weakened free-surface vortex flow is more economical and practical. Hence, in this study, a comprehensive set of experiments were conducted to partially reduce vortex strength and air entrainment at vertical pipe intakes, using rectangular anti-vortex plates. This phenomenon results in increasing water discharge compared with a corresponding free-surface vortex for the same water depth, i.e. in cases of shaft spillway. The plates were used as singles and in pairs and placed symmetrically and... 

The study of air-water, two-phase flows in hydraulic structures such as pressurized flow tunnels, culverts, sewer pipes, junctions, and similar conduits is of great importance for design purposes. Air can be provided by vortices at water intakes, pumping stations, aerators, steep channels, etc. Under certain conditions, air may also be introduced into pressurized intake systems, which may form large bubbles in portions of the pipe. The bubbles may, in turn, cause an unstable slug flow, or other flow patterns, that leads to sever periodic transient pressure. In this paper, an experimental model (a circular and transparent pipeline, 90 mm in ID and 10 m in length) is used to predict pressure... 

Incremental launching is a widespread bridge erection technique which may offer many advantages for bridge designers. Since internal forces of deck vary perpetually during construction stages, simulation and modeling of the bridge behavior, for each step of launching, are tedious and time consuming tasks. The problem becomes much more complicated in construction progression. Considering other load cases such as support settlements or temperature effects makes the problem more intricate. Therefore, modeling of construction stages entails a reliable, simple, economical and fast algorithmic solution. In this paper, a new Finite Element (FE) model for study on static behavior of bridges during... 

Introduction: Research evidence indicates that maladaptive reorganization of the brain plays a critical role in amplifying pain experiences and pain chronification; however, no clear evidence of change exists in brain wave activity among patients with chronic low back pain (CLBP). The objective of this study was to assess brain wave activity in patients with CLBP, compared to healthy controls. Methods: Twenty-five patients with CLBP and twenty-four healthy controls participated in the study. A quantitative electroencephalography device was used to assess brain wave activity in eyes-open and eyes-closed (EO and EC) conditions. The regional absolute and relative power of brain waves were... 

Air-water two-phase flow usually occurs during a sudden rise in water level at a tunnel or during the falling of the water level at an upstream reservoir while entering the conduit. When this happens, different flow patterns are generated, due to the hydraulics of flow and fluid properties. An analytical/numerical model, based on the assumption of a rigid incompressible water column and a compressible air bubble, is derived, to simulate pressure fluctuation, void fraction, air/water flow rate and water velocity in a closed conduit, including water depth at the upper reservoir, due to air bubbles becoming trapped in the water, for the highest possible number of flow patterns. It is a... 

Air in water flow is a frequent phenomenon in hydraulic structures. The main reason for air entrainment is vortices at water intakes, pumping stations, tunnel inlets, and so on. The accumulated air, in a conduit, can evolve to a different flow pattern, from stratified to pressurized. Among different patterns, slug is most complex with extreme pressure variations. Due to lack of firm relations between pressure and influential parameters, study of slug flow is very important. Based on an experimental model, pressure fluctuations inside a circular, horizontal, and inclined pipe (90 mm inside diameter and 10 m long) carrying tow-phase air-water slug flow has been studied. Pressure fluctuations... 

A rectangular labyrinth weir has a very good flood release capacity as well as strong economical and structural advantages. In this study, combined analytical and experimental investigations were undertaken for a rectangular labyrinth weir. The analytical model is based on the synthesis of general weir equations and spatially varied flow dynamic equations. A comprehensive set of experiments led to characterisation of the flow behaviour for low and high heads over the weir and indicated the influences of weir geometry on the release capacity. The results show that this type of weir represents an effective weir alternative and could be five times more efficient than a corresponding traditional... 

In the present study, methods for improving the hydraulic performance of labyrinth side weirs in a rectangular channel are reported based on model experimentation. For this purpose different arrangements and configurations of groups of guide vane plates and piles in the side weir flow field were tested. Experiments were conducted on labyrinth side weirs of different lengths and sill heights fitted in the test section of a rectangular glass-walled channel. Depths of flow were measured in both longitudinal and crosswise directions at regular intervals and their profiles were studied. It was found that the discharge coefficient of the labyrinth side weirs under these conditions gave... 

Side weirs are hydraulic control structures widely used in irrigation and drainage systems as well as wastewater treatment plants. These structures also serve as adjusting/diverting flow structures with a minimum head loss. In the present study, by applying experimental data of more than 400 laboratory tests and using the multivariable nonlinear partial least-squares (PLS) method, three nonlinear equations are proposed for discharge coefficient, CM, of triangular and asymmetric labyrinth side weirs. These equations relate the discharge coefficient to the relevant geometrical and hydraulic dimensionless characteristics of flow. Results indicate that the new proposed equations are more... 

A comprehensive set of experiments was performed on weirs placed obliquely in a rectangular open channel. The main objectives were to investigate the effect of the weir angle relative to the approach flow direction on the behaviour and the hydraulic flow characteristics and to examine methods such as using upstream guide vanes and inclined aprons to increase the effective oblique weir length. Results indicate that by increasing the oblique angle, the effective length of the oblique weir increases significantly. Relationships are provided for the threshold submergence and the effective length of the oblique weir. Design recommendations are also presented for the use of guide vanes and...