Sharif Digital Repository

A novel, magnetic nanocarrier was successfully synthesized through a facile and economical producer in which Fe3O4 magnetic nanoparticles were coated by starch-g-poly (methyl methacrylate-co-PEG-acrylamide). The surface of nanocarrier was then modified by hydrazine to preparation of a pH-responsive carrier. The resulted nanocarrier was applied for delivery of doxorubicin (DOX) as an effective anti-cancer drug. DOX was reacted with hydrazine linkage on the surface of nanocarrier to form hydrazone bond. Due to the presence of numerous hydrazine groups on the surface of magnetic nanocarrier large amounts of DOX was loaded onto the carrier (327 mg g−1). © 2016 The Korean Society of Industrial... 

A novel heterogeneous catalyst has been synthesized based on the distillation-precipitation-polymerization of methyl acrylate onto modified magnetic nanoparticles followed by the amidation of the methyl ester groups using N,N-dimethylethylenediamine. The resulting poly(dimethylaminoethyl acrylamide) coated magnetic nanoparticles (MNP@PDMA) catalyst was characterized using an array of sophisticated analytical techniques, including FT-IR, TGA, SEM, TEM, CHN, vibrating sample magnetometer (VSM), and XRD analysis. The resulting heterogeneous base catalyst allowed the performance of a domino Knoevenagel condensation/Michael addition/cycloaddition reaction toward the synthesis of... 

Anchoring of copper sulfate in layered poly(imidazole-imidazolium) coated magnetic nanoparticles provided a highly stable, active, reusable, high loading, and green catalyst for the click synthesis of 1,2,3-triazoles via a one-pot cycloaddition of alkyl halide, azide, and alkyne (Cu-A3C). The catalyst was characterized by FTIR, TGA, TEM, SEM, XRD, EDAX, VSM and AAS. High selectivity, broad diversity of alkyl/benzyl bromide/chloride and alkyl/aryl terminal alkynes, and good to excellent yields of products were obtained using 0.7 mol% catalyst. The catalyst was readily recovered and reused up to 6 times without significant loss of activity  

A heterogeneous magnetic copper catalyst was prepared via anchoring of copper sulfate onto multi-layered poly(2-dimethylaminoethyl acrylamide)-coated magnetic nanoparticles and was characterized using various techniques. The catalyst was found to be active, effective and selective for one-pot three-component reaction of alkyl halide, sodium azide and alkyne, known as copper-catalyzed click synthesis of 1,2,3-triazoles. As little as 0.3 mol% of catalyst was found to be effective under the optimum conditions. The catalyst could also be recycled and reused up to seven times without significant loss of activity. Thermal stability, high loading level of copper on catalyst, broad diversity of... 

A magnetic nanocomposite was prepared by entrapment of Fe3O4 nanoparticles into the cross-linked ionic liquid/epoxy type polymer. The resulting support was used for covalent immobilization of cellulase through the reaction with epoxy groups. The ionic surface of the support improved the adsorption of enzyme, and a large amount of enzyme (106.1 mg/g) was loaded onto the support surface. The effect of the presence of ionic monomer and covalent binding of enzyme was also investigated. The structure of support was characterized by various instruments such as FT-IR, TGA, VSM, XRD, TEM, SEM, and DLS. The activity and stability of immobilized cellulase were investigated in the prepared support. The... 

A heterogeneous tungstate-based catalyst has been prepared for selective oxidation of sulfides to sulfoxides in the presence of 30% H2O2. The catalyst was prepared via immobilization of high amounts of WO4 2− onto the cross-linked poly(ammonium ethyl acrylamide) coated magnetic nanoparticles (MNP). FT-IR, TEM, TGA, VSM, XRD, EDX, and CHN analysis were used for characterization of catalyst. Variety of sulfides successfully converted to the related sulfoxides using 1 mol% of catalyst at room temperature in high yields. The catalyst was easily recovered and reused up to 6 times without loss of activity  

A novel bi-functional polymeric catalyst was synthesized by immobilization of tungstate anions onto the nitrogen rich poly(ionic liquid)/magnetic nanocomposite. The resulting catalyst has two types of catalytic sites: (i) immobilized WO4 anions with bis-imidazolium ionic liquid cation for selective oxidation of alcohols and (ii) basic amine groups for Knoevenagel condensation between produced aldehyde and malononitrile. Due to the polymeric nature of the catalyst, large amounts of tungstate and basic nitrogen groups were presented on the solid surface which led to a decrease in the applied catalyst mass for catalytic reaction. High catalytic activity and excellent selectivity of catalyst in... 

A novel magnetically recoverable catalyst was prepared in which magnetic nanoparticles (MNPs) were functionalized by bis-imidazolium tungstate ionic liquid molecules. The resulting catalyst was highly dispersible in water and selectively oxidized a wide range of alcohols and sulfides using H2O2 as a green oxidant. The catalyst was easily recovered and reused at least 5 times under the described reaction conditions without any significant loss of reactivity  

In this paper, "Subspace" method is generalized to asymmetrical case. In the new algorithm described here, "Lanczos" method is used to find the first subspace and to solve the eigenvalue problem resulted in generalized subspace method. To solve the standard eigenvalue problem developed by "Lanczos" method "Jacoby" method is used. If eigenvalue problem includes damping matrix, that will be imported in new defined mass and stiffness matrices  

Control of unstable non-minimum-phase delayed stochastic processes is a challenging problem. In this work based on the Diophantine equation and using pole-placement technique, a discrete control scheme for such processes has been proposed. Robust stability of the suggested control structure has been shown. Advantages of the proposed scheme over the existing algorithms have been shown through computer simulations. It has been shown that performance of the proposed scheme for handling model mismatch and colored noise is superior to the previous work proposed in the literature  

This article indicates the accurate method for load level calculation to solve the power flow problem when capacitor reactive power is involved. Using the correct method causes some changes in the results and conclusion stated in the discussed paper on optimal reconfiguration and capacitor placement in radial distribution systems  

Purpose - The purpose of this paper is to describe optical flow-based navigation of a very light fixed-wing aircraft in flight between obstacles. Design/methodology/approach - The optical flow information of two cameras mounted on the aircraft is used to detect the obstacle. It is assumed that the image processing has been completed and the optical flow vectors have been obtained beforehand. The optical flow is used to detect the obstacles and make a rapid turn manoeuvre for the aircraft. Findings - It is shown that using the optical flow feedback by itself is unable to give a rapid turn to the aircraft and its rate should be employed into the control law. Six degree-of-freedom flight... 

Capacitor placement/setting is one of the main means for loss reduction and voltage profile improvement in distribution systems. If capacitor placement is meant, the objective function will be the cost of energy losses besides the capacitors costs in a specified period of time. Here, reconfiguration can be used as a strategy to reform the base configuration of the distribution network in order to place the capacitors more efficiently with lower costs. On the other hand, if capacitors are already available in a network, optimum capacitors setting and network reconfiguration should be performed for power loss minimization. In this paper both power loss minimization and capacitor placement cost... 

This paper reports on the diversity of languages displayed in the linguistic landscape of Julfa district, a largely Armenian dominated area, in the city of Isfahan in Iran. The data included a corpus of 323 photographs taken from the top-down and bottom-up signage in this quarter of the city. Ethnographic fieldwork was also conducted to reach a deeper understanding of the linguistic landscape in Julfa. The results of the analyses indicated that Julfa, as home to Armenians in diaspora and also a luxurious neighborhood frequented by more modern strata of the Isfahani society, is occupied more noticeably with Persian and English language and to a lesser extent with Armenian language. The... 

Purpose: The purpose of this paper is to investigate the English for publication purpose practices of doctoral students in Iran. The overall objective was to explore their motives, hurdles and strategies in academic writing. Design/methodology/approach: This case study draws on a narrative inquiry to explore nine science and engineering doctoral students’ perceptions of academic publication. The data were analyzed through a hybrid process of inductive and deductive thematic analysis. Findings: The qualitative results showed three dominant themes, namely: motives for publication, hurdles to publication and strategies for dealing with these challenges were extracted. The main sources of... 

This survey investigated the cultural identity of Iranian English language teachers. Accordingly, a cultural identity model was proposed a priori, based on which a questionnaire was developed and piloted on 50 Iranian English language teachers (α = 0.87). The developed questionnaire was then administered to 636 male and female Iranian English language teachers. The results of confirmatory factor analysis showed that the model was fit and eight components namely 1) religious beliefs, 2) history, 3) customs, 4) manners and behaviors, 5) Persian language, 6) literature and art, 7) parents’ influence and 8) family relations were confirmed to form the core of Iranian cultural identity. The... 

The present mixed-methods research examined the identity and attitude of Iranian English language learners as a result of their participation in an online critical reflective course. The participants were 38 English language students who attended ten online sessions within a five-month English language course. Their online posts underwent inductive qualitative content analysis and subsequently five themes were extracted. In addition, the content of the first and last two sessions were analysed quantitatively. A validated questionnaire was also administered and 18 participants were interviewed. Qualitative and quantitative content analyses of the data revealed eight finalised codes. The...