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Fabrication and characterization of TiO2 deposited black electroless Ni-P solar absorber
, Article Applied Surface Science ; Volume 496 , 2019 ; 01694332 (ISSN) ; Ghorbani, M ; Afshar, A ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Preparing a selective, efficient, and low-cost solar absorber is one of the main challenges in solar to thermal energy conversion. In this paper, black electroless Ni–P (ENi-P) solar absorber has been fabricated, and the effect of nanoporous TiO2 antireflection layer (ARL) on its optical and corrosion properties has been investigated. The optimum black coating was obtained by blackening in 9 M nitric acid solution at 50 °C for 40 s, in which a solar absorptance of 99.3% was achieved. Deposition of TiO2 ARL increased the solar absorptance of coating to 99.7% and addition of 0.8 g Pluronic F127 (F127) as pore former, further increased this value to 99.9% and solar-to-heat efficiency of the...
Improvement of the electrochemical performance of a nickel rich LiNi0.5Co0.2Mn0.3O2 cathode material by reduced graphene oxide/SiO2 nanoparticle double-layer coating
, Article New Journal of Chemistry ; Volume 43, Issue 6 , 2019 , Pages 2766-2775 ; 11440546 (ISSN) ; Paknahad, P ; Ghorbanzadeh, M ; Sharif University of Technology
Royal Society of Chemistry
2019
Abstract
Due to its high discharge capacity, low cost, and good safety, LiNi0.5Co0.2Mn0.3O2 (NCM 523) is regarded as a promising cathode material for the next-generation of lithium-ion batteries. However, poor cycling stability and rate capability are the main disadvantages of the NCM 523 cathode material. In this work, SiO2 single layer-coated and reduced graphene oxide (outer)/SiO2 (inner) double layer-coated NCM 523 have been prepared by a facile wet chemical method. Field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), Raman spectroscopy and Fourier transform infrared (FTIR) spectroscopy results confirm that NCM 523...
Elevated-temperature behaviour of LiNi0.5Co0.2Mn0.3O2 cathode modified with rGO-SiO2 composite coating
, Article Journal of Alloys and Compounds ; Volume 843 , 2020 ; Khalili Azar, M ; Esmaeili, M ; Tanhaei, M ; Dolati, A ; Hosseini H, S. M ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
An intense decrease in cycling performance and safety is a challenge for elevated temperature application of LiNi0.5Co0.2Mn0.3O2 (NCM) cathode material. In this paper, effect of two types of nano-coatings on improvement of elevated temperature performance of NCM cathode material has been investigated. One of the coatings contains SiO2 nanoparticles and the other one contains composite of reduced graphene oxide and SiO2 nanoparticles (rGO-SiO2). The coatings were fabricated by a facile wet chemical method. The SiO2 coated cathode material showed an excellent elevated temperature cycling stability, however, a decrease in discharge capacity and rate capability of this sample was observed. On...
Effect of TiO2 Coating on Efficiency of Black Electroless Ni-P Solar Absorber
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor) ; Afshar, Abdollah (Supervisor)
Abstract
In this thesis Blackening of electroless nickel-phosphorous coating and the effect of TiO2 anti-reflection coating on optical properties of coating was investigated. In the first step, electroless nickel coatings with different amounts of phosphorous on 1050 aluminium substrate deposited. In second step, blackening of coatings by chemical and electroche-mical methods have studied and in final step, effect of TiO2 antireflection coatings with different amount of Pluronic F127 on the optimum black surface and properties of coating investigated. Chemical blackening performed in nitric acid and effect of acid concenteration, Blackening time and temperature studied. optimized condition was...
Electrochemical performance and elevated temperature properties of the TiO2-Coated Li[Ni0.8Co0.1Mn0.1]O2 cathode material for high-safety li-ion batteries
, Article ACS Applied Energy Materials ; Volume 4, Issue 5 , 2021 , Pages 5304-5315 ; 25740962 (ISSN) ; Azar, M. K ; Esmaeili, M ; Malekpour, N ; Hosseini Hosseinabad, S. M ; Moakhar, R. S ; Dolati, A ; Ramakrishna, S ; Sharif University of Technology
American Chemical Society
2021
Abstract
Nowadays, the LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode material has attracted great research interest due to its high energy density and less usage of costly raw materials. However, the high nickel content of NCM811 brings about an extremely unstable interface between the electrode and electrolyte and therefore inferior cyclic stability. Herein, we have proposed a straightforward method to deliver 1, 2, and 4 wt % of TiO2 nanoparticles (NPs) on the surface of the NCM811 cathode material and to improve its properties at room and high temperatures. Based on scanning electron microscopy and transmission electron microscopy observations, the coating thickness varies from 10 to 35 nm and the 2 wt %...
Corrosion-wear behavior of AA1050/mischmetal oxides surface nanocomposite fabricated by friction stir processing
, Article Journal of Alloys and Compounds ; Volume 832 , 2020 ; Razmjoo Khollari, M. A ; Ebadi, M ; Alishavandi, S ; Kokabi, A. H ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
In this study, the wear and corrosion characteristics of six-pass friction stir processed (FSPed) AA1050/mischmetal oxide nanocomposite (6PPA) was compared to six-pass FSPed sample without powder (6 PA) and annealed base metal (BM). Different wear characteristics, such as weight loss, wear rate and coefficient of friction (COF) were studied. In order to evaluate the corrosion resistance of samples, immersion and cyclic polarization tests were performed. In addition, worn and corroded surfaces were investigated by field emission scanning electron microscopy (FESEM). The result of pin on disk dry sliding wear test revealed that wear resistance improved by employing FSP through finer grain...
Enhanced electrochemical performance and thermal stability of ZrO2- And rGO-ZrO2-Coated Li[Ni0.8Co0.1Mn0.1]O2Cathode material for Li-Ion batteries
, Article ACS Applied Energy Materials ; Volume 4, Issue 1 , 2021 , Pages 934-945 ; 25740962 (ISSN) ; Razmjoo Khollari, M. A ; Esmaeili, M ; Heidari, E ; Hosseini Hosseinabad, S. M ; Siavash Moakhar, R ; Dolati, A ; Ramakrishna, S ; Sharif University of Technology
American Chemical Society
2021
Abstract
LiNi0.8Co0.1Mn0.1O2 (NCM811) has been considered as a promising cathode for Li-ion batteries (LIBs) due to its high electrochemical capacity and low cost; however, poor cycling stability is one of the main restricting factors in industrial applications of the NCM811 cathode material. Notably, the capacity fading and low structural stability of NCM811 are intensified at elevated temperatures. ZrO2- and composite rGO-ZrO2-coated NCM811 were fabricated by a facile wet chemical method and evaluated at 25 and 55 °C to overcome these impediments. The ZrO2 coating provides superior cycling and thermal stability and perfectly protects the cathode active material from deleterious side reactions, and...
Theoretical study of high repetition rate short pulse generation with fiber optical parametric amplification [electronic resource]
, Article Journal of Lightwave Technology ; May 2012, Volume 30, Issue 9, PP. 1263-1268 ; Ariaei, A. M ; Jadidi, M. M ; Salehi, J. A ; Sharif Unversity of Technology
Abstract
In this paper, we study theoretically the generation of high repetition rate short pulses using fiber optical parametric amplification. We show that the pulse shape and duration depend on the signal location relatively to the pump frequency. We demonstrate that in order to get the shortest pulse width, the signal must be located at one of the extremities of the gain spectrum associated with the pump peak power. We derive the analytical expression of the pulse shape in this case and compare it to the exponential gain regime case. Using numerical simulations, we also analyze the impact of walk-off and pump phase modulation that is required to suppress Stimulated Brillouin Scattering and derive...
A novel omega shaped microwave absorber with wideband negative refractive index for C-band applications
, Article Optik ; Volume 242 , 2021 ; 00304026 (ISSN) ; Baqir, M. A ; Iftikhar, A ; Ali, M. M ; Rahim, A. A ; Niaz Akhtar, M ; Mughal, M. J ; Naqvi, S. A ; Sharif University of Technology
Elsevier GmbH
2021
Abstract
This paper reports a polarization controllable and angle-insensitive perfect metamaterial absorber (PMA). The proposed PMA consists of periodically arranged asymmetric omega-shaped resonators made of metallic copper. The absorptivity was analyzed considering the microwave C-band from 4 GHz to 8 GHz. The proposed PMA shows an absorption peak with almost 100% absorptivity at 6.2 GHz. Also, wideband negative index of refraction is observed. Further, the absorber is inspected for the different rotation angles of the top metasurface (omega-shaped ring) along the optical axis, and obliquity of incidence angle for both TE and TM polarized waves. Moreover, surface electric field and surface current...
Explicating botanical bactericides as an intervention tool towards citrus canker
, Article Plant Protection ; Volume 8, Issue 1 , 2024 , Pages 25-32 ; 26171279 (ISSN) ; Atiq, M ; Rajput, N. A ; Akram, A ; Arif, A. M ; Kachelo, G. A ; Nawaz, A ; Jahangir, M. M ; Jabbar, A ; Ijaz, A ; Sharif University of Technology
2024
Abstract
Recent research efforts were made to investigate botanical bactericides as an intervention tool for citrus canker. Five botanical extracts (Eruca vesicaria, Eucalyptus globulus, Trigonella foenum-graecum, Nigella sativa, and Citrullus colocynthis) were evaluated at three different concentrations (0.25%, 0.5%, and 0.75%) against Xanthomonas citri pv. citri under in vitro conditions. Among all treatments, two effective plant extracts, alone and in combinations, were assessed at three different time points (7 days, 14 days, 21 days) under greenhouse conditions. In vitro and greenhouse experiments were conducted under a Completely Randomized Design. Results showed that C. colocynthis expressed...
Formal process algebraic modeling, verification, and analysis of an abstract Fuzzy Inference Cloud Service
, Article Journal of Supercomputing ; Vol. 67, issue. 2 , February , 2014 , pp. 345-383 ; Online ISSN: 1573-0484 ; Rahmani, A. M ; Movaghar, A ; Teshnehlab, M
2014
Abstract
In cloud computing, services play key roles. Services are well defined and autonomous components. Nowadays, the demand of using Fuzzy inference as a service is increasing in the domain of complex and critical systems. In such systems, along with the development of the software, the cost of detecting and fixing software defects increases. Therefore, using formal methods, which provide clear, concise, and mathematical interpretation of the system, is crucial for the design of these Fuzzy systems. To obtain this goal, we introduce the Fuzzy Inference Cloud Service (FICS) and propose a novel discipline for formal modeling of the FICS. The FICS provides the service of Fuzzy inference to the...
Impact of holmium on structural, dielectric and magnetic properties of Cu–Zn spinel ferrites synthesized via sol–gel route
, Article Journal of Materials Science: Materials in Electronics ; Volume 32, Issue 2 , 2021 , Pages 2205-2218 ; 09574522 (ISSN) ; Khan, M. A ; Hussain, A ; Akhtar, M. N ; Ahmad, M ; Javid, M. A ; Sharif University of Technology
Springer
2021
Abstract
The mixed nano-ferrites materials Cu0.6Zn0.4HoxFe2−xO4 (0.00 ≤ x ≤ 0.12) were prepared via the sol–gel auto combustion technique. The TGA curve established the annealing temperature (500 °C) for phase formation. The single exothermic peak on the DSC plot occurred at 341 °C temperature. XRD patterns of these nano ferrites verified single phase formation of the FCC cubic structure. The lattice constant a was increased from 8.4244 to 8.4419 Å and then its value decreased to 8.4319 Å. Crystallite size was found in the range of 7 to 16 nm. The surface morphology of the samples was observed from the scanning electron microscope (SEM) images. The grain size was found within the range of 90 nm to...
Impact of holmium on structural, dielectric and magnetic properties of Cu–Zn spinel ferrites synthesized via sol–gel route
, Article Journal of Materials Science: Materials in Electronics ; Volume 32, Issue 2 , 2021 , Pages 2205-2218 ; 09574522 (ISSN) ; Khan, M. A ; Hussain, A ; Akhtar, M. N ; Ahmad, M ; Javid, M. A ; Sharif University of Technology
Springer
2021
Abstract
The mixed nano-ferrites materials Cu0.6Zn0.4HoxFe2−xO4 (0.00 ≤ x ≤ 0.12) were prepared via the sol–gel auto combustion technique. The TGA curve established the annealing temperature (500 °C) for phase formation. The single exothermic peak on the DSC plot occurred at 341 °C temperature. XRD patterns of these nano ferrites verified single phase formation of the FCC cubic structure. The lattice constant a was increased from 8.4244 to 8.4419 Å and then its value decreased to 8.4319 Å. Crystallite size was found in the range of 7 to 16 nm. The surface morphology of the samples was observed from the scanning electron microscope (SEM) images. The grain size was found within the range of 90 nm to...
An experimental study on mechanical behavior of a calcite cemented gravelly sand
, Article Geotechnical Testing Journal ; Volume 41, Issue 3 , May , 2018 , Pages 494-507 ; 01496115 (ISSN) ; Haeri, S. M ; Shahrabi, M. M ; Khosravi, A ; Sajadi, A. A ; Sharif University of Technology
ASTM International
2018
Abstract
In the study presented herein, a simple method for laboratory calcite cementation of a reconstituted gravelly sand was presented. This method was used to prepare cemented gravelly sand specimens, which have similar natural characteristics to alluvial deposit of the city of Tehran. The formation and distribution of calcite bonds, as well as the effectiveness of the presented calcite cementation method in increasing interparticle cohesion, as observed in weakly to moderately cemented soil in Tehran, were evaluated by means of chemical analysis, X-ray diffraction technique, and unconfined compressive strength tests. The cementation technique was used to prepare triaxial specimens with calcite...
A new dynamic optimal m2m rf interface setting in relay selection algorithm (dorsa) for iot applications
, Article IEEE Access ; Volume 10 , 2022 , Pages 5327-5342 ; 21693536 (ISSN) ; Hemmatyar, A. M. A ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2022
Abstract
Machine-to-Machine (M2M) communication is an important type of communication in the Internet-of-Things (IoT). How to send data in these high-density communications using relay selection can help improve the performance of this type of communication in various applications. In addition, the possibility of simultaneous use of different Radio Frequency (RF) interfaces helps to use the spectrum more efficiently. In this work, we try to further use machine communication RF equipment and improve the average data rate of networks in some applications such as the IoT, which have their own bandwidth requirements. Therefore, we provide an optimization algorithm for relay selection as well as the...
P-V-L Deep: A big data analytics solution for now-casting in monetary policy
, Article Journal of Information Technology Management ; Volume 12, Issue 4 , 2021 , Pages 22-62 ; 20085893 (ISSN) ; Kazemi, M. A ; Alborzi, M ; Azar, A ; Kermanshah, A ; Sharif University of Technology
University of Tehran
2021
Abstract
The development of new technologies has confronted the entire domain of science and industry with issues of big data's scalability as well as its integration with the purpose of forecasting analytics in its life cycle. In predictive analytics, the forecast of near-future and recent past - or in other words, the now-casting - is the continuous study of real-time events and constantly updated where it considers eventuality. So, it is necessary to consider the highly data-driven technologies and to use new methods of analysis, like machine learning and visualization tools, with the ability of interaction and connection to different data resources with varieties of data regarding the type of big...
Spray characteristics and atomization behavior of bio-diesel (Norouzak) and diesel fuel blends
, Article Particulate Science and Technology ; 2016 , Pages 1-12 ; 02726351 (ISSN) ; Jafari, M ; Ahari, M ; Saidi, M. H ; Hajinezhad, A ; Mozaffari, A. A ; Sharif University of Technology
Taylor and Francis Inc
2016
Abstract
Norouzak oil seeds that are the source of bio-diesel (Norouzak) fuel grow mostly in Gonabad and Kashmar located in Khorasan, north east of Iran. Spray characteristics of Norouzak bio-diesel have been experimentally and theoretically studied in this work. Norouzak fuel is added to the conventional diesel fuel, and mixture formations of several blends have been investigated and compared with each other. Moreover, by varying ambient and injection conditions, behaviors of spray of different blends have been explored. Microscopic and macroscopic properties of spray such as Sauter Mean Diameter (SMD), Ohnesorge number, spray tip penetration, spray cone angle, spray projected area and volume have...
Spray characteristics and atomization behavior of bio-diesel (Norouzak) and diesel fuel blends
, Article Particulate Science and Technology ; Volume 36, Issue 3 , 2018 , Pages 270-281 ; 02726351 (ISSN) ; Jafari, M ; Ahari, M ; Saidi, M. H ; Hajinezhad, A ; Mozaffari, A. A ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
Norouzak oil seeds that are the source of bio-diesel (Norouzak) fuel grow mostly in Gonabad and Kashmar located in Khorasan, north east of Iran. Spray characteristics of Norouzak bio-diesel have been experimentally and theoretically studied in this work. Norouzak fuel is added to the conventional diesel fuel, and mixture formations of several blends have been investigated and compared with each other. Moreover, by varying ambient and injection conditions, behaviors of spray of different blends have been explored. Microscopic and macroscopic properties of spray such as Sauter Mean Diameter (SMD), Ohnesorge number, spray tip penetration, spray cone angle, spray projected area and volume have...
Experimental and theoretical investigations on spray characteristics of bio-ethanol blends using a direct injection system
, Article Scientia Iranica ; Volume 24, Issue 1 , 2017 , Pages 237-248 ; 10263098 (ISSN) ; Jafari, M ; Ahari, M ; Saidi, M. H ; Hajinezhad, A ; Mozafari, A. A ; Sharif University of Technology
Sharif University of Technology
2017
Abstract
In the present work, the spray characteristics of bio-ethanol and its blends have been experimentally and theoretically investigated. To have a comprehensive study, the effects of ambient condition and injection pressure on the spray of different blends have been considered. Macroscopic and microscopic characteristics of spray such as tip penetration length, cone angle, projected area, volume, Sauter Mean Diameter (SMD), and Ohnesorge number are investigated precisely. Besides, air entrainment and atomization analyses have been carried out to improve mixture formation process. Using curve fitting and least squares method, theoretical correlations have been suggested in such a way to predict...
Sustainable process design for heat exchanger network considering inherent safety and process economics
, Article Canadian Journal of Chemical Engineering ; Volume 102, Issue 7 , 2024 , Pages 2481-2494 ; 00084034 (ISSN) ; Shariff, A. M ; Rashid, M. I ; Aadil, M. A ; Umer, A ; Irfan, M ; Sharif University of Technology
2024
Abstract
Process lifecycle has several stages, including process design covered in multiple stages. Process economics is a vital factor in finalizing the process design. Besides economics, inherent safety is an important concept contributing to sustainable process design generation. The inherent safety concept has been applied via equipment characteristics for individual equipment. Since a method considering inherent safety with equipment aspects and process economics has not been available, therefore, a new method has been proposed, namely sustainable process design for heat exchanger network (SPDHEN), to integrate inherent safety, equipment aspects, and process economics. SPDHEN uses indexing to...