Sharif Digital Repository

CO2 as a green house gas plays a significant role in the global warming and weather changes. Absorption by means of amine solutions is the main industrial technique for separating of CO2 from gas mixtures. Hazards associated with high temperature during solvent recovery, large size of equipment, corrosion, solvent degradation, and other reasons has made researchers to look for alternative processes such as adsorption. The aim of this study was to synthesis and modify the nano adsorbent for CO2 capture. To fulfill this purpose, various nano silica structures were synthesized and the amount of adsorption of each sample was determined. To investigate the performance capability nano_adsorbents,... 

Oil/water separation is an important field, not only for scientific research, but also for environmental, economic, and social issues. On the one hand, oily wastewater, resulting from industries such as steel, aluminum, food, textile, leather, petrochemical and metal finishing, has become the most common pollutant all over the world. On the other hand, frequent oil spill accidents are of great concern since the discharge can lead not only to serious environmental pollution, but also a great loss of energy.
In crude oil removing water is necessary due to reducing corrosion, increasing thermal values of fuels obtained from crude oil, preventing catalists from destruction by water and... 

Optimization of energy consumption is generally important in mobile networks and in particular in automotive networks. One of the challenges of installing roadside units in automotive case networks is to provide energy to the equipment assigned to these units. In some cases, power is easily available, but in many places, the cost of energy is very high and does not have economic justification. Therefore, optimization of energy consumption in roadside unit is of great importance. Typically, vehicles limitations in terms of energy consumption for communications are far lower than that of a roadside unit. In this dissertation, part of roadside communication to vehicles is shifted to the... 

In this study, the performance of electrocoalescence in a microfluidic device was investigated through numerical simulations. The microfluidic device consisted of two immiscible fluids, a continuous phase, and a dispersed phase, which were modeled as incompressible Newtonian fluids. The interface between the two phases was tracked using a phase-field model. A flow-focusing geometry was employed to crate water droplets in oil. The dispersed droplets were then pass over a set of electrodes. The merging of two adjacent droplets in the microfluidic device was observed by applying a constant electric field. The voltage of 60 V is the lowest voltage at which the regular merging of pairs of drops... 

Selective oxidation of H2S to elemental sulfur in a fixed bed reactor over seven nanocatalysts has been investigated and compared to commercial claus catalyst. Among them, Al2O3-supported sodium oxide nanocatalyst prepared with wet chemical technique and Al2O3 nanocatalyst prepared with spray pyrolysis method were the most active catalysts for selective oxidation of H2S to elemental sulfur. The remaining nanocatalysts were deactivated, mainly due to the interaction with H2S and conversion into sulfides. For synthesis of Al2O3 with spray pyrolysis method we use statistical design of experiments (box-behnken design) in order to screen the effects of significant synthesizing parameters  

Macroeconomic fluctuations have a serious impact on household welfare. In natural resource exporting countries - and in particular oil countries - the main source of macroeconomic fluctuations is oil revenue fluctuations, and as a result, preventing oil revenue fluctuations from decreasing has an important role in reducing macroeconomic fluctuations and household welfare. One of the ways in which oil revenue fluctuations enter the economy is through the budget. The lack of a proper fiscal rule in spending natural resource revenues in the budget has a great impact on economic instability. In this study, the current situation, which is in the form of a percentage division of oil revenues... 

In this study, the influence of multi wall carbon nanotube on the thermal properties and microstructure of open cell flexible polyurethane (PU) foam was investigated. To do this untreated CNT (named here n-CNT) along with three different highly functionalized CNTs having carboxyl, hydroxyl and amide functional groups, abbreviated here by CNT-COOH, CNT-OH and CNT-NH-COR, respectively, were employed. A series of PU foam with and without CNTs (both treated and untreated ones) were prepared by cast molding. Prior molding, the CNTs (0.1 wt% loading) were first dispersed into the polyol (Mw = 3000 g/mol and OH No. 56) and then the mixture was subsequently added to the isocynate (TDI). The SEM... 

Delay-tolerant networks refer to the networks that lack stable end-to-end paths due to the high mobility of nodes. In order to tackle the intermittent connections, nodes of delay-tolerant networks store the data packets and carry them. Nodes forward data packets according to routing protocols once they enter each other's communication range. In order to increase the probability of delivery, several or many copies of a packet can be disseminated in the network. Over the past years, various routing protocols have been proposed for delay-tolerant networks. These protocols differ from each other in the number of copies that are disseminated in the network or the information used to make routing... 

In this research a novel palladium nanocatalyst was synthesized over single-wall carbon nanotube (SWNT) support and then applied in the selective hydrogenation of acetylene in an ethylene rich-flow stream. This nanocatalyst displayed a very promising selectivity toward ethylene production upon rising of the temperature, as well as suppressing oligomer formation during acetylene hydrogenation. It was rationalized that the overwhelming governing mechanism for the acetylene hydrogenation over the 0.48 wt% Pd/SWNT was the hydrogen transfer. Furthermore, new operating conditions for selective hydrogenation of acetylene in ethylene rich-flow were introduced through which the selective... 

The major obstacle in using natural gas as a clean and abundant fuel in transportation industries is the low density of energy obtained from its combustion. Adsorbed Natural Gas (ANG) is a useful method to increase the energy density and store the natural gas. The lower cost and higher safety have made it different from the other storage technologies. In addition, ANG can be useful to solve the lack of gas in the peak of consumption. Among all adsorbents, Activated Carbon (AC) has shown the highest adsorption capacity of natural gas. In the present project, walnut shell has been used as the precursor in the chemical synthesise of AC. The main effective factors in chemical activation, such as... 

Financial distress can propagate through different channels such as bank run, deposit interbank market,networks and asset prices. In this paper, with the assumption of deposit insurance, no linkages between banks, no deposit interbank market and fixed asset prices, we show that asset-side shocks might propagate through both loan interbank market and deposit market. However, when there is aggregate liquidity surplus in the banking system, loan interbank market results in the first best allocation. In contrast, aggregate liquidity shortage does not result in optimum allocation. In the presence of deposit and loan interbank market, not only shocks propagate but also they are magnified with the... 

In various fields of engineering sciences, SUT occupies the highest rank among other technical universities in Iran based on the ranking of Islamic World Science Citation Center (ISC) in 2013. It is, therefore, the host of the majority of exceptionally talented engineering students. In this respect, students of SUT are expected to perform considerably well in their future academic and vocational careers. The primary aim of this investigation is to shed light on a more appropriate course syllabus customized to the needs of these gifted students. A triangulation approach to data collection was employed to gain more insights into the study. A five-point Likert scale questionnaire was... 

A series of V2O5 catalysts supported on multiwall carbon nanotube (MWCNT), single wall carbon nanotube (SWCNT) and graphene were synthesized by hydrothermal and reflux methods for oxidative dehydrogenation of propane (ODHP) to propylene. The catalysts were characterized by techniques including the BET surface area measurements, XRD, FTIR, H2-TPR, NH3-TPD, FESEM and UV-vis diffuse reflectance. The performance of the catalysts and the supports were subsequently examined in a fixed bed reactor. The vanadium catalyst supported on graphene with C/V molar ratio of 1:1 synthesized through the hydrothermal method had the best performance under the reactor test conditions of 450°C, feed C3H8/Air... 

Access to the data of Tap30, a ride-hailing company in Iran, has allowed us to estimate the demand elasticity of online taxis. As Tap30 divides Tehran into 256 regions for pricing from Jan to June 2018, we assumed that unobservable consumer characteristics near borders are the same for adjacent regions. We used the Regression Discontinuity method to compare ride requests of people who live on two sides of borders and estimated the demand elasticity of Tap30. This research concludes that by 10 percent increase in price, the demand decreases about 3.5 percent on average in 1 hour time period. On the other hand, in 6 hours time period, the demand decreases about 7.5 percent on average by 10... 

There is a need for renewable energy sources to be more feasible. The purpose of this project is to develop a compact device that is able to harvest wind energy and transform it into electrical energy using the concept of vortex shedding. When calibrated correctly, the vortex shedding will induce resonant oscillation. Electricity would be collected from this oscillation using a magnet and coil assembly. This method was proven to work in water, but has not been applied to air currents. Our group designed and built a small-scale prototype to be tested in closed circuit wind tunnel. The wind harvester works at a moderate wind range of 3 to 5 m/s. Data was collected on the amplitude and... 

Due to the potential risk of sulfur compounds in fossil fuels and according to today’s regulations, sulfur content should be kept as low as possible, e.g., below 5 ppm. Mercaptans are one of the sulfur components in natural gas. Scope of this research defined as catalytic removal of ethyl mercaptan from the gas stream. For this purpose, two microreactor systems placed in series. In the first microreactor, catalytic decomposition of ethyl mercaptan has been investigated. In the first step of this survey, a microreactor with 24 microchannels with a newly designed distributor has been developed with a computational fluid dynamic technique. in comparison to the conventional triangular... 

Dominance over the seismic behavior of structures leads to proper design and the cost reduction of structures according to the structures demand performance. In this regard, the issue of performance-based seismic design of structures has been proposed in which the nonlinear behavior of structures is the basis for the design and evaluation of structures during earthquakes. Moreover, regarding of soil under the structures will change the elastic and inelastic behavior of structures; also, the effects of soil-structure interaction on the seismic performance of structures should be considered to achieve the real behavior of structures. Hence, the purpose of this study is to evaluate the... 

Nitrogen injection is a promising enhanced oil recovery process. Asphaltene precipitation during miscible gas injection is a common problem in oilfields throughout the world. In this work, a comprehensive study is conducted on effect of gas injection on phase behavior and asphaltene instability of live oil samples. Effects of oil API, gas type and concentration, pressure and temperature are studied under natural depletion and nitrogen injection processes by means of high pressure filtration and a photographic procedure coupled with image analysis. Filtration results show that nitrogen destabilizes asphaltenes more compared to methane and the problem is more severe for heavier crude samples....