Sharif Digital Repository

The high production costs of pure platinum electrodes, considered the gold standard for hydrogen evolution reactions, have made the development of compositionally graded coatings a notable solution. This study focuses on the electrochemical fabrication of compositionally graded Co-Pt coatings using the potential step method, with steps at -900 mV, -645 mV, and -450 mV, each applied for 450 s. To optimize the electrolyte bath, two separate baths containing cobalt (II) sulfamate and hexachloroplatinic acid were examined: one with 0.016 M Co²⁺ and another with 10 mM Pt⁴⁺, in the presence of boric acid and sodium saccharin. The baths underwent electrochemical tests, including LSV, CV, and... 

Tsunami, like many other natural disasters leaves people a short time for escape. When talking about Tsunami, the escape time is the period it takes for the wave to start moving from the epicenter, change into a giant wave gradually and reach to a cost. In order to minimize damages of this phenomenon, the escaped time has to be estimated without delay. For this purpose the first needed action is modeling the Tsunami waves. Analytical and numerical models and software that are designed based on them do exist. To have an efficient and rapid Tsunami alarming system all of these options are examined in this project. Then having a reliable model quite a few probable scenarios are propounded. The... 

In the present work, the integration of production scheduling and process control in a multi-product CSTR reactor is addressed. In order to reduce the complexity of solving this integrated problem, in the scheduling layer, a reduced closed-loop model, named scale bridging model, based on neural network concept is used. In the control layer, a neural network-based controller is used to achieve control objectives such as tracking, stability and robustness against model uncertainty. In addition, the designed closed loop system is used to obtain offline setpoint-output data set in order to train neural network based scale bridging model. In a comparative study, both simultaneous and sequential... 

When swellable elastomer are surrounded by suitable fluid, they absorb the fluid and swell. This capability is used to design different tools. For example, drug release devises, sensors and actuators, in microfluidic devises such as micro-valves and micro-mixers, and seal devises. Most of these devises are shaped cylindrically. Therefore, have a thorough knowledge about how cylindrical swellable elastomer behavior, give us a good vision about how to design such actuators. In this thesis we have used constitutive equation of such materials and have investigated behavior of cylindrical swellable elastomers analytically and numerically. Analytical investigation is focused of transient behavior... 

Knowledge was traditionally understood as a one-sided foundation for all political action and, consequently, for political power. Since the late nineteenth century, however, it has been argued that political power and action also influence knowledge—and it was even suggested that power is, in fact, the sole factor shaping knowledge. Prominent advocates of this idea, such as Michel Foucault and Friedrich Nietzsche—whose thoughts profoundly influenced Foucault—employed the method of genealogy to examine historical case studies in an attempt to substantiate this claim. Yet, a critical examination of their arguments reveals that genealogy cannot support such a universal assertion. Hence, it is... 

Full numerical methods are usually used for the analysis of periodic structures such as photonic crystals and diffraction gratings. The main drawback of these methods is that they are time-consuming and thus are not appropriate for the design process. In this thesis, approximate and fast methods, based on transmission line models, for the analysis of periodic structures are proposed. To this end, in the first part of the thesis, we investigate one-dimensionally periodic metallic gratings. Longitudinally homogenous metallic gratings, enhanced reflection phenomenon and longitudinally inhomogenous metallic gratings are examined, and simple, and efficient transmission line models for these cases... 

Potential of plasmonic waveguide structures to confine light in sub-wavelength scales attracted many attentions in recent years. Among these structures planar metal-insulator-metal waveguide and plasmonic slot waveguide are more promising. That is because of their easy fabrication process along with their various reported applications. However, there are some obstacles in the path of developing plasmonic integrated circuits, among whichhigh propagation loss can be named as the most important. To solve this issue, photonic waveguides can be used as the lossless interconnections between small footprint plasmonic components on optical chips. Therefore, application of plasmonic slot waveguide... 

The existing transmission line models of plasmonic nanostructures are modified in this thesis to study the electromagnetic characteristics of nano-plasmonic structures in a more efficeint yet accurate enough fashion. First, rectangular plasmonic cavities made by carving dielectric rectangles within a metallic region are modeled by trasnmission lines of finite length being appropriately terminated at their both ends. The resonance conditon in the proposed model yeilds the resonance frequencies, quality factors, and mode profiles of its correspondig plasmonic resonator. The accuracy of the proposed model is assessed by using the fully numerical finite-difference time-domain method (FDTD)... 

In this thesis an approximate method is proposed for analysis of two dimensional photonic crystal waveguides. In this method an equivalent impedance is assigned to photonic crystal regions and the waveguide region is modeled with a transmission line. Waveguide’s loss is also analysed and computed by this method. In other words the proposed method is able to determine the complex propagation constant of guided modes without computing any complex roots for dispersion equation. Although like any other approximate method, the accuracy of this method is dependent to some special conditions but it’s advantage over other numerical methods is its simplicity and its capability for waveguide designs.... 

The existing transmission line models of plasmonic nanostructures are modified in this thesis to study the electromagnetic characteristics of nano-plasmonic structures in a more efficeint yet accurate enough fashion. First, rectangular plasmonic cavities made by carving dielectric rectangles within a metallic region are modeled by trasnmission lines of finite length being appropriately terminated at their both ends. The resonance conditon in the proposed model yeilds the resonance frequencies, quality factors, and mode profiles of its correspondig plasmonic resonator. The accuracy of the proposed model is assessed by using the fully numerical finite-difference time-domain method (FDTD)... 

Ring and disk resonator are studied in this thesis. First, the complex resonance frequencies of two-dimensional homogeneous ring and disk resonators are extracted by following the standard approach and then a novel method is proposed to extract the complex eigen-frequencies of two-dimensional inhomogeneous ring and disk resonators. The inhomogeneity of the refractive index is arbitrary along the radial direction. The proposed method is shown to be more efficient than the standard approach based on the stair-case approximation. It is therefore appropriate for resonator design and is thus employed for systematic study of the opposing trends of geometrical parameters in maximization of... 

Due to the growing need for plasmonic wavs in microwave and terahertz spectra, a periodic arrangement of one-dimensional cut-through slits is investigated and an equivalent model based on the effective medium theory is derived. In contrast to the all previous attempts that were successful in mimicking only the zeroth-order diffracted waves, the proposed effective medium is capable of mimicking all diffraction orders. The parameters of the equivalent model are established by comparing the scattered waves of the semi-homogeneous medium and those of the main structure obtained by invoking the rigorous mode matching approach based on the single mode approximation inside the slits. This medium is... 

Thus far numerous components and devices have been designed and realized based on plasmonics. Hereon, we focus on PlasMOStor which is probably the first and most important CMOS compatible plasmonic modulator. It resembles to its electronic counterpart MOS transistor in geometry, unless, it has a plasmonic waveguide instead of the regular channel to modulate optical signals . By applying voltage to the gate and inset of charge carrier accumulation, optical properties of the channel changes and plasMOStor turns off. In this thesis, we carry out a through investigation of plasMOStor’s operation. We show that the proposed theoretical description of plasMOStor is fallacious. Subsequently,... 

Semi-analytical solutions for the nonlinear, one dimensional wave equation have been investigated. The aim of this procedure is to deliver fast and yet accurate approaches for solving the abovementioned equasions. These solutions make a good alternative for full-numerical methods, which are usually time consuming and combersome. Therefore the proposed methods may find complete priority, considering design goals. Lack of a fast numerical method for solving the nonlinear, steady state cases, make the proposed approaches relevant, dealing theses problems. By employing the presented methods, It is possible to effieciently simulate the behavior of the space-wave packet, incident on the nonlinear... 

In this thesis, equations governing the pulse propagation in fiber optics are investigated and methods for numerical solution of these equations are modified or extended to more general cases. First, the extraction of these equations from Maxwell's equations is explained and then the numerical methods are discussed. For extracting the equations, we assume the fiber medium as a longitudinally inhomogeneous medium, so the coupling between the forward and backward waves is taken into account. In addition, the effect of birefringence in fiber is included in the analysis and its modeling as a stochastic process is explained in detail. Two numerical methods based on operator splitting technique... 

In this thesis, while a comprehensive study of different methods for the characterization of the optical fibers is done, a unique and effective method is being introduced for the characterization of the dispersion coefficient of Highly Nonlinear Fibers (HNLFs). The proposed method is based on the Brillouin Optical Time Domain Analysis (BOTDA) of a wave generated by the Four Wave Mixing (FWM) interaction. The current method, which includes an experimental scheme and an algorithm for solving the inverse problem, offers high sensitivity and experimental accuracy at the longitudinal resolution of 1 meter. The noise level has been considerably reduced by understanding different sources of the... 

This dissertation accounts hydrodynamic coefficients for the hull form of Dolphine Craft using an Experimental-Numerical method. First, a short preface is mentionded about Dolphine craft and its charcterstics. Then, different methods for determining the hydrodynamic coeeficient are reviewed and the method used in this dissertation is introduced. After that, the selected methods will numerically be modeled. For accurate modeling, virtual labarotory is organizing for performing these tests During modeling, six degree freedom equation including the kinematic and Dynamics of body element are extractred and consequently, they are expressed for the rigid body and control volume of fluid. The...