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Facile, Efficient and Low Cost Synthesis of N-(1H-imidazoline-2-yl)-1H-Benzimidazol-2-Amine and its Derivatives
, M.Sc. Thesis Sharif University of Technology ; Mahmoodi Hashemi, Mohammed (Supervisor)
Abstract
Benzimidazoles are a bioactive family of chemicals which had been subject of many studies because of their valuable properties, and has a long history of production in chemical industries. Investigation on their properties and reactions with goal of achieving to new derivatives have drawn attention of many research teams. Recently, 2- Imidazolineaminobenzimidazole had been synthesized by microwave-assisted reaction of 2-Aminobenzimidazole with 2-Methylsulfanylimidazoline hydrogen iodide. But because of difficulties aroused by use of microwave system and expensive chemicals, we decided to utilized reaction procedures which could be facile, inexpensive with capability of high reaction scales....
Mass distribution management & dynamic balancing of aircraft mass
, Article Aircraft Design ; Volume 4, Issue 1 , 2001 , Pages 51-61 ; 13698869 (ISSN) ; Soltan Mohammed, B ; Sharif University of Technology
2001
Abstract
A new methodology has been proposed to control the distribution of mass in an aircraft during the design and development process. Having estimated the total mass, the aircraft is considered to be composed of different segments each with an unknown mass and the equations of motion are derived based on this discritized mass model. A suitable mass distribution is then found based on the desired dynamic and static stability criterion. Using this methodology the aircraft static margin can be controlled by changing the external shape (Xac) as well as mass distribution (Xcg). By relating all applicable mass moments of inertia to the frequencies and damping ratios of longitudinal and...
Synthesis and Application of Acidic and Hydrophobic Ionic Liquids in Mannich Reaction and Esterification of Fatty Acids
, M.Sc. Thesis Sharif University of Technology ; Mahmoodi Hashemi, Mohammed (Supervisor)
Abstract
The current study deals with application of a surfactant-like Brønsted acidic ionic liquid (IL) 1-dodecyl-3-methylimidazolium hydrogensulfate (catalys 1) for Mannich reaction at room temperature. The reaction has been efficiently proceeds in water as solvent without using any harmful and expensive organic additives. Our observation has been shown that the reaction is selective for cyclohexanone and no product was observed by using cyclopentanone at room temperature. Density functional theory (DFT) calculations were performed to provide evidence about the nature of reactivity of the cyclohexanone/cyclopentanone. The activity of the catalyst 2 (1-dodecyl-2,3-dimethylimidazolium...
Comparative analysis of the power output capabilities of grid-following and grid-forming inverters considering static, dynamic, and thermal limitations
, Article IEEE Transactions on Power Systems ; Volume 39, Issue 2 , 2024 , Pages 2693-2705 ; 08858950 (ISSN) ; Zhou, W ; Mohammed, N ; Bahrani, B ; Sharif University of Technology
IEEE
2024
Abstract
This article investigates the maximum transferable power (MTP) of inverter-based resources (IBRs) and provides the output capability curves (OCCs) of grid-tied grid-following inverters (GFLIs) and grid-forming inverters (GFMIs). To this end, in the first part of the article, mathematical equations for GFLI static, thermal, and phase-locked loop (PLL)-induced power transfer limits are derived in terms of the grid short-circuit ratio (SCR) and its X/R ratio. Then, considering other operational limitations, such as the IBR AC- and DC-side voltage limits, the OCC of the GFLI is obtained. Additionally, the impact of the reactive current and the reactive control mode on the OCC is further studied,...
Enhanced frequency control for power-synchronized pll-less grid-following inverters
, Article IEEE Open Journal of the Industrial Electronics Society ; Volume 4 , 2023 , Pages 189-204 ; 26441284 (ISSN) ; Ravanji, M. H ; Zhou, W ; Bahrani, B ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2023
Abstract
This article presents an enhanced power-synchronized grid-following inverter (ePSGFLI) for reliable and stable integration of renewable energy resources into the grid. By eliminating the use of a phase-locked loop (PLL) in the control loop, the ePSGFLI resolves instability issues commonly associated with conventional PLL-based grid-following inverters (GFLIs). Furthermore, in contrast to existing PLL-less strategies like linear parameter-varying control of power-synchronized GFLI (LPV-PSGFLI), which suffer from steady-state errors and instability during grid frequency deviations, the proposed ePSGFLI ensures stable performance without steady-state errors, regardless of the strength of the...
Rapid admittance measurement of power converters using Double-PLL grid-following inverters
, Article IEEE Transactions on Power Delivery ; Volume 39, Issue 3 , 2024 , Pages 1407-1419 ; 08858977 (ISSN) ; Ravanji, M. H ; Mohammed, N ; Bahrani, B ; Sharif University of Technology
2024
Abstract
The increasing use of inverter-based resources (IBRs) in power systems highlights the need for a deep understanding of their stability and dynamics. Traditional analytical models, limited by the black-box nature of IBRs, underscore the importance of frequency-domain methods through measured admittance. Facing challenges in real-world admittance measurement, such as the absence of ideal voltage or current sources, the use of measurement inverters as perturbation sources has emerged as a promising approach, despite drawbacks like reduced system stability and increased measurement time. This article introduces a novel control strategy for measurement inverters, elucidating the impact of abc/dq...
Density Functional Theory Study on Interactions between Hydroxyurea as an Anticancer Drug and Tyrosyl Radical
, M.Sc. Thesis Sharif University of Technology ; Fattahi, Alireza (Supervisor) ; Mahmoodi Hashemi, Mohammed (Supervisor)
Abstract
Quantum calculation based on the density functional theory (DFT) level and 6-311++G (d,p) basis set was employed to study the relation between the structure and radical scavenging activity of a series of hydroxybenzohydroxamic acid derivatives, namely: [HU]; hyroxyurea, [TX]; 3,4,5-trihydroxybenzamidoxime, [DX]; 3,4-dihydroxybenzohydroxamic acid, [4-HBA]; 4-hydroxybenzohydroxamic acid, [2,3-DHBA]; 2,3-Dihydroxybenzohydroxamic acid, [3,5-DHBA]; 3,5-Dihydroxybenzohydroxamic acid and [2-HBA]; 2-hydroxybenzohydroxamic acid in the gas phase, water and benzene environments. The hydrogen bond property of the studied structures and their radicals as well as radical cations was investigated using...
Experimental investigation on mechanical characterization of Epoxy-E-Glass fiber-particulate reinforced hybrid composites
, Article ACS Omega ; Volume 9, Issue 23 , 2024 , Pages 24761-24773 ; 24701343 (ISSN) ; Badruddin, I.A ; Shaik, A.S ; Kamangar, S ; Khan, A.A ; Sharif University of Technology
2024
Abstract
The present investigation focuses on the manufacturing and mechanical evaluation of epoxy-based composites reinforced with fiberglass with and without various particle fillers. The study explores the potential use of industrial wastes, such as coal powder (CP), coal fly ash (CFA), bagasse ash (BA), palm fruit ash (PFA), ash from rice husks (RHA), bone ash (BoA), marble/granite powder (MP), combinations of coal fly ash and coal powder (CFACP), blends of coal fly ash and marble powder (CFAMP), and combinations of coal fly ash and bone ash (CFABoA).The use of industrial factory wastes as a filler in polymer composite materials is becoming more and more common due to the improvement in...
Predicting the environmental economic dispatch problem for reducing waste nonrenewable materials via an innovative constraint multi-objective Chimp Optimization Algorithm
, Article Journal of Cleaner Production ; Volume 365 , 2022 ; 09596526 (ISSN) ; Ren, H ; Habibi, M ; Mohammed, K. J ; Khadimallah, M. A ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
The usage of conventional fossil fuels has aided fast economic growth while also having negative consequences, such as increased global warming and the destruction of the ecosystem. This paper proposes a novel swarm-based metaheuristic method called Chimp Optimization Algorithm (ChOA) to tackle the environmental, economic dispatch issue and reducing the waste nonrenewable materials. In this regard, two objective functions named fuel cost function and emission cost function are proposed. Unique constrained handling also solves the challenge of multi-objective optimization. Standard IEEE 30 bus with six generators and a 10-unit system are used to demonstrate the usefulness of ChOA. The result...
Study of Some Effective Parameters on Uv Curable Coating Containing Nano Silver
, M.Sc. Thesis Sharif University of Technology ; Mahmoodi Hashemi, Mohammed (Supervisor) ; Bastani, Saeed (Co-Advisor)
Abstract
Antibacterial coatings are a branch of paints and coatings industry that has a wide application from Clothing and Textiles to Floor and Medical instrument. Different antibacterial agents such as silver, titanium dioxide, zinc oxide, gold, chitosan, Silicon dioxide, Magnesium hydroxide and carbon nanotubes have been used. UV curable coatings are economic and environmentally friendly coatings and they are one of the fastest growing segments in the paint and coatings industry. Many studies have been conducted on UV curable coatings and their properties. Among different resins, The UV curable polyurethane offer properties such as: Excellent hardness, High gloss, good chemical and weather...
A review of using solar energy for cooling systems: applications, challenges, and effects
, Article Energies ; Volume 16, Issue 24 , 2023 ; 19961073 (ISSN) ; Eleiwi, M. A ; Mohammed, H. I ; Ameen, A ; Ahmad, S ; Sharif University of Technology
Multidisciplinary Digital Publishing Institute (MDPI)
2023
Abstract
Energy security refers to a country’s capacity to provide the energy resources essential to its wellbeing, including a reliable supply at an affordable costs. Economic growth and development cannot occur without access to reliable energy sources. Energy availability is a proxy for a country’s standard of living and a key factor in its economic development and technical progress. Solar power is the most reliable and cost-effective option when it comes to meeting the world’s energy needs. Solar-powered cooling systems are one example of how solar energy may be used in the real world. Solar-powered air conditioners have become more popular in recent years. The problems caused by our reliance on...
, M.Sc. Thesis Sharif University of Technology ; Mahmoodi Hashemi, Mohammed (Supervisor) ; Rajab Zade, Ghadir (Supervisor)
Abstract
TiO2/SiO2/HPAsnanocompositeswas prepared by the sol-gel technique at room tempareture and used as the heterogeneous catalysts for the acylation of alcohols employing acetic anhydrid under solvent-free conditions at room tempareture. It was found that the catalytic activity of TiO2/SiO2/HPAs, in all cases of HPAs, was much higher than that of TiO2/SiO2. The most catalytic activity was obtained by TiO2/SiO2/H14NaP5W30O110 which completed the acylation reaction of benzyl alcohol at 1h. Examining the various concentrations of H14NaP5W30O110 in the composite, 9% w/w concentration of TiO2/SiO2/HPAs showed maximum catalytic activity, and by increasing the HPA concentration, activity remains...
The Use of Dithiocarbamate and Rhodanines For The Synthesis Of Sulfur-Containing Heterocyclic Compounds
, M.Sc. Thesis Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor) ; Mahmoodi Hashemi, Mohammed (Supervisor)
Abstract
Nowadays, heterocycle compounds containing sulfur have become very important in various industries, especially the pharmaceutical industry; Therefore, these two projects aim to provide better and more efficient ways to synthesize these types of compounds. In the first project, we developed an efficient one-pot, four-component procedure for the synthesis of 2,6-diamino-4-Aryl-4H-Thiopyran-3,5-dicarbonitrile derivatives via a reaction between primary amines, carbon disulfide, malononitrile, and benzylidenemalononitrile in the presence of magnetic NH2.MIL-101(Fe)/ED as a basic metal-organic framework catalyst. Magnetic NH2.MIL-101(Fe)/ED was synthesized through anchoring FeCl3 on CoFe2O4...
Investigation of the Reaction of Dithiocarbamic Acid Salts with Carbonyl Compounds (Ketones and Aldehydes), Epoxides and Ortho Esters
, M.Sc. Thesis Sharif University of Technology ; Mahmoodi Hashemi, Mohammed (Supervisor) ; Ziyaei Halimehjani, Azim (Co-Advisor)
Abstract
In the first section, for the first time, a reaction of dithiocarbamic acid salts with carbonyl compounds has been investigated in the presence of BF3.OEt2. The reaction is temperature dependent meaning that the reaction gives two different products at low and high temperatures. At 15-20 0C, the 2-iminium-1,3-dithietane is the main product.As the reaction temperature goes up, formation of gem-bis(dithiocarbamates) is dominant.In addition, deprotection of gem-bis(dithiocarbamates) was investigated by using of nitric acid as the only deprotecting agent. The structure of a 2-iminium-1,3-dithietane was confirmed by X-ray crystallographic analysis.
In the second and third sections, in our aim...
In the second and third sections, in our aim...
Rosa Damascena mediated ZnO-Red Ochre nanocomposite for the electrochemical determination of 5-Fluorouracil
, Article Arabian Journal of Chemistry ; Volume 16, Issue 4 , 2023 ; 18785352 (ISSN) ; Khayatkashani, M ; Soltani, N ; Mohammed, H. T ; Tavakkoli, N ; Jafari, M ; Salavati Niasari, M ; Sharif University of Technology
Elsevier B.V
2023
Abstract
In this study, ZnO-Red Ochre nanocomposite was green synthesized by Rosa Damascena (RD) extract (RDZRONCs). Proton Induced X-ray Emission microanalysis (Micro-PIXE) and X-ray diffraction (XRD) pattern confirmed the presence of hematite (Fe2O3), and quartz (SiO2) mineral phases in the Red Ochre (RO) nanoclay. In addition, the XRD pattern shows the ZnO, ZnFe2O4, SiO2, Fe2O3, and Si phases in the RDZRONCs that were green synthesized with natural RD extract and RO. The RDZRONCs were used to modify the carbon paste electrode (CPE) for the electrochemical determination of the anticancer drug 5-fluorouracil (5-FU). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques...
Red mud catalyzed one-pot synthesis of nitriles from aldehydes and hydroxylamine hydrochloride under microwave irradiation
, Article Arkivoc ; Volume 2007, Issue 15 , 2007 , Pages 162-170 ; 1551-7012 (ISSN) ; Azimi, N ; Mohammed Vali, M ; Eftekhari Sis, B ; Hashemi, M. M ; Baniasadi, M. H ; Teimouri, F ; Sharif University of Technology
Arkat
2007
Abstract
Red mud (RM) which emerges as a by-product from the alumina producing process has been used as an efficient catalyst for one-pot direct synthesis of nitrile compounds from aldehydes and hydroxylamine hydrochloride under microwave irradiation. ©ARKAT USA, Inc
Recent advances and developments of the application of hybrid nanofluids in parabolic solar collector energy systems and guidelines for future prospects
, Article Journal of Engineering Research (Kuwait) ; 2024 ; 23071877 (ISSN) ; Aljibori, H. S ; Mohammed, H. I ; Ameen, A ; Ahmad, S ; Ben Hamida, M. B ; Al-Rubaye, A. H ; Sharif University of Technology
2024
Abstract
This study addresses challenges in enhancing the thermal efficiency of parabolic solar collector energy systems using hybrid nanofluids, focusing on issues like nanoparticle clumping and decreased effectiveness. The objective is to optimize design parameters for improved energy absorption and efficiency by evaluating the thermal performance of hybrid nanofluids through theoretical and experimental analyses, aiming to enhance the overall efficiency of solar collector systems. The thermal performance of solar collector systems was evaluated by conducting numerical simulations and experimental analyses to investigate the effects of various nanoparticle compositions and concentrations. The...
Network vulnerability analysis through vulnerability take-grant model (VTG)
, Article 7th International Conference on Information and Communications Security, ICICS 2005, Beijing, 10 December 2005 through 13 December 2005 ; Volume 3783 LNCS , 2005 , Pages 256-268 ; 03029743 (ISSN); 3540309349 (ISBN); 9783540309345 (ISBN) ; Sadoddin, R ; Jalili, R ; Zakeri, R ; Omidian, A. R ; Sharif University of Technology
2005
Abstract
Modeling and analysis of information system vulnerabilities helps us to predict possible attacks to networks using the network configuration and vulnerabilities information. As a fact, exploiting most of vulnerabilities result in access rights alteration. In this paper, we propose a new vulnerability analysis method based on the Take-Grant protection model. We extend the initial Take-Grant model to address the notion of vulnerabilities and introduce the vulnerabilities rewriting rules to specify how the protection state of the system can be changed by exploiting vulnerabilities. Our analysis is based on a bounded polynomial algorithm, which generates the closure of the Take-Grant graph...
Sequence dependence of the binding energy in chaperone-driven polymer translocation through a nanopore
, Article Physical Review E - Statistical, Nonlinear, and Soft Matter Physics ; Volume 83, Issue 1 , January , 2011 ; 15393755 (ISSN) ; Ejtehadi, M. R ; Metzler, R ; Sharif University of Technology
2011
Abstract
We study the translocation of stiff polymers through a nanopore, driven by the chemical-potential gradient exerted by binding proteins (chaperones) on the trans side of the pore. Bound chaperones prevent backsliding through the pore and, therefore, partially rectify the polymer passage. We show that the sequence of chain monomers with different binding affinity for the chaperones significantly affects the translocation dynamics. In particular, we investigate the effect of the nearest-neighbor adjacency probability of the two monomer types. Depending on the magnitude of the involved binding energies, the translocation speed may either increase or decrease with the adjacency probability. We...
First passage time distribution of chaperone driven polymer translocation through a nanopore: Homopolymer and heteropolymer cases
, Article Journal of Chemical Physics ; Volume 135, Issue 24 , 2011 ; 00219606 (ISSN) ; Metzler, R ; Ejtehadi, M. R ; Sharif University of Technology
2011
Abstract
Combining the advection-diffusion equation approach with Monte Carlo simulations we study chaperone driven polymer translocation of a stiff polymer through a nanopore. We demonstrate that the probability density function of first passage times across the pore depends solely on the Péclet number, a dimensionless parameter comparing drift strength and diffusivity. Moreover it is shown that the characteristic exponent in the power-law dependence of the translocation time on the chain length, a function of the chaperone-polymer binding energy, the chaperone concentration, and the chain length, is also effectively determined by the Péclet number. We investigate the effect of the chaperone size on...