Sharif Digital Repository

This paper presents the results of an analytical study on the dynamic characteristics of the Shaking Table facilities at Sharif University. This 3 degree of freedom shaking table is driven by 3 servo-control hydraulic actuators, and consists of a 12 ton, 4m×4m×0.6m steel deck. The main objective of this investigation is to identify the degree of flexibility of the deck, and its adverse effects in causing errors in the simulation of seismic effects on different structural specimens. Many frame specimens of different weights and configurations are subjected to seismic motions, and their responses are calculated using FE models. Some of these models were designed to account for eccentric... 

A novel magnetic heterogeneous copper catalyst was synthesized by immobilization of copper ions onto triazole functionalized Fe3O4. The catalyst was fully characterized by FT-IR, TGA, CHN, SEM, TEM, EDX and atomic adsorption spectroscopy. The resulting catalyst was used in the synthesis of 1,2,3-triazoles via a one-pot three component reaction of alkynes, alkyl halides, sodium azides under green conditions. The catalyst was reused ten times and no significant loss of activity was observed  

In this study, high-vanadium austenitic manganese steel (HV-AMS) alloys and the standard Hadfield steel were investigated. The microstructure of these high-vanadium alloyed Hadfield steels was studied thoroughly using optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction (XRD) and was compared to the Hadfield steel. The hardness and unnotched Charpy impact strength of HV-AMS alloys and Hadfield steel were examined at ambient temperature in the as-cast and heat-treated conditions. A pin-on-disk wear test at linear speed of 10. m/min and a 55. N normal load was employed to evaluate the wear behavior of both steel samples. Microstructural results showed that varying... 

Predicting the effective elastic properties of carbon nanotube-reinforced nanocomposites is of great interest to many structural designers and engineers for improving material and configuration design in recent years. In this paper, a finite element model of a CNT composite has been developed using the Representative volume element (RVE) to evaluate the effective material properties of nanocomposites. Based on this model, the effects of geometrical characteristics such as the aspect ratio, orientation and volume fraction of the CNTs in conjunction with the interphase behavior on the mechanical properties of the nanocomposites are elucidated and the elastic properties of a complex polymeric... 

Inkjet-printing (IJP) technology is recognized as a significant breakthrough in manufacturing high-performance electrochemical energy storage systems. In comparison to conventional fabrication protocols, this printing technique offers various advantages, such as contact-less high-resolution patterning capability; low-cost, controlled material deposition; process simplicity; and compatibility with a variety of substrates. Due to these outstanding merits, significant research efforts have been devoted to utilizing IJP technology in developing electrochemical energy storage devices, particularly in supercapacitors (SCs). These attempts have focused on fabricating the key components of SCs,... 

Sport video shot classification is a basic step in the sport video processing. For many purposes such as event detection and summarization, shot classification is needed for content filtering. In this paper, we present a new method for soccer video shot classification. At first, in-field and out-of-field frames are separated. In in-field frames three features based on number of connected components and shirt color percent in vertical and horizontal strips are extracted. The features are all new and showed excellent discrimination in the feature space. These features are given to SVM for classifying long, medium and close-up shots. One of the advantages of our method is that, close-ups can be... 

The focus of the paper is on cross-layer transmission based on rateless coding for relay networks. In the proposed method, rateless coding is used at the packet level and a separate physical layer coding is used at the physical layer. As rateless codes are originally designed and optimized for erasure channels, using these codes at the physical layer can lead to significant performance degradation. The proposed scheme has the advantage of a cross-layer design which uses a rateless code at the packet level modeled by an erasure channel. Based on the analysis and simulation results provided in this paper, the cross-layer scheme results in earlier successful decoding at the destination  

In nuclear reactor core design, achieving the optimized arrangement of fuel assemblies (FAs) is the most important step towards satisfying safety and economic requirements. In most studies, nuclear fuel optimizations have been performed by using a finite number of different types of FAs. However the effect of FA numbers with different enrichments and the difference between their maximum and minimum enrichment values can be important and should be evaluated in the optimization process. This research is aimed at evaluating the effect of using different enrichment values for FAs. This issue has been investigated by focusing on two parameters, namely, the initially selected enrichment and the... 

4-hydroxycoumarin 2a and 4-hydroxy-6-methyl-pyran-2-one 2b were applied in a one-pot reaction with Baylis-Hillman adduct acetates 1 to form novel 3-benzylpyrano [3, 2-c] pyran-2, 5-diones 3 in high yields (70-85%). The synthesized framework is available in many biologically active moieties. The reaction was carried out under different conditions to achieve optimum conditions. The results indicated that Et3N, as a base under solvent-free conditions, was optimum. The reaction procedure and purification method are mild and straightforward  

In this investigation, in-situ precipitation of vanadium carbides was employed to reinforce Fe-13Mn and Fe-13Mn-3W alloys by means of conventional melting and casting route. Microstructures were characterized by optical and scanning electron microscopy techniques.Mechanical properties of the materials were determined by hardness, impact toughness and tension tests. It was observed that tungsten improved the strength of the matrix and the reinforcements as well as tensile properties and work hardening rate of the VC-reinforced composite. Ball mill abrasion test was utilized to simulate impact-abrasion wear condition using two types of abrasive minerals. The results showed that the degree of... 

4-hydroxyquinolinones 7 were applied as 1,3-dinucleophiles in the reaction with Baylis-Hillman adduct acetates 6 to synthesize, in high yields of 75-92%, novel 2H-pyrano[3,2-c]quinoline-2,5(6H)-diones which are present in a number of biologically active compounds. The reaction was carried out under different conditions to achieve the optimum ones. The results indicated that acetonitrile as solvent and K2CO3 as base, under reflux conditions, were the optimum conditions. The reaction times are short and the experimental procedure is straightforward  

The accuracy of static neutronic parameters in the nuclear reactors depends upon the determination of group constants of the diffusion equation in the desired geometry. Although several methods have been proposed for calculating these parameters, there is still the need for more reliable methods. In this paper a powerful and innovative method based on Spatial Homogenization and Temperature Variation (SHTV) of physical properties of a WWER-1000 nuclear reactor core for calculating the relative power distribution of Fuel Assemblies (FA) and the hot fuel rod, is presented. The method is based on replacing the heterogeneous lattices of materials with different properties by an equivalent... 

The first example of a heterogeneous catalytically active system for Buchwald–Hartwig and Ullmann homocoupling of unactivated aryl halides (fluorobenzene) is presented. The novel magnetic heterogeneous palladium catalyst was synthesized by immobilization of palladium ions onto an aminopyridine-functionalized Fe3O4. The catalyst was fully characterized by FTIR spectroscopy, temperature-programmed reduction, thermogravimetric analysis, CHN elemental analysis, transmission electron microscopy, field-emission scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, and atomic absorption spectroscopy. By using this catalyst system, various types of primary and... 

A new heterogeneous and highly dispersive nanocatalyst in water was prepared by the immobilization of Cu2+ onto glucose on Fe3O4. The catalyst was fully characterized by FT-IR, TGA, CHN, SEM, EDX, and atomic absorption spectroscopy. The synthesized catalyst was used in the synthesis of different derivatives of 1,2,3-triazole via a one-pot three-component reaction of alkynes, alkyl halides, and sodium azide. To the best of our knowledge, this novel catalyst adheres to the principles of green chemistry. The nanocatalyst could be recycled and reused in several runs without significant loss of activity  

Herein, we demonstrate a facile low temperature approach to prepare a gel polymer electrolyte (GPE) based on the triiodide/iodide redox couple in a quasi-solid-state dye-sensitized solar cell (DSSC). Only one polymeric agent (i.e., hydroxypropyl cellulose (HPC)) is used for the preparation of a non-volatile GPE system for the standard liquid electrolyte containing 1-methyl-3-propylimidazolium iodide (MPII). The prepared GPE completely penetrates into a TiO2 photoanode at room temperature due to the uniform distribution of Ti, Ru and I elements in the cross-section of the electrode, forming an interpenetrating GPE/TiO2 network to access all dye molecules. The GPE with the optimum HPC : MPII... 

This paper addresses a bi-level mixed-integer nonlinear programming (MINLP) model for the competitive facility location problem in a closed-loop supply chain (CLSC), in which a firm (i.e., leader) aims at entering a market by locating new distribution and collection facilities, where a competitor (i.e., follower) already exists. The goal is to find the location and attractiveness of each facility going to be established by the leader who seeks to maximize its profit while also taking the follower's response into account. The attractiveness of each facility is a function of integer variables related to the facility's characteristics. Customer behavior is considered to be probabilistic based... 

Abstract: We report robust green synthesis of novel 1,2,3-triazole-based sulfonamides bearing different motifs such as fluorine under click conditions in presence of a copper-based magnetically recoverable and reusable heterogeneous nanocatalyst. The organocopper catalyst at 0.5 mol.% was highly recyclable (up to five times) when recovered using an external magnet without significant loss in catalytic activity. The mild reaction conditions and excellent yields (69–95 %) make this protocol an attractive method for efficient synthesis of the title compounds. The structure of product 3a was determined by Röntgen crystal structure analysis. Graphical Abstract: [Figure not available: see... 

Perchloric acid immobilized on silica gel (SiO2-HClO4) has been utilized as a mild and cheap reagent for onepot preparation of different varieties of flavylium salts via tandem reaction of different acetophenones with Salicylaldehydes under solvent-free conditions. Different reaction conditions such as conventional heating and microwave irradiation have been investigated. The corresponding flavylium salts have been prepared in high yields. The procedure is milder and more convenient than the known procedures  

This study seeks a method for formulating directional strategy of wind turbine industry in Iran. To this end, by initially evaluating various economic viewpoints concerning the development of industries, the necessity of government intervention is recognized. By defining the concepts of national industry policy, firm technology strategy, and national technology strategy, the role of directional industry strategy is then made clear. Furthermore, the six assumptions of emphasis on formulating strategy (rather than on formulating policy), emphasis on formulating directional strategy, model's prescriptivism, emphasis on formulating the strategy at the level of industry, Iran's being a developing... 

A novel heterogeneous copper catalyst was synthesized in which poly(1-vinyl imidazole-co-ionic liquid) was used as a solid heterogeneous support. The catalyst was readily synthesized in a large scale amount. The catalyst has a high loading level of copper ions and can be used in low weight percentages. The resulting catalyst was highly active in the preparation of triazoles by the Huisgen 1,3-dipolar cycloaddition method. In some cases the catalytic turnover number and frequency reached 70 002 and 3889 h-1, respectively. The catalyst was recycled many times without significant loss of activity. This journal is