Sharif Digital Repository

This thesis contains four chapters. In first chapter the role of water in organic reactions as a ecofriendly solvent, computational chemistry and dynamic nuclear magnetic resonance were studied. In the second chapter synthesis of new 4-hydroxy pyrrole derivatives in water were reported. For the synthesis of these compounds arylglyoxal derivatives, 1,3-dicarbonyl compounds and ammonium acetate were used. The reaction conditions are very mild. The third chapter contains the synthesis of new (4 or 5)-Aryl-2-aryloeil-(1H)-imidazole compounds in aqueous media. We also investigated the tauto-isomerisation of isomeric imidazoles during this reaction using DNMR technique. In forth chapter a... 

This thesis contains two parts .In the first part a catalyst such as AlCl3/Al20 has been demonstrated to catalyze Michael addition reaction of amines to a,�- unsaturated compounds with high yields , short reaction time and under solvent-free condition.The Michael addition to a,�- unsaturated compounds produces quantitively the mono addition products.The next part is about olefins epoxidation . Alkene epoxidation is a useful reaction in organic synthesis. Epoxides play an important role in industrial intermediates for the production of fine chemicals as well as pharmaceuticals .The hydrogen peroxide has been used as an oxidant because it is considered as an economical and appropriate reagent... 

Enanthioselective synthesis of biological molecules are so important in synthetic chemistry, and because of their biological activities, β-amino carbonyl compounds have earned so much attention in this area of chemistry. Mannich reaction is a classical method for synthesis of these molecules. The Mannich reaction is a three-component reaction between an enolizable CH-acidic carbonyl compound, an amine, and an aldehyde producing β-amino carbonyl compounds. But acidic or basic difficult circumstances, long reaction time, low yield and enantioselectivity, are the drawbacks of classical methods. In this project, we used titania-based solid acid as an enantioselective catalyst to overcome these... 

The study of the religious experience is always one of the most important topics in researches related to the religion field. Religious and mystical experiences have always been one of the key religious concepts. The religious experience, like other human experiences, always comes with reactions in the human brain. Study of the religious experience from a neuroscience perspective can help us to answer questions and issues in the field of religious experience and cognitive credit of it. Assessment of what happens in the people’s brain during rituals like meditation or deep concentration provides a good window into understanding of what this means for people, being mystical or religious or... 

In this research, piezocatalysts ceramics Bi4Ti3-xMnxO12 (x=0,0.1,0.2,0.3) were synthesized by hydrothermal method and utilized in the process of rhodamine B piezocatalytic degradation.These piezocatalysts were characterized using XRD, FE-SEM, FT-IR, DRS and PL methods. The results of XRD patterns confirmed the formation of orthorhombic crystal structure of Bi4Ti2.9Mn0.1O12 and Bi4Ti3O12 piezocatalysts. FT-IR spectroscopy confirmed the existence of chemical bonds of piezocatalysts. FE-SEM images showed the formation of Bi4Ti2.9Mn0.1O12 and Bi4Ti3O12 nanoplates. Using DRS analysis data, the absorption edge wavelength and energy gap of the synthesized piezocatalysts were obtained. Also, the... 

In the first stage of this research, different amounts of glycidoxypropyltrimethoxysilane (GPS) were grafted as a coupling agent on the surface of nanosilica particles (NS). Surface characterization was done by Particle Size Analyzer and Thermal Gravimetric Analyzer (TGA) and that way, samples were distinguished from each other. More comparisons were taken by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). Then the different amounts of modified NS were added into the matrix of an epoxy resin and the physical and mechanical properties of samples were tested with Abrasion Resistance test, Tensile Strength test, Thermal Mechanical Analysis (TMA),... 

Purification of waste water containing metal ions, is one of major environmental problems which have threaten human’s life, other creatures and even agricultural products by means of polluting suberranean water. Copper ion is one of dangerous heavy metals that exists in potable water and agricultural uses, due to serious problems in health of humans and aquatic. In recent years, different methods for purification of waste water containing heavy metal ions have been published. Right now, thorough these methods such as: filtration, coagulation, precipitation and adsorption are being used, which have their own advantages and disadvantages.In this research, new method for purification of waste... 

This project investigates on synthesis of β-amino carbonyl compounds with new approach to become closer to green chemistry principals.In this project, we investigated the synthesis of β-amino carbonyl compounds with aromatic amines and electron deficient alkenes in the Michael reaction using boric acid and glycerol in water as a green media. High yields of the products and easy handling are some advantages of this procedure. Also, we investigated the Michael reaction in different solvents and temperatures but gave better results in the aqueous media. Moreover, thiomorpholine derivatives were synthesized using this method to give excellent yield.
 

Dithiocarbamates are a group of compounds that nowadays have been used extensively in pharmaceutical agents, organicsynthesis and as fungicides in agriculture.We haveshown, an efficient. regiospecific method for the synthesis of cyclic dithiocarbamates by one-pot three-component cascade reaction of an amine, CS2 and α,β-unsaturated aldehyde via Michael addition/hemiamination reaction in watre under a mild and green procedure with excellent yields and complete regioselectivity