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lotfi-varnoosfaderani--mohammad
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Carbon Dioxide Recovery From Flue Gases by Means of Appropriate Absorbents
, M.Sc. Thesis Sharif University of Technology ; Molaei Dehkordi, Asghar (Supervisor)
Abstract
Due to the increasing concentration of greenhouse gases in the earth's atmosphere and their destructive consequences, many scientists and researchers have turned to preventing the emission of greenhouse gases, such as carbon dioxide. One of the primary sources of carbon dioxide emissions is flue gases. Carbon dioxide is one of the most important greenhouse gases, the release of which causes global temperature increase and climate change. One of the options for reducing carbon dioxide emissions from gas streams is using reactive amine solvents, considered the most critical technologies for carbon dioxide removal. The only commercially available carbon dioxide separation method is absorption...
Electrodeposition of Zn-Ni Alloy Nanometer Multilayer
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Electrodeposion of Zn-Ni Alloy Nanometer Multilayer has been studied. The investigations show that Multilayer coatings have more corrosion resistance than a Monolayer. The electrodeposition of the multilayer coatings was performed with the single bath technique. The sulfate-borate bath has been used for electrodeposition of the Multilayer coatings. The switching cathode density current has been used for the multilayer coatings in cathode current densities of 20, 30, 40, and 50 mA.cm-2. The number of layers with constant overall thickness of 2 µm was 20, 40, 80, and 100. The composition of layers varied between 5-11% wt Ni with the values of cathode current densities. The Response Surface...
Design and Implementation of an Intelligent Agent for Automatic Configuration of Content Delivery Servers
, M.Sc. Thesis Sharif University of Technology ; Fazli, Mohammad Amin (Supervisor)
Abstract
Content delivery networks play a significant role in improving the quality of internet services by placing the necessary content closer to users on servers. Currently, over half of internet traffic is delivered through these networks to end users. The efficiency of a content delivery network depends on various parameters, including the type of requested content, workload distribution methods, network topology, routing algorithms, caching policies, network server configurations, and resource allocation (shared or dedicated hardware resources). Additionally, the requests made to a content delivery network vary based on the type of service and even the time of day, making optimization a...
Sustainable ammonia production from steam reforming of biomass-derived glycerol in a heat-integrated intensified process: Modeling and feasibility study
, Article Journal of Cleaner Production ; Volume 324 , 2021 ; 09596526 (ISSN) ; Lotfi Varnoosfaderani, M ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
Currently, ammonia, as a clean and sustainable energy carrier, is intensively synthesized from its elements during the Haber-Bosch technology. This process requires a large amount of energy and emits numerous amounts of carbon dioxide, because hydrogen is dominantly produced from fossil fuels through reforming processes. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to intensify a heat-integrated process for the co-production of ammonia and syngas from glycerol valorization. In this process, glycerol reforming continuously provides hydrogen...
Use of biomass-derived glycerol as an alternative to fossil fuels for aniline production: Energy saving and environmental aspects
, Article Fuel ; Volume 310 , 2022 ; 00162361 (ISSN) ; Lotfi-Varnoosfaderani, M ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Catalytic reduction of nitrobenzene is the leading technological step in aniline production. The hydrogen required for this stage, is dominantly produced from fossil fuels through reforming processes, which take much energy and emit large amounts of CO2. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming to reduce the dependence on hydrocarbon resources and mitigate climate change. This research aims to analyze a mass- and heat-integrated multi-tubular membrane reactor, containing nitrobenzene hydrogenation (exothermic-side) and glycerol steam reforming (endothermic-side) for co-production of aniline and syngas. In this process, hydrogenation...
Design, Manufacture and Control of a Fluidic Thrust Vectoring System in Small Scale
, M.Sc. Thesis Sharif University of Technology ; Saghafi, Fariborz (Supervisor)
Abstract
Thrust vector control as a method toward increasing of the aircrafts’ maneuverability and expanding the flight envelope into poor aerodynamic conditions, is considered a major field of academic and industrial appeal. Older methods based upon an approach of utilizing a mechanical instrument, impose quite a large amount of cost onto the design, prototyping and operation of the aircraft, even though they lead to improve in maneuverability. Having taken these setbacks into account, to simplify the manufacturing process and to reduce the thrust losses due to mechanical control of the thrust vector, the direction of research was set toward realizing and employing the flow control procedures. In...
Capacity of Memory Quantum Channels
, M.Sc. Thesis Sharif University of Technology ; Karimipour, Vahid (Supervisor)
Abstract
One of the most important problems of quantum information theory is to try to determine the channel capacity of noisy quantum channels. Alice would like to send Bob information over many uses of a noisy quantum communication link. As the line is usually noisy, this cannot be done perfectly, and so they must use suitable coding methods to minimize the error. Different coding methods yield different rates of information transition and different errors, the channel capacity is defined as the maximum rate at which information may be transferred with vanishing error in the limit of a large number of channel uses. There are a variety of different capacities, depending upon whether Alice and Bob...
Catalytic conversion of bio-renewable glycerol to pure hydrogen and syngas: Energy management and mitigation of environmental pollution
, Article Energy Conversion and Management ; Volume 247 , 2021 ; 01968904 (ISSN) ; Lotfi Varnoosfaderani, M ; Moghadasin, M. H ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
Hydrogen and syngas, as two effective clean fuels, have a considerable stake in the global fuel market. These are dominantly produced from fossil fuels through reforming processes, which lose a large amount of energy and emit numerous amounts of CO2. Bio-renewable glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to manage a heat-integrated reactor with three concentric cylinders, containing exothermic-side (methane tri-reforming), endothermic-side (glycerol steam reforming), and permeation-side for co-production of pure hydrogen and syngas. In this process,...
Model Development for the Evaluation of Hydrogen Storage Capacity in Hybrid Nanostructures
, Ph.D. Dissertation Sharif University of Technology ; Saboohi, Yadollah (Supervisor) ; Ghofrani, Mohammad Bagher (Supervisor)
Abstract
In the present work storage of hydrogen molecules in hybrid nanostructures has been evaluated. Hybrid nanostructures consist of carbon structure bases which have been doped by metal atoms. Carbon structures used in this thesis include graphene and metal organic frameworks (MOFs). Carbon structures have superior properties such as very low density, while metal atoms are considered to enhance the interactions and increase the hydrogen storage capacity. In the first step of the work, Monte Carlo method was applied to model the system. To develop the Monte Carlo method for hydrogen adsorption on graphene sheets, Feynman-Hibbs corrections were added to Lennard-Jones potential. However in the next...
Design of Globally Convergent Observers for Robotic Systems
,
M.Sc. Thesis
Sharif University of Technology
;
Namvar, Mehrzad
(Supervisor)
;
Mobed, Mohammad
(Supervisor)
Abstract
In a typical rigid robot manipulator, joint angels and velocities are often considered as system states. Joint angels are usually measured by precise Shaft Encoders. However, lack of velocity measurement sensors “Tachometers” and their undesired characteristics in most of existing robotic systems make it difficult to have access to full system states. As full access to the system states in various applications is inevitable, velocity observers can be used to reconstruct or estimate the unmeasured velocity signals. This thesis presents an observer for global estimation of joint velocities in robot manipulators. A non-minimal model of a robotic manipulator is introduced to design an...
Value Creation in Content-oriented E-business
, M.Sc. Thesis Sharif University of Technology ; Miremadi, Iman (Supervisor) ; Ghafoori, Mohammad Hossein (Co-Supervisor)
Abstract
Considering the high growth potential of creative industry as well as the increasing trend of e-business, content-oriented digital business has been the main focus of this research. These enterprises are a subset of the creative industry that are primarily developed in the digital context. After reviewing the literature, it was observed that the keyword "value creation" in this type of business has been less considered by research.On the other hand, in conversations with managers who are active in the industry, a practical vacuum was revealed on how to create value in these firms; Because a comprehensive review of value creation processes in these firms can ultimately lead to more profitable...
Design, Processing and Characterization of Radially Graded Porous Structure for Dental Implant
, M.Sc. Thesis Sharif University of Technology ; Farahmand, Farzam (Supervisor) ; Movahedi, Mohammad Reza (Supervisor)
Abstract
Functionally graded porous structures are very close to the bone tissue. Parameters that are related to the pore size and other parameters that determine mechanical properties, can closely represent properties of bone tissue. These parameters contain the percentage of the porosity and the pore size on the porosity side, and modulus of elasticity and yield stress from mechanical view. Calibrated structures with complex geometries, containing porous material, also can be produced by 3D printing technology. One application of porous structures is in production of dental implant with a cylindrical shape, containing a dense core, surrounded by a porous region. The aim of the present study is to...
Quantum Correlations of Two Qubit Systems
, Ph.D. Dissertation Sharif University of Technology ; Karimipour, Vahid (Supervisor) ; Memarzadeh Esfahani, Laleh (Co-Advisor)
Abstract
Composite quantum systems are generally correlated and these correlations may have classical or quantum nature. Entanglement is only a special type of quantum correlations and separable states may be quantum correlated. Quantum discord, local quantum uncertainty and the rank of the correlation matrix are the most important measures of quantum correlations beyond entanglement. Regarding the various applications of discordant separable states in the field of quantum information, the important problem is how to produce discordant separable states and what is the resource which should be used for this preparation. In this thesis we present a method of preparation for such states in two qubit...
Preparation of Nanofluid by Using Hybrid Nanostructures and Investigation of Thermal and Rheological Properties and Using it in the Petroleum Fluids
, M.Sc. Thesis Sharif University of Technology ; Rashtchian , Davood (Supervisor) ; Rashidi, Alimorad (Supervisor) ; Lotfi, Roghayeh (Co-Advisor)
Abstract
In this study, thermal and rheological properties of nanofluids of water/carbon nanotubes, water/spherical silica nanoparticles and water/hybrid nanoparticles (hybrid of carbon nanotubes and spherical silica nanoparticles) have been investigated. To do so, carbon nanotubes have been synthesized by CCVD process and spherical silica nanoparticles and hybrid nanoparticles by wet chemical method. After synthesis of nanomaterials, nanofluids have been prepared by using SDBS as a dispersant with the concentration of 1.5 times of concentration of nanomaterials and then thermal conductivity, kinematic viscosity, dynamic viscosity and density of nanofluids have been investigated. As the results show,...
Effect of metal doping, boron substitution and functional groups on hydrogen adsorption of MOF-5: A DFT-D study
, Article Computational and Theoretical Chemistry ; Vol. 1044, issue , 2014 , Pages 36-43 ; ISSN: 2210271X ; Saboohi, Y ; Sharif University of Technology
2014
Abstract
In the present work, adsorption of hydrogen molecules over a metal organic framework (MOF-5) has been investigated by using first principles density functional theory (DFT). Different strategies have been applied for improving hydrogen storage, i.e. metal doping, boron substitution and functionalization. The metal atoms used for enhancing hydrogen adsorption include Li, Ca and Sc. It is found that the binding energy between these metal atoms and MOF is not enough to prevent clustering. Therefore a number of carbon atoms are substituted by boron atoms and it is indicated that boron substitution enhances the binding energies, significantly. Also the results reveal that boron substituted MOF...
Interaction of hydrogen molecules with perfect, defective and scandium doped polycyclic aromatic hydrocarbon structures
, Article Computational and Theoretical Chemistry ; Volume 1026 , 2013 , Pages 65-71 ; ISSN: 2210271X ; Saboohi, Y ; Sharif University of Technology
2013
Abstract
In the present work the interaction of hydrogen molecules with perfect, defective and scandium doped polycyclic aromatic hydrocarbon (PAH) has been evaluated. At first the potential barrier for the penetration of hydrogen molecules through PAH structures has been investigated and then the adsorption of hydrogen molecules over PAH structures has been studied. To model the graphene surface for barrier calculations, it is shown that coronene can successfully estimate the graphene monolayer. The barrier height is calculated for perfect and two different defective PAH structures including Stone-Wales (SW) and 585. It is found that PAH even with small defects is impermeable to hydrogen molecules....
A comparative study on hydrogen interaction with defective graphene structures doped by transition metals
, Article Physica E: Low-Dimensional Systems and Nanostructures ; Vol. 60 , June , 2014 , pp. 104-111 ; ISSN: 13869477 ; Saboohi, Y ; Sharif University of Technology
2014
Abstract
In the present work, the interaction of hydrogen molecules with defective graphene structures doped by transition metal (TM) atoms is investigated by using first principles density functional theory (DFT). Defective graphene structures include Stone-Wales (SW), 585 and 555-777 and transition metals include early TMs, i.e. scandium (Sc), titanium (Ti) and vanadium (V). It is found that in comparison with the pristine graphene, presence of defects significantly enhances the metal binding. Among three defects, 585 divacancy leads to the strongest binding between graphene and metal. Hydrogen adsorption is then evaluated by sequential addition of hydrogen molecules to the system. The results...
Interaction of hydrogen molecules with defective graphene sheets: An ab initio study
, Article AIChE 2012 - 2012 AIChE Annual Meeting, Conference Proceedings ; 2012 ; 9780816910731 (ISBN) ; Saboohi, Y ; Sharif University of Technology
2012
Abstract
Hydrogen appears as one of the most promising energy carriers. Hydrogen has the advantage of being the cleanest fuel and as a result it can efficiently help limiting the greenhouse effect. However one of the major barriers for the large scale use of hydrogen, especially in the transportation sector, is hydrogen storage issue. There are four different technologies for storing hydrogen which are as follows: (1) Cryogenic liquid hydrogen (LH); (2) compressed gas storage; (3) metal hydride storage technology; (4) Physisorption methods. Physisorption of hydrogen in novel carbon nanostructures such as carbon nanotubes and graphene seems to be a safe and promising method for storage of hydrogen....
Drag performance of divergent tubular-truncated cones: A shape optimization study
, Article International Journal of Environmental Science and Technology ; Volume 9, Issue 1 , 2012 , Pages 105-112 ; 17351472 (ISSN) ; Rad, M ; Sharif University of Technology
2012
Abstract
The use of more efficient energy consuming devices, which are closely associated with reduction of environmental pollution, has gained significant interest in the recent decades. The reduction of drag coefficient also improves safety and durability of environmental structures subjected to high-velocity fluid flow, and causes the noise and vibration to decrease as well. This paper describes the efficiency improvement in energy management by means of reducing drag coefficient in a practical divergent tubular- truncated cone. Extensive numerical simulations with emphasis on the shape optimization study were performed in order to find minimum drag coefficient for both laminar and turbulent flows...
Global adaptive estimation of joint velocities in robotic manipulators
, Article IET Control Theory and Applications ; Volume 4, Issue 12 , December , 2010 , Pages 2672-2681 ; 17518644 (ISSN) ; Namvar, M ; Sharif University of Technology
2010
Abstract
This study presents a method for global estimation of joint velocities in robotic manipulators. The authors consider a non-minimal model of a robotic manipulator and design an adaptive observer capable of handling uncertainties in robot dynamics. Smoothness of the dynamics of the proposed observer allows its easy implementation in comparison with non-smooth observers. Dimension of the proposed observer is shown to be at least 3n where n stands for the manipulator's degrees of freedom. This number is less than the dimension of most existing globally convergent adaptive observers. Global asymptotic convergence of state estimates to their true values is achieved under no persistency of...