Sharif Digital Repository

The petroleum industry suffers from reservoir souring phenomena, which has negative impacts on production facilities, health, and environment. Injection of incompatible water into the reservoir (waterflooding), which is considered as an enhanced oil recovery (EOR) method, is one of the most common causes of reservoir souring. In general, injected brine, especially seawater, contains high amounts of sulfate ion (SO42−). A high concentration of sulfate in the presence of sulfate-reducing bacteria (SRB) leads to the microbial reservoir souring. During this phenomenon, sulfide, specifically hydrogen sulfide gas (H2S) appears in the producing fluid of the reservoir. In this paper, a coupled... 

TiO2 is a promising photoanode material for photoelectrochemical (PEC) water splitting, but its severe bulk recombination of photogenerated carriers, sluggish oxygen evolution reaction (OER) kinetics and poor visible light response are the main bottleneck problems. Here, the carbon quantum dots (CQDs) modified anatase/rutile TiO2 photoanode (CQDs/A/R-TiO2) was designed by growth of anatase TiO2 nanothorns on rutile TiO2 nanorods and further surface modification of CQDs. The results revealed that the A/R-TiO2 heterojunction significantly suppressed the bulk recombination of photogenerated carriers. With further incorporation of CQDs into A/R-TiO2, dramatical improvement of OER kinetics and... 

In order to generate adequate electricity energy, conventional power plants utilize dramatic volume of water resources. Different methods such as replacing cutting-edge technologies of facilities have been proposed to diminish water consumption in this industry. Most of the approaches are considered as medium or long-term solution which requires substantial investment costs. Meanwhile, because of the process and technology, natural gas-fired power plants need less water among conventional power plants. Therefore, shifting unit commitment planning toward these power plants would aid to save water consumption. Nevertheless, overlooking combined cycle power plants can perform negative impact on... 

In this paper, we study the resource allocation and scheduling problem for a downlink non- orthogonal multiple access (NOMA) network where the base station (BS) allocates the spectrum resources and power to the set of users. We aim to optimize the sub-channel assignment and power allocation to achieve a balance between the number of scheduled users and total sum-rate maximization. To solve the above problem, we propose a many-to-many two-sided user-subchannel matching algorithm in which the set of users and sub-channels are considered as two sets of players pursuing their own interests. The algorithm converges to a pair-wise stable matching after a limited number of iterations. Simulation... 

Power generation consumes a substantial amount of water in the power industry. In order to address the impact of water consumption restriction on the power generation, this paper proposes a security-constrained unit commitment (SCUC) formulation considering water consumption impact as an additional constraint. To this end, the water consumption in power plants is formulated. Consequently, the SCUC is extended to consider the consumed water volume as a restricting factor. A procedure is introduced to investigate the most appropriate point of power generation operation to save a vital amount of water by raising reasonable generation costs. The objective of the proposed model is to minimize the... 

In this paper, the resource allocation and scheduling problem for a full-duplex (FD) orthogonal frequency-division multiple-access network is studied where an FD base station simultaneously communicates with multiple pairs of uplink (UL) and downlink (DL) half-duplex (HD) users bidirectionally. In this paper, we aim to maximize the network sum-rate through joint UL and DL user pairing, OFDM subchannel assignment, and power allocation. We formulate the problem as a non-convex optimization problem. The optimal algorithm requires an exhaustive search, which will become prohibitively complicated as the numbers of users and subchannels increase. To tackle this complex problem more efficiently, we... 

A pragmatic distributed algorithm (PDA) is proposed for supporting the ef-cient spectral access of multiple Primary Users (PUs) and Cognitive Users (CUs) in cooperative Cognitive Radio (CR) networks. The CUs may serve as relay nodes for relaying the signal received from the PUs to their destinations, while both the PUs' and the CUs' minimum rate requirements are satis-ed. The key idea of our PDA is that the PUs negotiate with the CUs concerning the speci-c amount of relaying and transmission time, whilst reducing the required transmission power or increasing the transmission rate of the PU. Our results show that the cooperative spectral access based on our PDA reaches an equilibrium, when it... 

Hydrogen sulfide (H2S) generated by natural gas exploitation is a dangerous and harmful gas that needs to be purified. Electrochemical Natural Gas Desulfurization offers a promising way for H2S purification and resource utilization in ambient conditions. However, poor energy efficiency and low resource value limit the prospective application in the industry. Herein, we propose a gas-liquid flow electrocatalysis system that couples H2S oxidation and O2 reduction processes to effectively recover sulfur and H2O2 with low energy consumption. Gas diffusion and mass transfer are accelerated by gas-liquid flow cells, which also significantly decrease the resistance. Besides, I-/I3- redox pairs... 

Growing plastic pollution in the context of COVID-19 has caused significant challenges, exacerbating this already out-of-control issue. The pandemic has considerably boosted the demand for personal protective equipment (PPE), such as facemasks and gloves, all over the globe, and mismanaging this growing plastic pollution has harmed the environment and wildlife significantly. To mitigate negative environmental impacts, it is necessary to develop and implement effective waste management strategies. This present study estimated the daily facemask generation throughout the pandemic in Iran based on the distribution of urban and rural populations and, likewise, the daily generation of hand gloves... 

The fabrication of supported noble metal nanocrystals (NCs) with well-controlled morphologies have been attracted considerable interests due to their merits in a wide variety of applications. Photodeposition is a facile and effective method to load metals over semiconductors in a simple slurry reactor under irradiation. By optimizing the photodeposition process, the size, chemical states, and the geometrical distribution of metal NCs have been successfully tuned. However, metal NCs with well-controlled shapes through the photodeposition process have not been reported until now. Here, we report our important advances in the controlled photodeposition process to load regular noble metal NCs.... 

This article intends to examine thermoelastic damping (TED) in circular cylindrical nanoshells by considering small-scale effect on both structural and thermal areas. To fulfill this aim, governing equations are extracted with the aid of nonlocal elasticity theory and dual-phase-lag (DPL) heat conduction model. Circular cylindrical shell is also modeled on the basis of Donnell–Mushtari–Vlasov (DMV) equations for thin shells. By inserting asymmetric simple harmonic oscillations of nanoshell into motion, compatibility and heat conduction equations, the size-dependent thermoelastic frequency equation is obtained. By solving this equation and deriving the frequency of nanoshell affected by... 

The objective was to determine the effect of several variables - vehicle operation, weight, and accessory use - on emissions production during common on-road heavy-duty vehicle operations. Oxides of nitrogen (NOx), hydrocarbon, and carbon monoxide emissions from a heavy-duty diesel tractor equipped with a 1999 engine were measured continuously during on-road tests. The vehicle was operated at predetermined steady-state modes of 25, 55, and 65 mph as well as full-throttle accelerations from 0 to 25 mph and 0 to 55 mph and decelerations from 65 to 0 mph. Vehicle weight (payload) and accessory use (air-conditioning) were varied. In general, increases in gross vehicle weight from 52,000 lb to... 

Electric power system and its components, most of which developed based on the rising electricity demand during economic growth periods of 1970s and 1980s, have aged and some are not being replaced quickly. In addition, the integration of variable sources of energy has changed the way assets are being managed for optimal operation. Aging assets and uncertainty in power system load profile and demand management create a challenge for the optimal operation and maintenance of the electricity grid. This special section aims at addressing the challenges and opportunities in deployment of smart grid technologies such as wireless sensors for condition monitoring and intelligent electronic devices... 

In the presented work, vibrational behavior related to a curved nanopipe which is under supersonic airflow and conveying fluid flow, is examined. To model the size-dependent nanopipe, the Quasi-2D hybrid type of nonlocal strain gradient theory (QHNSGT) is presented. Formulations are obtained by means of Hamilton's principle for bi-directional functionally graded (Bi-FG) nanopipe. Also, formulations are solved by means of the generalized differential quadrature method (GDQM). By taking into account that the fluid flow is infinite, incompressible, uniform flow, Newtonian, laminar, as well, as viscous, and with the help of the Navier-Stokes equation, the fluid-structure interaction is obtained.... 

The treatment of refractory wastewater and energy utilization are challenging environmental issues. Carbonate as the most common anion abounds in the aquatic environment. Here, we proposed a novel method to degrade carbonate-containing wastewater and simultaneous electricity generation via the combined oxidation of CO3[rad]− and O2[rad]− radicals. The CO3[rad]− radical was produced by the photoelectrode of TiO2/Si photovoltaic cell with the rear Si photovoltaic cell providing external bias, and the O2[rad]− radical was produced from the generation of H2O2 on a gas diffusion electrode (GDE), and they were both further enhanced from the activation reaction of H2O2 with HCO3− electrolyte. The... 

H2S and CO2 are the main impurities in raw natural gas, which needs to be purified before use. However, the comprehensive utilization of H2S and CO2 has been ignored. Herein, we proposed a fully resource-based method to convert toxic gas H2S and greenhouse gas CO2 synchronously into CO and elemental S by using a novel electrochemical reactor. The special designs include that, in the anodic chamber, H2S was oxidized rapidly to S based on the I−/I3− cyclic redox system to avoid anode passivation. On the other hand, in the cathodic chamber, CO2 was rapidly and selectively reduced to CO based on a porous carbon gas diffusion electrode (GDE) modified with polytetrafluoroethylene and cobalt... 

The paper at hand intends to evaluate thermoelastic damping (TED) in circular plates by incorporating nonlocal effect within the constitutive and heat conduction frameworks. To attain this purpose, nonclassical coupled thermoelastic equations are established on the basis of nonlocal elasticity theory and Guyer–Krumhansl (GK) heat conduction model. By considering symmetric time–harmonic vibrations, the size-dependent thermoelastic frequency equation is derived. By solving this nonclassical eigenvalue problem, real and imaginary parts of damped natural frequency are separated. According to the definition of TED in the framework of complex frequency approach, a closed-form expression... 

Warm-up period is considered as the most critical phase in the operation of any device that converts the energy of a fuel into heat, electricity, and other products, including power generation units since the system efficiency and environmental pollution levels are much worse than the normal operation in that phase. Considering this point, in this study, applying the zero-flow coolant strategy to reduce the warm-up period is suggested for power generation units and it is investigated in details. An internal combustion engine is selected as the case-study and implementation of the method to enhance the performance of that from both energy and environmental aspects are studied comprehensively.... 

Nickel oxide (NiOx) is a promising hole transport material in inverted organic-inorganic metal halide perovskite solar cells. However, its low intrinsic conductivity hinders its further improvement in device performance. Here, we employ a trimercapto-s-triazine trisodium salt (TTTS) as a chelating agent of Ni2+ in the NiOx layer to improve its conductivity. Due to the electron-deficient triazine ring, the TTTS complexes with Ni2+ in NiOx via a strong Ni2+-N coordination bond and increases the ratio of Ni3+:Ni2+. The increased Ni3+ concentration adjusts the band structure of NiOx, thus enhancing hole density and mobility, eventually improving the intrinsic conductivity of NiOx. As a result,... 

This research explored the influences of shielding gases on the appearance of weld beads and the microstructures and mechanical properties of thin-wall samples using conventional gas metal arc welding as the heat source by using 5356 aluminium alloy welding wire as the raw materials and nitrogen (N2) and argon (Ar) as the shielding gases. The results showed that under the same parameters and after mono-layer single-bead welding was performed using N2 as the shielding gas, the bead height was higher, the bead width was narrower, and the penetration depth was shallower. The grain size of the thin-wall sample protected by N2 was 43.5–47.8 % smaller than that obtained under Ar protection....