Sharif Digital Repository

The present work was aimed to account a green and eco-friendly synthesis of palladium nanoparticles using Rosmarinus officinalis leaves extracts for the first time, therefore, that can be an acceptable replacement for chemical media to improve potential biological properties. The synthesized palladium nanoparticles were fully characterized using FT-IR, XRD, FESEM, TEM and UV/Vis spectroscopy techniques. Catalytic activity was investigated by Mizoroki-Heck reaction, and optimized based on solvent, temperature and time of the reaction, and the best results were found in water as a green media without any additional reagents. Biological activity of the synthesized nanoparticles were evaluated... 

The state-of-art technologies keep generating new ways of improving on remote sensing and Earth monitoring like Synthetic Aperture Radars that is widely used in military applications such as reconnaissance and espionage especially on military and industrial sensitive and strategic areas. In order to protection of strategic fields and being aware of hostile activities and also do sufficient countermeasure action, in this research a simple SAR satellite detection and tracking is proposed by using a reliable fast search and tracking antenna considering the limitation of radio visibility duration of SAR satellites. The tracking antenna is a DBF phased array antenna with circular polarized patch... 

A 6-bit passive phase shifter for 2.5- to 3.2-GHz frequency band has been designed and implemented in a standard 0.18- μm CMOS technology. A new switched-network topology has been proposed for implementing the 5.625 ° phase shift step. The insertion loss of the circuit is compensated with an on-chip bidirectional amplifier. The measured return losses of the circuit are better than 8 dB with output 1-dB compression point of +9.5 dBm in the transmit mode and noise figure of 7.1 dB in the receive mode. The fabricated phase shifter demonstrates an average rms phase error of less than 2° over the entire operation bandwidth, which makes it suitable for high-precision applications  

Due to problems followed by asphaltene deposition, which cause many remedial processes and costs, it seemed necessary to develop equations for determining asphaltene precipitation quantitatively or qualitatively. In this study a new scaling equation as a function of temperature, molecular weight, and dilution ratio (solvent) has been developed. This equation can be used to determine the weight percent of precipitated asphaltene in the presence of different precipitants (solvents). The proposed methodology utilizes least square support vector machines/regression (LSSVM/LSSVR) to perform nonlinear modeling. This paper proposes a new feature selection mechanism based on coupled simulated... 

Computer base and simulation technique have been applied for modeling the semi-solid die filling and part of the solidification process of aluminum A356 alloy. A fairly simple one-phase rheological model has been implemented into a fluid flow finite element software Procast, to solve the partial differential equations. This model is purely viscous nature and is implemented in the power law cut-off model of Procast. The constitutive parameters of this model were determined for a rheocast A356 alloy. Using these parameters and comparing the simulation results with experimental data showed good correlation with the model prediction. The designed die for rheocasting was applied for the... 

In this paper, high cycle fatigue behavior and thermal properties of blend specimens made of polylactic acid (PLA) and polycaprolactone (PCL) were studied and the influence of crystallization was investigated on the fatigue behavior. In this regard, fused deposition modeling method was employed to manufacture neat-PLA, neat-PCL, PLA/10wt.% PCL (90/10), and PLA/20wt.% PCL (80/20) specimens. The results show that the addition of 10wt.% and 20wt.% of PCL to the neat-PLA increases the elongation of the specimens by 32% and 284%, respectively, compared to that of the neat-PLA. However, Young’s modulus respectively decreases by 22% and 34%. According to the differential scanning calorimetry (DSC)... 

Considering the desirable biodegradable properties and mechanical characteristics of poly lactic acid (PLA) and poly caprolactone (PCL), these polymers are recently widely utilized in medical applications including the fabrication of body-compatible implants. One of the most efficient manufacturing methods to fabricate polymer-based implants is 3D printing, due to its ability to rapidly produce parts with complex geometries. In this study, an effort has been made to study the impact of the dip-coating process on tensile and high cycle fatigue behavior of 3D printed PLA/PCL blends, using PCL/chloroform solution. The results demonstrate that after applying the PCL coating on the surface of the... 

Smoking is known as a major cause of chronic obstructive pulmonary disease (COPD) and hence immediate and effective interventions are required for its elimination. This study aimed to collect valid data with regard to cigarette smoking in adult population of north of Iran for policy making by a meta-analysis of the documents of national non-communicable disease risk factors surveillance system. We investigated relevant evidences by searching in published and non-electronic databases. Data were extracted based on variables such as year of the study, sex, age group and prevalence of smoking habit. Based on results of heterogeneity, we applied fixed or random effects model to estimate the... 

Introduction: In recent years, the use of cost-effective, multifunctional, environmentally friendly and simple prepared nanomaterials/nanoparticles have been emerged considerably. In this manner, different synthesizing methods were reported and optimized, but there is still lack of a comprehensive method with multifunctional properties. Materials and Methods: In this study, we aim to synthesis the copper oxide nanoparticles using Achillea millefolium leaf extracts for the first time. Catalytic activity was investigated by in situ azide alkyne cycloaddition click and also A3 coupling reaction, and optimized in terms of temperature, solvent, and time of the reaction. Furthermore, the... 

Attitude Determination (AD) is one of the key requirements of many current and emerging remote sensing missions. As such AD has been traditionally accomplished through a variety of algorithms and measurement models pertinent to sensing mechanisms. The current paper addresses conceptual validation and utility of a novel radiation based heat (measurement) model for space application. The proposed new Heat Attitude (HA) model utilizes temperature data to relate the Satellite Surfaces’ (SS) Net Heat Flux (NHF) to attitude assuming that the satellite navigational data are available. As Sun and the Earth are considered the main external sources of radiation, their effects are modeled for the SS... 

The treatment of water contaminated by bacteria is becoming a necessity. The nanomaterials possessing both intrinsic antibacterial properties and photocatalytic activity are excellent candidates for water disinfection. The powdered form of nanomaterials can be aggregated while embedding the nanomaterials into the NFs can overcome the limitation and enhance the photocatalytic activity and transition from UV-light to visiblelight. Here, graphene oxide (GO) was synthesized, grafted to chitosan, and decorated with silver nanoparticles (Ag NPs) to produce Ag-decorated reduced GO-graft-Chitosan (AGC) NPs. The blends of polyacrylonitrile (PAN) and AGC NPs were prepared in various concentrations of... 

A tri-layered nanofibrous hydrogel thin film with temperature sensitivity is introduced as a new controlled drug release system to treat breast cancer. A simultaneous heat generation with the tunable release of dual drugs is observed in response to visible light radiation. A tri-layered nanofibrous sheet was fabricated through sequential electrospinning the blends of Au@Chit@DOX-loaded poly(N-isopropylacrylamide-co-N-methylol acrylamide) (poly (NIPAAm-co-NMA)) and Curcumin-loaded poly (vinyl alcohol) (Cu-loaded PVA), where the Cu-loaded PVA nanofibers (NFs) are sandwiched between two layers of Au@Chit@DOX-loaded poly (NIPAAm-co-NMA) NFs. After thermal crosslinking of the tri-layered... 

Doxorubicin (DOX) is a potent anti-cancer agent and there have been attempts in developing nanostructures for its delivery to tumor cells. The nanoparticles promote cytotoxicity of DOX against tumor cells and in turn, they reduce adverse impacts on normal cells. The safety profile of nanostructures is an important topic and recently, the green synthesis of nanoparticles has obtained much attention for the preparation of biocompatible carriers. In the present study, we prepared layered double hydroxide (LDH) nanostructures for doxorubicin (DOX) delivery. The Cu–Al LDH nanoparticles were synthesized by combining Cu(NO3)2·3H2O and Al(NO3)3·9H2O, and then, autoclave at 110. The green... 

The design and implementation of the hybrid control method for a three-pole active magnetic bearing (AMB) is proposed in this paper. The system is inherently nonlinear and conventional nonlinear controllers are a little complicated while the proposed hybrid controller has a piecewise linear form, i.e., linear in each sub-region. A state-feedback hybrid controller is designed in this study and the unmeasurable states are estimated by an observer. The gains of the hybrid controller are obtained by the LQR method in each sub-region. To evaluate the performance, the designed controller is implemented on an experimental setup. The experimental results show that the proposed method can efficiently... 

In this paper, a comparison between several array geometries, including planar arrays and volume arrays, for two-dimensional Direction of Arrival (DOA) estimation using Multiple Signal Classification (MUSIC) is presented. For each geometry, various criteria is taken into consideration and a comparative study of the performance of geometries is carried out. The geometries together with their ultimate direction finding performance are compared based on Root Mean Square Error (RMSE), the ambiguity functions, and Cramer-Rao Bounds (CRB). Furthermore, the effects of phase and amplitude variations of the array element radiation pattern, namely Vivaldi and Monopole antenna, on DOA estimation... 

Nanowire arrays of copper oxide were first grown vertically using simple and cost effective thermal oxidation method on a copper foil. Subsequently, in order to deposit and grow PbS nanocyrstalline thin films on CuO NWs by utilizing the chemical bath deposition technique, these arrays were immersed as the substrate in the reaction solution consisting of Pb(NO3)2, (NH2)2CS and NaOH. The final products were characterized in detail by which the formation of uniform, unique arrays of CuO@PbS core–shell NWs was confirmed. Due to the nature of methods employed in synthesis of this hetero structure, the tuning of core and shell size and consequently properties of the novel structure is easily... 

A technique to achieve the globular weld structure using stirring the localized semisolid zone during butt-joining of zinc AG40A (Zamak-3) die cast alloy is reported. Since the semisolid temperature range of this alloy is very narrow, the accurate controlling of weld pool temperature must be considered. By presented process, globular microstructure of the weld zone can be achieved. Moreover the near weld zone would have the globular structure due to semisolid holding. A gas heating system was designed to heat up the nitrogen gas to desired temperature accurately. A heating element was embedded in a castable ceramic block while a stream of gas could pass closely around the hot element length.... 

Globulization of the grain refined AZ91 magnesium alloy with Ca on a cooling slope was investigated. Dendritic morphology of the grains was transferred into round and well distributed small particles as a result of grain-refinement effect of Ca in the alloy. Semi-solid holding of the alloy was carried out at different temperatures to improve the spherecity of the globules. Results show that, remelting at 540 °C for 30 min provides the best shape factor for the alloy. The study of coarsening kinetic in this alloy showed lower growth rate alternative other research which used same condition for produce semi-solid billet just in using Ca  

In this research, the characteristics of the prepared samples in epoxy matrix by means of X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), as well as scanning electron microscope (SEM) are evaluated. Meanwhile, the obtained mechanical properties of the specimen are investigated. Thermogravimetric analysis (TGA) is also employed to evaluate the thermal degradation of manufactured nanocomposites. The thermal neutron absorption properties of nanocomposites containing 3 wt% of montmorillonite nanoclay (closite30B) have been studied experimentally, using an Am-Be point source. Mechanical tests reveal that the higher B4C concentrations, the more tensile strengths, but lower... 

It is known that the thermomechanical processing is one of the most important techniques for improving quality and mechanical properties of microalloyed steels. In this paper, the main parameters of hot forging (preheat temperature, strain and post-forging cooling rate) on the primary austenite grain size of vanadium microalloyed steel (30MSV6) were studied. From this investigation, it was found that increasing preheat temperature from 1150 °C to 1300 °C will result in a decrease in grain size number. Furthermore, it has shown that as the strain increases, the austenite grain size number increases, as is evident for the two cooling rates of 2.5 °C/s and 1.5 °C/s for primary austenite....