Sharif Digital Repository

Based on exclusive thermal dynamic of nanomaterials, various applications are noted in engineering and industrial processes. Owing to such thermal impact, the researchers have presented comprehensive research on nanomaterials. While claiming novel applications of nanofluids, the stability of nanomaterials is important for which less attention has been paid. On this end, the aim of current research is to predict the thermal instability of graphene nanoparticles with suspension of water base fluid due to transient Hartmann flow. The Poiseuille flow of water-based nanoparticles subject to the magnetic force is assumed between two plates. The numerical outcomes are predicted with implementation... 

Nonlinear optical (NLO) materials are essential components in modern photonics and optical devices due to their ability to generate new frequencies through the nonlinear interaction with intense light. Synthesizing porphyrin-based NLO materials is complex and challenging, requiring specialized techniques to achieve high purity and yield. Controlling chromophore orientation and optimizing nonlinear optical properties are key difficulties that demand interdisciplinary efforts for practical photonics and optical applications. In the present study by using z-scan technique some of non-linear optical (NLO) parameters includingthird order NLO susceptibility (χ3), and molecular second... 

This paper focuses on characterization of intervertebral disc behavior upon fatigue stress. It consists in in-vitro experiments to measure intervertebral disc deformation with regard to forces applied to produce fatigues test. In this paper, a system modeling based non-invasive method to assess back pain is proposed which may be used for designing of prediction model to predict the failure of intervertebral disc (IVD) experiencing fatigue loading. An artificial compression fracture was simulated in the lower level of vertebra followed by a poly(methyl methacrylate) (PMMA) bone cement injection. Fatigue loading was applied on the specimens and the load was incrementally increased form 650 N... 

Cotton contributes 0.6% to the value added in GDP and 3.1% to the value added in the agriculture sector of Pakistan. The dusky cotton bug (DCB), Oxycarenus hyalinipennis (Hemiptera: Lygaeidae), is among the insect pest species of highest economic significance in cotton production in the country. Adults and nymphs feed on seeds and cotton bolls, affecting seed germination. The dusky cotton bug is a polyphagous insect that feeds on a variety of host plants. Its adults and nymphs typically feed on squares of the cotton plant, resulting in a pale yellow color of squares and subsequent shedding of infested squares. Insecticide resistance in cotton insect pests is an emerging threat to sustainable... 

Aluminum alloys have promising characteristics which make them more useful in industrial applications for thermal management and entropy of the fluidic system. Hence, the current research deals with the analysis of entropy and thermal performance of (C2H6O2–H2O)/50:50% saturated by (AA7072/AA7076/Ti6AI4V) alloys. Traditional problem modified using enhanced characteristics of ternary alloys and hydrocarbon 50:50% base fluid. Further, significant effects of nonlinear solar radiations, dissipation and convective heat condition effects are also taken in the problem formulation. The developed model analyzed numerically and simulated the results for thermal performance, comparative entropy, shear... 

This study focuses on a forward looking approach in which deep eutectic solvents (DESs), a new class of designer solvents, were impregnated into micro porous polyvinylidene fluoride (PVDF) membrane for the separation of CO2 from CH4. Three types of DESs were prepared by mixing and heating of hydrogen bond acceptor (choline chloride) with either malic acid, tartaric acid or oxalic acid as hydrogen bond donor. The Fourier transform infrared spectroscopy confirmed the hydrogen bond interactions in the resulting DES. Thermal gravimetric analysis (TGA) was used to evaluate the thermal stability of the prepared membranes. The DES based supported liquid membranes were investigated systematically to... 

The microfluidic device, known simply as microfluidics, is an emerging technology that has become a significant tool for pharmaceutical businesses to process and analyze materials for developing, optimizing, testing, and delivering various drugs in advanced nanocarriers. Technically, microfluidics is a technique to handle small solution volumes (nanoliters to picoliters) in microchambers of different geometries and dimensions ranging from a few nanometers to hundreds of micrometers. Each year, many pharmaceutical drug delivery systems have failed clinical translation because of scale-up problems. Now, scientists are trying to find some suitable alternatives and more robust methodologies to... 

This study aimed to evaluate the efficacy of vinegar-soaked Ficus carica fruits (VSFCF) for managing cholelithiasis in adults. A parallel-group, single-blinded, randomized controlled trial at Noreen Nishat Welfare Hospital, Khanewal, Pakistan, was conducted from December 2023 to February 2024. Fifty adults with ultrasound-confirmed cholelithiasis were randomly assigned to receive either VSFCF (1 g/kg/day) or ursodiol (600 mg/day). Primary outcomes included gallstone size reduction, while secondary outcomes assessed symptom relief (pain, bloating, digestive discomfort) and hepatic markers. Data analysis was performed using SPSS with a significance level set at P<0.05. Results indicated a... 

Chitosan-doped zinc oxide nanoparticles (CS-ZnO NPs) were meticulously fabricated using the sol-gel methodology. The CS-ZnO NPs underwent comprehensive analytical assessments, employing advanced techniques, encompassing X-ray diffraction (XRD), scanning electron microscopy (SEM), UV visible (UV-Vis) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, and thermogravimetric analysis (TGA). An average crystallite size of 15 nm was calculated through XRD. These NPs showed an absorption band at 292 nm. TGA revealed the two-phase weight loss mechanism in the investigated nanocomposite. Effective antibacterial activity, at various NPs concentrations, was observed against Xanthomonas... 

The growth and productivity of different varieties of beetroot Beta vulgaris were examined in presence of urea, nitrogen, phosphorus, potassium, compost and salt during the field trial, and the chemical constitution of three different varieties, dark red, ruby queen and detroit-2 was identified quantitatively by spectrophotometer. Ruby queen shows maximum growth as compared to dark red and detroit-2. The application of urea, nitrogen, phosphate, potassium and compost reduces the amount of catalase and total antioxidant enzymic potensial while increasing the concentrations of proteins, lipids, and sugars, with high growth and yield. Maximum growth was observed in the presence of urea, while... 

Pr and Co co-doped BiFeO3 multiferroics of the following composition BiCoxPrxFe1-2xO3, where (x = 0.00, 0.05, 0.10, 0.15, 0.20 and 0.25) were prepared via sol-gel route. XRD, FTIR, SEM, VSM and VNA were used to evaluate the structural, phase, morphological and electromagnetic properties of Pr and Co co-doped multiferroics. All the undoped and Pr–Co co-doped multiferroics were of single rhombohedral phased whereas at higher concentration the orthorhombic structure was present. FTIR analysis exhibited the presence of orthorhombic phase. SEM images revealed that the grains of Pr and Co doped multiferroics are circular and elliptical in shape. Dielectric and electromagnetic properties were... 

Pr and Co co-doped BiFeO3 multiferroics of the following composition BiCoxPrxFe1-2xO3, where (x = 0.00, 0.05, 0.10, 0.15, 0.20 and 0.25) were prepared via sol-gel route. XRD, FTIR, SEM, VSM and VNA were used to evaluate the structural, phase, morphological and electromagnetic properties of Pr and Co co-doped multiferroics. All the undoped and Pr–Co co-doped multiferroics were of single rhombohedral phased whereas at higher concentration the orthorhombic structure was present. FTIR analysis exhibited the presence of orthorhombic phase. SEM images revealed that the grains of Pr and Co doped multiferroics are circular and elliptical in shape. Dielectric and electromagnetic properties were... 

The X-ray photoemission (XPS) measurements of Cu1-xTlxBa2Ca2 Cu3-yZnyO10-δ (y = 0, 2.65) superconductors have been performed and compared. These studies revealed that the charge state of thallium in the Cu0.5Tl0.5Ba2O4-δ charge reservoir layer in Zn doped samples is Tl1+, while it is a mix of Tl1+ and Tl2+ in Zn free samples. The binding energy of Ba atoms in the Zn doped samples is shifted to higher energy, which when considered along with the presence of Tl1+ suggested that it more efficiently directed the carriers to ZnO2 and CuO2 planes. The evidence of improved inter-plane coupling witnessed in X-ray diffraction is also confirmed by XPS measurements of Ca atoms in the Zn doped samples.... 

X-ray photo-emission spectroscopy (XPS) studies of Cu1-xTlxBa2Ca3Cu4 O12-y superconductor thin films have been carried out for understanding the mechanism of superconductivity and to find out the reasons for the increase of zero resistivity critical temperature Tc(R = 0) with post-annealing in a nitrogen atmosphere. It is observed from these studies that reduction of charge state of thallium is a source of doping of carriers to the CuO2 planes. The reduced charge state of thallium (i.e. Tl1+) promotes lower oxygen concentration in the charge reservoir layer, which possibly results in movement of electrons to the conducting CuO2 planes. The higher density of electrons in the CuO2 planes... 

Sustainable agriculture is a pivotal driver of a nation’s economic growth, especially considering the challenge of providing food for the world’s expanding population. Agriculture remains a cornerstone of many nations’ economies, so the need for intelligent, sustainable farming practices has never been greater. Agricultural industries worldwide require sophisticated systems that empower farmers to manage their crops efficiently, reduce water wastage, and optimize yield quality. Yearly, substantial crop losses occur due to unpredictable environmental changes, with improper irrigation practices being a leading cause. In this paper, we introduce an innovative irrigation time control system for... 

Ca-doped Ni–Mg–Mn spinel ferrites with compositions of Ni0·5Mg0·3Mn0.2CaxFe2-xO4 (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) were prepared via sol-gel auto-ignition technique. TGA/DTA, FTIR, XRD, FESEM, and VSM were employed to evaluate the thermal, spectral, structural, morphological, and magnetic features of Ca-doped Ni–Mg–Mn spinel ferrites. TGA/DTA curves show the weight loss in the sample. This weight loss was attributed to the oxidation and decomposition of the sample contents at a temperature of 500 °C. XRD reveals a single-phase structure of the Ni–Mg–Mn nano ferrites. A single-phase orthorhombic structure was confirmed for Ca-doped Ni–Mg–Mn ferrites. Structural parameters such as lattice... 

As of late quantum calculus is broadly utilized in different parts of mathematics. Uniquely, the hypothesis of univalent functions can be newly portrayed by utilizing q-calculus. In this paper, we utilize our recently presented symmetric p,q-number m p,q to characterize new symmetric p,q-derivative D p,q of analytic function f in the open unit disk U. Utilizing D p,q, we introduce new class of analytic star-like functions and examine some fascinating results. © 2021 Khalid Akbar et al  

As of late quantum calculus is broadly utilized in different parts of mathematics. Uniquely, the hypothesis of univalent functions can be newly portrayed by utilizing q-calculus. In this paper, we utilize our recently presented symmetric p,q-number m p,q to characterize new symmetric p,q-derivative D p,q of analytic function f in the open unit disk U. Utilizing D p,q, we introduce new class of analytic star-like functions and examine some fascinating results. © 2021 Khalid Akbar et al  

Thermal engineering and industrial processes see various multidisciplinary applications due to the enhanced thermal performances of nanomaterials. The nanomaterials preserve a profound breakthrough in enhancing the heat transfer phenomenon. The objective of the current investigation is to address the thermal applications of couples-stress nanofluid in the presence of triple diffusion effects. The analysis is subject to the bioconvective significance of the suspension of microbes. The viscosity and thermal conductivity of a couple stress fluids are assumed to be variable. Moreover, we endorse linear thermal radiation effects and approach the problem with an effective Prandtl number. The... 

The high temperature superconductor thin films Cu1-xTl xBa2Ca3Cu4O12-δ (Cu1-xTlx- 1234) are post-annealed in a nitrogen atmosphere. The zero-resistivity critical temperature (Tc(R ≤ 0)) of these thin films is increased from 92.3 to 104K. The grain size is enhanced and their morphology is improved with the post-annealing. The enlargement of grain size is linked to fluctuation-induced conductivity (FIC) in the light of Aslamazov-Larkin (AL) theory. The FIC measurements have shown that the cross-over of three-dimensional (3D) to two-dimensional (2D) behaviour of fluctuations is shifted to higher temperature values with an increase of post-annealing temperature. These results have shown that the...