Sharif Digital Repository

Electrospray ionization of 2,6-naphthalenedicarboxylic acid readily affords its doubly deprotonated dicarboxylate dianion (1 2-). This species clusters with background water and added alcohols in an ion trap at ∼10-3 Torr. Sequential solvation is observed to afford mono and dicoordinated ions. Surprisingly, the latter cluster (1 2- • 2TFE) is protonated by 2,2,2-trifluoroethanol (TFE) whereas 1 2-and 1 2- • TFE are not even though δHacid(TFE)=361.7±2.5kcalmol-1 (as given in the NIST website at http://webbook.nist.gov) and the B3LYP/6-31+G(d,p) proton affinities are 384.7 (1 2-), 377.6 (1 2- • TFE), and 362.7 (1 2- • 2TFE) kcal mol-1. That is, only the weakest base in this series, and the... 

Electrospray ionization of 2,6-naphthalenedicarboxylic acid readily affords its doubly deprotonated dicarboxylate dianion (12−). This species clusters with background water and added alcohols in an ion trap at ∼10−3 Torr. Sequential solvation is observed to afford mono and dicoordinated ions. Surprisingly, the latter cluster (12−• 2TFE) is protonated by 2,2,2-trifluoroethanol (TFE) whereas 12−and 12−• TFE are not even though ΔH°acid(TFE) = 361.7 ± 2.5 kcal mol−1 (as given in the NIST website at http://webbook.nist.gov) and the B3LYP/6-31+G(d,p) proton affinities are 384.7 (12−), 377.6 (12−• TFE), and 362.7 (12−• 2TFE) kcal mol−1. That is, only the weakest base in this series, and the dianion... 

Machine learning (ML) is generating new opportunities for innovative research in energy economics and finance. We critically review the burgeoning literature dedicated to Energy Economics/Finance applications of ML. Our review identifies applications in areas such as predicting energy prices (e.g. crude oil, natural gas, and power), demand forecasting, risk management, trading strategies, data processing, and analyzing macro/energy trends. We critically review the content (methods and findings) of more than 130 articles published between 2005 and 2018. Our analysis suggests that Support Vector Machine (SVM), Artificial Neural Network (ANN), and Genetic Algorithms (GAs) are among the most... 

For a given quantum field theory, provided the area of the entangling surface is fixed, what surface maximizes entanglement entropy? We analyze the answer to this question in four and higher dimensions. Surprisingly, in four dimensions the answer is related to a mathematical problem of finding surfaces that minimize the Willmore (bending) energy and eventually to the Willmore conjecture. We propose a generalization of the Willmore energy in higher dimensions and analyze its minimizers in a general class of topologies Sm×Sn and make certain observations and conjectures that may have some mathematical significance  

A luminescent coating of CaAlSiN3:Eu2+ particles applied on photoanode (TiO2) layer of SQ1 sensitized solar cell by doctor blading the paste of phosphor particles. The luminescent layer acted as a dual functional layer and enhanced the short circuit current density (JSC) by 64% via both scattering effect and downshifting of the photons in 400-600nm spectral range to photons in 600-800nm spectral range. Considerable relative enhancement in incident photon to current conversion efficiency (IPCE) up to 350% in 400-600nm spectral range proves the down shifting effect as the dominant factor for the improved performance of dye sensitized solar cell (DSSC). © 2016 Elsevier B.V  

Probabilistic Context-Free Grammars (PCFGs) are useful tools for syntactic analysis of natural languages. Availability of large Treebank has encouraged many researchers to use PCFG in language modeling. Automatic learning of PCFGs is divided into three different categories, based on the needed data set for the training phase: supervised, semi-supervised and unsupervised. Most current inductive methods are supervised, which need a bracketed data set in the training phase. However, lack of this kind of data set in many languages, has encouraged us to pay more attention to unsupervised approaches. So far, unsupervised approaches have achieved little success. By considering a history-based... 

A simple functional form for a general equation of state based on an effective near-neighbor pair interaction of an extended Lennard-Jones (12,6,3) type is given and tested against experimental data for a wide variety of fluids and solids. Computer simulation results for ionic liquids are used for further evaluation. For fluids, there appears to be no upper density limitation on the equation of state. The lower density limit for isotherms near the critical temperature is the critical density. The equation of state gives a good description of all types of fluids, nonpolar (including long-chain hydrocarbons), polar, hydrogen-bonded, and metallic, at temperatures ranging from the triple point... 

ADI have been used for a wide variety of application in automotive,rail,and heavy engineering industry because of its excellent mechanical properties such as high strength with good ductility,good wear resistance,and good fatigue properties. The properties of austempered ductile iron are dependent on both chemistry and heat treatment, which has lead to invention of MADI (machinable austempered ductile iron). MADI is a new class of ductile iron with superior mechanical property than regular ductile iron with the same machinability characteristic. In this study Different cycles of austempering process (austenitization and austempering cycle) applied Due to the effect of heat treatment cycle on... 

In this paper, we present a new unsupervised coreference resolution method, that models coreference resolution as a graph labeling problem. The proposed approach uses an incremental graph development method that hierarchically deploys coreference features from higher precision to lower ones. Then, a relaxation labeling method is used for solving the graph labeling problem  

ADI have been used for a wide variety of applications in automotive, rail, and heavy engineering industry because of its excellent mechanical properties such as high strength with good ductility, good wear resistance, and good fatigue properties. The properties of austempered ductile iron are dependent on both chemistry and heat treatment, which has lead to invention of MADI (machinable austempered ductile iron). MADI is a new class of ductile iron with superior mechanical property than regular ductile iron with the same machinability characteristic. In this study Different cycle of austempering process (austenitization and austempering cycle) applied Due to the effect of heat treatment... 

This paper introduces a new hybrid electro membrane bioreactor (HEMBR) for reverse osmosis (RO) pretreatment and advanced treatment of effluent by simultaneously integrating electrical coagulation (EC) with a membrane bioreactor (MBR) and its performance was compared with conventional MBR. Experimental results and their statistical analysis showed removal efficiency for suspended solids (SS) of almost 100% for both reactors. HEMBR removal of chemical oxygen demand (COD) improved by 4% and membrane fouling was alleviated according to transmembrane pressure (TMP). The average silt density index (SDI) of HEMBR permeate samples was slightly better indicating less RO membrane fouling. Moreover,... 

The subject of this study is to investigate the effect of repair on the fatigue life of tubular joints. Six cracked specimens previously subjected to fatigue loading underwent weld repair. Two of these specimens were shot peened before primary fatigue loading. It is shown that repair for the original specimens increases the fatigue life by roughly 150%. The increase of fatigue life for shot peened and repaired specimens is around 105%. The in-depth residual stresses are measured on the repaired joints before and after fatigue loading. It can be stated that repair made a remarkable improvement on the fatigue behavior of tubular joints examined in this investigation. However, where repair is... 

Environmental pollution, particularly water pollution caused by organic substances like synthetic dyes, is a pressing global concern. This study focuses on enhancing the adsorption capacity of layered double hydroxides (LDHs) to remove methylene blue (MB) dye from water. The synthesized materials are characterized using techniques like FT-IR, XRD, SEM, TEM, TGA, EDS, BET, BJH, AFM, and UV–Vis DRS. Adsorption experiments show that Zn–Al LDH@ext exhibits a significant adsorption capacity for MB dye compared to pristine LDH. In addition, Zn–Al LDH@ext shows a significant increase in stability, which is attributed to the presence of phenolic compounds in the extract and the interactions between... 

The nanofibers prepared by electrospinning process have high potential for the removal of toxic matters from wastewaters. In the present study, the titanium dioxide and titanium dioxide/zinc oxide (TiO2/ZnO) nanofibers prepared by electrospinning technique were coated on the sewage sludge carbon (SSC) surface for adsorption of Ni(II), Cu(II), and COD from aqueous solutions and industrial wastewaters of Iran. The synthesized adsorbents were characterized using XRD, SEM and EDX analysis. The effect of adsorbent type, pH, adsorbent dosage, contact time and initial concentrations of Ni(II), Cu(II) and COD on the adsorption capacity of synthesized SSC/TiO2 and SSC/TiO2/ZnO nanofibrous adsorbents... 

The nanofibers prepared by electrospinning process have high potential for the removal of toxic matters from wastewaters. In the present study, the titanium dioxide and titanium dioxide/zinc oxide (TiO2/ZnO) nanofibers prepared by electrospinning technique were coated on the sewage sludge carbon (SSC) surface for adsorption of Ni(II), Cu(II), and COD from aqueous solutions and industrial wastewaters of Iran. The synthesized adsorbents were characterized using XRD, SEM and EDX analysis. The effect of adsorbent type, pH, adsorbent dosage, contact time and initial concentrations of Ni(II), Cu(II) and COD on the adsorption capacity of synthesized SSC/TiO2 and SSC/TiO2/ZnO nanofibrous adsorbents... 

Analysis of microparticle size and fluorescence intensity can be used to classify microparticles. We designed and fabricated an optofluidic system that characterizes microparticles, including fluorescent microparticles and microalgae. A new type of multi-pixel photon counter (MPPC) was employed to miniaturize the device, lower its power consumption, and make it insensitive to magnetic fields. The system uses a 635 nm laser for excitation of the microparticles' fluorescence. The scattered light from the fluorescent microparticles, as well as Chlorella vulgaris and Chlorella protothecoides, were measured. Additionally, we analyzed the width and height of the measured signals generated as a... 

Peripheral milling is extensively used in manufacturing processes, especially in aerospace industries where end mills are used for milling of wing parts and engine components. The generation of complex shapes with high quality for various types of materials is the main advantage of milling in contrast to other machining processes. During the milling process, the occurrence of self-excited vibrations or chatter may cause reduction in material removal rate (MRR), damage to the tool and spindle bearing or may result in poor dimensional accuracy and surface finish of the work-piece. In this paper, milling process is modeled as two degrees of freedom (2DOF) system in which the tool wear and... 

The special issue of the Journal of Supercomputers presents recent research results on multicore systems where contributions cover different topics such as architecture, programming tools and applications, as well as other related aspects of multicore systems design. Contributed papers include some of the high-quality papers accepted at the CADS 2013 conference that took place in Tehran, which were selected based on the evaluation scores and presentation quality at the conference. The review process required three rounds of diligent reviews and revisions resulting in the final accepted manuscripts for publication in the journal  

Migration to Three Dimensional Integrated Circuits (3D ICs) can provide higher scalability, higher throughput, and lower power consumption with respect to Two Dimensional Integrated Circuits (2D ICs). Also, the latency bottleneck of interconnections in 2D ICs is efficiently solved in 3D ICs. This is due to the use of Through-Silicon-Vias (TSVs) in the communication structure of 3D ICs. TSVs are among the efficient fabrication mechanisms that connect stacked layers in 3D ICs. However, proximity and large size of TSVs make them highly prone to crosstalk faults. Crosstalk faults can cause mutual undesired influences between TSVs and thus seriously threat the reliability of data transfer on... 

In this study, kernel least mean square (KLMS) algorithm with fractionally spaced equalizing structure is proposed for electrical compensation of chromatic dispersion (CD) and nonlinear phase noise (NLPN) in a dual polarization optical communications system with coherent detection. We consider single mode fiber channel. At the receiver, the additive optical noise is represented as additive white Gaussian noise. Phase modification is utilized at high signal powers to maintain the validity of Gaussian model of noise. We consider QAM and PSK modulations and evaluate the performance of the proposed method in terms of error rate, phase error, and error vector magnitude (EVM). The results are...