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hosseinpour--fatemeh
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ChemInform abstract: microwave-assisted rapid ketalization/acetalization of aromatic aldehydes and ketones in aqueous media [electronic resource]
, Article Journal of Chemical Research ; September 1999, Volume -, Number 9; Page(s) 562 to 563 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent
Synthesis and characterization of poly(methacrylates) containing spiroacetal and norbornene moieties in side chain [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 77, Issue 1, pages 30–38, 5 July 2000 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing...
Prediction of DNA/RNA Sequence Binding Site to Protein with the Ability to Implement on GPU
, M.Sc. Thesis Sharif University of Technology ; Koohi, Sommaye (Supervisor)
Abstract
Based on the importance of DNA/RNA binding proteins in different cellular processes, finding binding sites of them play crucial role in many applications, like designing drug/vaccine, designing protein, and cancer control. Many studies target this issue and try to improve the prediction accuracy with three strategies: complex neural-network structures, various types of inputs, and ML methods to extract input features. But due to the growing volume of sequences, these methods face serious processing challenges. So, this paper presents KDeep, based on CNN-LSTM and the primary form of DNA/RNA sequences as input. As the key feature improving the prediction accuracy, we propose a new encoding...
Investigation of heat transfer enhancement in a microchannel heat sink with the aid of internal fins: a metamodel approach
, Article Computer Aided Chemical Engineering ; Volume 48 , 2020 , Pages 85-90 ; Kazemeini, M ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Heat transfer enhancement with microchannel tools has been increased in recent year. In this study effect of geometric parameters as well as Reynolds number have been studied with experimental design approach. A metamodel was generated in this study for pressure drop and average Nusselt number passed all statistical tests. Order of an individual effect upon a response has been evaluated and interaction effects have been determined. Numerical results indicated that heat transfer increased significantly with inserting pyramidal micro fins. © 2020 Elsevier B.V
Determination of Number and Location of Models to Improve Transient Response in a Multi-model Adaptive Control
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohammad (Supervisor)
Abstract
In recent decays, multiple model controllers have been attracted much attention due to their essential ability to control of non-linear systems with wide operating ranges. Number and location of models are two important factors. In this research an algorithm for determining number of models and their locations has been proposed which can be counted as an extension to existing algorithms. Utilizing the proposed algorithm, the minimum number of models which achieve closed-loop stability can be determined. If transient response of non-linear system with these models be not satisfactory, the number of models are increased by one using Binary Search method, and consequently the location of models...
Cross-Lingual Speaker Adaptation for Statistical Parametric Speech Synthesis
, M.Sc. Thesis Sharif University of Technology ; Sameti, Hossein (Supervisor)
Abstract
Speech synthesis and its applications have been very attractive recently. The main purpose of this technique is to produce a speech signal with natural characteristics of human speech like prosody and emotion. Among all existing methods for speech synthesis, statistical parametric speech synthesis methods are more promising because ofhigher flexibility in comparison to other methods. One of the applications of speech synthesis is speech to speech translation. In these systems, the generated voice in target language should have the same characteristics as the input voice in source language. The main purpose of this research is to review and evaluate the cross lingual speaker adaptation...
Hydroelastic Analysis of Surface Piercing Propeller
, M.Sc. Thesis Sharif University of Technology ; Seif, Mohamad Saeed (Supervisor)
Abstract
Surface piercing propellers are particular type of supercavitating propellers that are commonly used for High-speed vessels. Most studies on this type of propellers has been investigating the hydrodynamic forces. But in recent years with increase in SPPs diameter used in vessels, structural analysis of this type of propellers is considered. For this purpose, studies on the stresses exerted on the propeller structures under load is done with the help of Hydro elastic methods. In this type of analysis, structura of propeller is intended to be flexible and Displacements under pressure checked and Tensions resulting from it are studied.
The present Thesis using ANSYS software to analyze a...
The present Thesis using ANSYS software to analyze a...
Data-Driven Pricing Based on Demand Prediction Using Machine Learning Methods
, M.Sc. Thesis Sharif University of Technology ; Sedghi, Nafiseh (Supervisor)
Abstract
Pricing plays an important and essential role in the profit and income of companies. The importance of pricing is not only related to its role in the company's profitability, but it also changes the customer's understanding and loyalty towards the company and can create the company's reputation or destroy it. Determining the right price will increase product sales and increase customer loyalty and create a competitive advantage for the company. One of the most important and influential variables in product pricing is the amount of demand. The main challenge of companies for product pricing is the uncertainty in their demand. In order to deal with this problem, data-driven pricing is used....
Design of Low-Power Zero Temperature Coefficient (ZTC) CMOS Oscillators
, M.Sc. Thesis Sharif University of Technology ; Akbar, Fatemeh (Supervisor)
Abstract
The increasing demand for autonomous vehicles and reliable communication protocols and hardware interfaces, such as CAN bus and USB, underscores the necessity for stable clock sources that maintain a low temperature coefficient (TC) over wide temperature ranges. This demand is particularly emphasized in applications such as wearables, network sensors, downhole devices, WSNs, and IoT, where long-lasting battery life and frequency-stable clock sources over a broad temperature range (e.g. -20 °C to 100 °C) are crucial. Traditionally, variations in frequency caused by temperature have been mitigated by employing off-chip components like crystals or ceramic based oscillators, but this approach...
Design of Low Power Harmonic Rejection Mixer for Wideband Application
, M.Sc. Thesis Sharif University of Technology ; Akbar, Fatemeh (Supervisor)
Abstract
The increasing demand for communication bandwidth and limited spectrum availability have heightened the complexity of radio front-end circuits in IoT applications. Achieving spectral efficiency is a key challenge, particularly for IoT devices operating at specific frequency bands such as 315 MHz, 433 MHz, 868 MHz, and 915 MHz.Due to the limited linearity of the transmit path, harmonic distortion components, known as counter intermodulation (CIM) products, are generated. These CIM products can directly fall into the receiver (RX) band or enter it via cross-modulation, thereby degrading the frequency division performance. Additionally, CIM products can interfere with protected bands, violating...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Development of Hollow Cylinder Apparatus for Testing of Unsaturated Sandy Soils
, M.Sc. Thesis Sharif University of Technology ; Jafarzadeh, Fardin (Supervisor)
Abstract
The main purpose of this study is to develop the Hollow Cylinder Apparatus (HCA) for unsaturated testing on granular materials and to investigate the effect of stress anisotropy on dynamic parameters of soils like shear modulus and damping ratio. Direction of loading and the magnitude of intermediate principal stress have significant effect on the anisotropic response of soils. In many of in-situ loading the direction of major principal stress does not coincide with deposition direction of soil or because of the three dimensional loading condition of soil, the effect of the intermediate principal stress cannot be ignored. On the other hand, in many areas, soils are in unsaturated condition....
Visibility Testing of Uncertain Segments
, M.Sc. Thesis Sharif University of Technology ; Ghodsi, Mohammad (Supervisor)
Abstract
Evaluating the enviroment for achieving efcient kwnoledge in order to justifed environment recognition and making decision based on data analysis is proponed in many felds.One of these problems is Visibility Problem. The Recieved data from real world as input, for visibility problem, is uncertain such that the recieving data of two different measurments will be different with high probability. Therefore, we defne the goal of this research to solving the visibility problem conditioned to that objects or segments are uncertain.Consider ”S” as a set of ”n” uncertain segments in plane. Each uncertain segment locates in two certain places and with probability 1 2 in each place, the goal is to...
Chemical-Biological Phosphate Removal Using MBBR Bioreactors
, M.Sc. Thesis Sharif University of Technology ; Borgheei, Mahdi (Supervisor)
Abstract
Growing rate of eutrophication in receiving waters has made the enhancement of wastewater treatment plants to advanced methods of nutrients removal as necessary. Nitrogen and Phosphorus as the nutrients can reduce the quality of water and even make it unusable. Phosphorus is known to be one of the main reasons of eutrophication and creation of algal bloom. In this study, chemical-biological method for phosphate removal from the municipal wastewater is studied. Experiments are implemented for hydraulic retention times of 4, 8 and 16 hours, total intake concentration of phosphorus 7 ppm, COD 400 ppm and Nitrogen 25 ppm. Ferric Chloride as the precipitator chemical substance injected into the...
Enhancing Energy Efficiency in Ideal Binary Distillation tower with a Dynamic Process Intensification
, M.Sc. Thesis Sharif University of Technology ; Vafa, Ehsan (Supervisor)
Abstract
In this thesis titled "Enhancing Energy Efficiency in Ideal Binary Distillation tower with a Dynamic Process Intensification," operational methods in distillation units are explored and improved. Given the high cost of energy, limited energy resources, and environmental considerations, increasing energy efficiency in process industries has become significantly important. In this context, this research attempts to enhance the performance of the distillation unit by utilizing dynamic process intensification with two operational points corresponding to the production of products with purities both higher and lower than the desired product purity, and switching between these two points. The...
The Impact of AV and CAV Vehicles on Capacity and Traffic Flow with Cooperative Lane changing in Mixed Traffic Environment
, M.Sc. Thesis Sharif University of Technology ; Nassiri, Habibollah (Supervisor)
Abstract
Autonomous vehicles, as an integral part of intelligent transportation systems, will play a significant role in the future of transportation services. These vehicles have a high potential to improve road traffic capacity and the efficiency of transportation systems. One type of autonomous vehicle is the connected and autonomous vehicle (CAV), which can communicate with each other, roadside units, traffic control signals, and other infrastructures or devices. This study investigates the impact of autonomous vehicles and connected and autonomous vehicles on the traffic flow of the Tehran-Karaj freeway and vice versa, under various penetration rates and in a mixed traffic environment. In this...
The Impact of Integrated Prediction and Optimization on the the Bullwhip Effect in supply chains
, M.Sc. Thesis Sharif University of Technology ; Sedghi, Nafiseh (Supervisor)
Abstract
The Bullwhip effect is a phenomenon that refers to the amplification of demand variance as one moves upstream in a supply chain. This effect imposes additional costs on the supply chain and complicates inventory planning. Several factors contribute to the emergence of this phenomenon, one of which is demand forecasting. Since the demand faced by each level of the supply chain is uncertain, every level must first forecast demand in order to plan its inventory and meet customer requirements. However, this very process of forecasting contributes to the bullwhip effect. In this study, we investigate the impact of machine learning and deep learning forecasting methods, along with their...
An efficient approach to cathode operational parameters optimization for microbial fuel cell using response surface methodology
, Article Journal of Environmental Health Science and Engineering ; Vol. 12, issue. 1 , 2014 ; Vossoughi, M ; Alemzadeh, I ; Sharif University of Technology
2014
Abstract
Background: In the recent study, optimum operational conditions of cathode compartment of microbial fuel cell were determined by using Response Surface Methodology (RSM) with a central composite design to maximize power density and COD removal. Methods: The interactive effects of parameters such as, pH, buffer concentration and ionic strength on power density and COD removal were evaluated in two-chamber microbial batch-mode fuel cell. Results: Power density and COD removal for optimal conditions (pH of 6.75, buffer concentration of 0.177 M and ionic strength of cathode chamber of 4.69 mM) improve by 17 and 5%, respectively, in comparison with normal conditions (pH of 7, buffer concentration...
An experimental design approach to determine effects of the operating parameters on the rate of Ru promoted Ir carbonylation of methanol
, Article World Academy of Science, Engineering and Technology ; Volume 73 , March , 2011 , Pages 598-603 ; 2010376X (ISSN) ; Kazemini, M ; Mohammadrezaee, A ; Sharif University of Technology
2011
Abstract
carbonylation of methanol in homogenous phase is one of the major routesfor production of acetic acid. Amongst group VIII metal catalysts used in this process iridium has displayed the best capabilities. To investigate effect of operating parameters like: temperature, pressure, methyl iodide, methyl acetate, iridium, ruthenium, and water concentrations on the reaction rate, experimental design for this system based upon central composite design (CCD) was utilized. Statistical rate equation developed by this method contained individual, interactions and curvature effects of parameters on the reaction rate. The model with p-value less than 0.0001 and R 2 values greater than 0.9; confirmeda...
Optimisation of Ru-promoted Ir-catalysed methanol carbonylation utilising response surface methodology
, Article Applied Catalysis A: General ; Volume 394, Issue 1-2 , February , 2011 , Pages 166-175 ; 0926860X (ISSN) ; Kazemeini, M ; Mohammadrezaee, A ; Sharif University of Technology
2011
Abstract
In this study, central composite design (CCD) at five levels (-1.63, -1, 0, +1, +1.63) combined with response surface methodology (RSM) have been applied to optimise methanol carbonylation using a ruthenium-promoted iridium catalyst in a homogenous phase. The effect of seven process variables, including temperature, pressure, iridium, ruthenium, methyl iodide, methyl acetate and water concentrations, as well as their binary interactions, were modelled. The determined R 2 values greater than 0.9 for the rate and methane formation data confirmed that the quadratic equation properly fitted the obtained experimental data. The optimum conditions for maximum rate and minimum methane formation were...