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A highly sensitive and selective colorimetric method for detection of copper ions, based on anti-aggregation of D-penicillamine (D-PC) induced aggregated gold nanoparticles (AuNPs) was developed. Copper ions can hinder the aggregation of AuNPs induced by D-PC, through formation of mixed-valence complex with D-PC that is a selective copper chelator. In the presence of a fixed amount of D-PC, the aggregation of AuNPs decreases with increasing concentrations of Cu2+ along with a color change from blue to red in AuNPs solution and an increase in the absorption ratio (A520/A 650). Under the optimum experimental conditions (pH 7, [AuNPs] =3.0 nmol L-1 and [NaCl]=25 mmol L-1), a linear calibration... 

Herein, a sensitive, simple, and rapid colorimetric assay for the detection of pamidronate disodium was developed based on the aggregation of citrate-capped gold nanoparticles (AuNPs). This was exploited from the affinity of electron-rich atoms toward the surface of AuNPs, resulting in the aggregation of AuNPs through intermolecular hydrogen bonding interactions. As a result of aggregation under optimum conditions ([NaCl] = 25 mM, [AuNPs] = 3.3 nM and pH 7.0), the color of AuNPs was changed from red to blue and the plasmon band of AuNPs around 520 was decreased along with the formation of a new peak at a longer wavelength in the approximate range of 600 to 700 nm. The intensity ratios of... 

A modified carbon paste electrode was prepared by incorporating the TiO2 nanoparticles in the carbon paste matrix. The electrochemical behavior of gallic acid (GA) is investigated on the surface of the electrode using cyclic voltammetry and differential pulse voltammetry. The surface morphology of the prepared electrode was characterized using the scanning electron microscopy. The results indicate that the electrochemical response of GA is improved significantly at the modified electrode compared with the unmodified electrode. Furthermore, the capabilities of electron transfer on these two electrodes were also investigated by electrochemical impedance spectroscopy. Under the optimized... 

The authors regret “There are some meaningless letters at the beginning of the article's title. The authors would like to inform that the correct title is “Development of a pH assisted AgNP-based colorimetric sensor Array for simultaneous identification of phosalone and azinphosmethyl pesticides.” The authors would like to apologise for any inconvenience caused. © 2019 Elsevier B.V  

Development of simple and rapid methods for identification of pesticides, due to their broad usage and harmful effects on mammals, has been known as a critical demand. Herein, we have introduced a silver nanoparticle (AgNP)based colorimetric sensor array for simultaneous identification of Azinphosmethyl (AM)and Phosalone (PS)pesticides. In the presence of the target pesticides, unmodified AgNPs at various pHs (4.5, 5.5 and 9.5)showed different aggregation behaviors. As a result of aggregation, the color and UV–Vis spectra of AgNPs changed differentially, leading to distinct response patterns for AM and PS. The aggregation induced spectral changes of AgNPs, were used to identify AM and PS... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow and turbulent flow through rough pipes. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3] for couette problem and with known results from experiments done by Nikuradse (1932).the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000... 

Chromium is widely recognized as a significant pollutant discharged into the environment by various industrial activities. The toxicity of this element is dependent on its oxidation state, making speciation analysis crucial for monitoring the quality of environmental water and assessing the potential risks associated with industrial waste. This study introduces a single-well fluorometric sensor that utilizes orange emissive thioglycolic acid stabilized CdTe quantum dots (TGA-QDs) and blue emissive carbon dots (CDs) to detect and differentiate between various chromium species, such as Cr (III) and Cr (VI) (i.e., CrO42− and Cr2O72−). The variations of fluorescence spectra of the proposed probe... 

An indirect colorimetric method is presented for detection of trace amounts of hydroquinone (1), catechol (2) and pyrogallol (3). The reduction of AuCl4- to Gold nanoparticles (Au-NPs) by these phenolic compounds in the presence of cetyltrimethylammonium chloride (CTAC) produced very intense surface plasmon resonance peak of Au-NPs. The plasmon absorbance of Au-NPs allows the quantitative colorimetric detection of the phenolic compounds. The calibration curves derived from the changes in absorbance at λ = 568 nm were linear with concentration of hydroquinone, catechol and pyrogallol in the range of 7.0 × 10-7 to 1.0 × 10-4M, 6.0 × 10-6 to 2.0 × 10-4 M and 6.0 × 10-7 to 1.0 × 10-4 M,... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3].the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000 has beeen found. A new dimensionless number introduced that indicates the theoretical relation between cosserat theory and... 

In present paper the theory of the micropolar fluid based on a Cosserat continuum model has been applied for analysis of Couette flow. The obtained results for the velocity field have been compared with known results from experiments done by Reichardt at Max Plank institute for fluids in Gottingen [1,2] and analytical solution of the problem from Gradient theory by alizadeh[3].the boundary condition used here was the no slip one and Trostel's slip boundary condition[4].a good agreement between experimental results and the results of the problem for Reynolds near 18000 has beeen found. A new dimensionless number introduced that indicates the theoretical relation between cosserat theory and... 

The potential of hydrogen (pH) is a basic and critical parameter representing the function of numerous chemicals/biomolecules. Due to the widespread applications of pH in diverse fields, the development of rapid and simple yet reliable probes for the determination of pH has attracted significant interest. In this paper, by using AuNRs, silver ions, and ascorbic acid as colorimetric pH sensor, a multicolorimetric nanosensor is described for pH measurement. The reduction of silver ions by ascorbic acid which is strongly influenced by pH, results in silver nanoshell deposition on the surface of AuNRs. Consequently, the formation of Au@Ag core-shell NRs causes a series of blue shifts in the... 

The gravity currents on the inclined boundaries are formed when the inflow fluid has a density difference with the ambient fluid and a tangential component of gravity becomes the driving force. If the density difference arises from the suspension of particles, the currents are known as particle-driven density currents, in which the local density of the gravity current depends on the concentration of particles. A low Reynolds k-ε turbulence model is used to simulate three dimensional turbidity currents. Also a laboratory apparatus was built to study the 3D flow resulting from the release of particle laden density currents on a sloping surface in a channel of freshwater via a sluice gate and... 

Flows generated by density differences are called gravity or density currents which are generic features of many environmental flows. These currents are classified as the conservative and non-conservative flows whether the buoyancy flux is conserved or changed respectively. In this paper, a low Reynolds k-ε turbulence model is used to simulate three dimensional density and turbidity currents. Also, a series of experiments were conducted in a straight channel to study the characteristics of the non-conservative density current. In experiments, Kaolin was used as the suspended material. Comparisons are made between conservative and non-conservative's height, concentration and velocity profiles... 

Pattern-based sensing with multi-component sensor arrays, despite its merits, may be laborious and time-consuming. As an alternative approach, herein, a condition-based single component sensor array has been provided which represents an elegantly simple, low cost and minimally instrumented format for the quantification and classification of antidepressants (ADs). Tuning the pH and ionic strength enabled the single component probe to interact with the target analytes through different binding modes, providing the required cross-reactivity for multiplex detection. The analytical figures of merit verified that the condition-based sensor array is precise and accurate in both the discrimination... 

The development of inexpensive, equipment-free, portable, and user/environmentally-friendly analytical devices that can be efficiently utilized for on-site detection of PA is still a great challenge. To address these unmet demands, we have developed a smartphone-based disposable sensing bioplatform through immobilization of chlorophyll in a cotton thread for fluorescent monitoring of picric acid (PA). The fluorescence quenching of chlorophyll upon increasing the PA concentration based on the inner filter effect was considered as the sensing strategy in the developed sensor. The fabricated thread-based microfluidic sensing bioplatform was further coupled with a compact, low cost, portable,... 

An efficient heterogeneous palladium catalyst system has been developed based on immobilization of Pd nanoparticles on silica-bonded N-propylpiperazine (SBNPP) substrate. SBNPP substrate can stabilize the Pd nanoparticles effectively so that it can improve their stability against aggregation. Also, grafted piperazine species onto the silica backbone prevents the removing of Pd nanoparticles from the substrate surface. It seems that the high recyclable capability of Pd-SBNPP catalysts is resulted from these two characteristics. Transmission electron microscopy (TEM) of catalyst is shown the size of Pd nanoparticles in Pd-SBNPP average of 20 nm. Furthermore, X-ray photoelectron spectroscopy... 

In this work, a colorimetric sensor array has been designed for the identification and discrimination of thiometon (TM) and phosalone (PS) as organophosphate pesticides and prothioconazole (PC) as a triazole pesticide. For this purpose, two different plasmonic nanoparticles including unmodified gold nanoparticles (AuNPs) and unmodified silver nanoparticles (AgNPs) were used as sensing elements. The principle of the proposed strategy relied on the aggregation AuNPs and AgNPs through the cross-reactive interaction between the target pesticides and plasmonic nanoparticles. Therefore, these aggregation-induced UV–Vis spectra changes were utilized to discriminate the target pesticides with the... 

Most nanoparticle based colorimetric sensor array utilize several sensor elements and static response for discrimination of target analytes. This approach can be complicated and costly to synthesize or functionalize different nanoparticles for providing wide color variation. Herein, triangular silver nanoparticles (TSNPs) were used to develop a colorimetric sensor array by time-dimension responses. The principle of this sensor array is based on the diverse etching process of TSNPs in the presence of three halide ions, including bromide (Br−), iodide (I−) and chloride (Cl−). Various etchings of TSNPs induced color changes at different reaction time intervals, which produced a colorimetric... 

The unique optical properties of plasmonic gold (Au) and silver Ag) nanoparticles (NPs) due to localized surface plasmon resonance (LSPR), surface modifications of Au and Ag NPs through non-covalent/covalent conjugations, and their applications in colorimetric detection of various ionic and neutral analytes are discussed in this chapter. The chapter begin with the basics of LSPR phenomenon, and then the effects like surrounding medium, composition, size, shape, structural configuration and interparticle coupling that influenced the LSPR of Au and Ag NPs are discussed. The different design principles for colorimetric assays using plasmonic Au and Ag NPs, such as analyte-induced aggregation... 

In the ratiometric fluorescent (RF) strategy, the selection of fluorophores and their respective ratios helps to create visual quantitative detection of target analytes. This study presents a framework for optimizing ratiometric probes, employing both two-component and three-component RF designs. For this purpose, in a two-component ratiometric nanoprobe designed for detecting methyl parathion (MP), an organophosphate pesticide, yellow-emissive thioglycolic acid-capped CdTe quantum dots (Y-QDs) (analyte-responsive), and blue-emissive carbon dots (CDs) (internal reference) were utilized. Mathematical polynomial equations modeled the emission profiles of CDs and Y-QDs in the absence of MP, as...