Sharif Digital Repository

A novel technique based on image processing inspired by the simple assumption for the first time to assess the roughness of nanofibrous mats based on grayscale variations is proposed. The height of a nanofibrous mat in different regions of the surface is simulated by grayscale variations in the image while the relation between grayscale and height is obtained as a linear function. The roughness is obtained by measuring height variations in the surface profile. Statistical roughness parameters of nanofibrous mats are also obtained from direct measurement with roughness profilometry and atomic force microscopy (AFM) for comparison of the roughness of nanofibrous mats between direct measurement... 

High-performance wearable electronic devices with the capability of converting mechanical force into electrical energy have been gaining increasing attention for biomedical monitoring applications. We present a novel wearable piezoelectric sensor based on a poly(vinylidene fluoride) (PVDF) nanofibrous membrane containing microporous zirconium-based metal-organic frameworks (MOFs) for arterial pulse monitoring. It is shown that the incorporation of 5 wt % of MOF greatly enhances the piezoelectric constant of the polymer fibrous mat by 3.4-fold without significant loss in its flexibility. The nanofibrous composite exhibits a peak-to-peak voltage of 600 mV under an applied force of 5 N, which... 

A novel technique based on image processing inspired by the simple assumption for the first time to assess the roughness of nanofibrous mats based on grayscale variations is proposed. The height of a nanofibrous mat in different regions of the surface is simulated by grayscale variations in the image while the relation between grayscale and height is obtained as a linear function. The roughness is obtained by measuring height variations in the surface profile. Statistical roughness parameters of nanofibrous mats are also obtained from direct measurement with roughness profilometry and atomic force microscopy (AFM) for comparison of the roughness of nanofibrous mats between direct measurement... 

Herein, a magnetic zirconium-based metal-organic framework nanocomposite was synthesized by a simple solvothermal method and used as an adsorbent for the removal of direct and acid dyes from aqueous solution. To enhance its adsorption performance, poly(propyleneimine) dendrimer was used to functionalize the as-synthesized magnetic porous nanocomposite. The dendrimer-functionalized magnetic nanocomposite was characterized by field-emission scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption/desorption isotherms, and vibration sample magnetometer. The obtained results revealed the successful synthesis and functionalization of the... 

Comparative studies between response surface methodology (RSM) and artificial neural network (ANN) methods to find the effects of electrospinning parameters on the porosity of nanofiber mats is described. The four important electrospinning parameters studied included solution concentration (wt.%), applied voltage (kV), spinning distance (cm) and volume flow rate (mL/h). It was found that the applied voltage and solution concentration are the two critical parameters affecting the porosity of the nanofiber mats. The two approaches were compared for their modeling and optimization capabilities with the modeling capability of RSM showing superiority over ANN, having comparatively lower values of... 

A novel rotary magnetohydrodynamic (MHD) (RMHD) micropump is presented in this paper in order to both benefit exclusive advantages from the MHD micropumps and eliminate the current obstacles in their implementation. Lorentz force, which is the actuation mechanism in RMHD, is used to propel a mercury slug in a circular microchannel in order to suck the working fluid from the inlet and pump it to the outlet. This idea is integrated with a valve which prevents the working fluid from passing through, while allowing the mercury slug to pass, during each pumping loop. The performance of a fabricated RMHD is evaluated, considering parameters such as pressure difference, running duration, electric... 

A novel molecularly imprinted xerogel (MIX) based on organically modified silica (ORMOSIL) was successfully prepared for on-line capillary microextraction (CME) coupled with high-performance liquid chromatography (HPLC). The sol-gel-based xerogel was prepared using only one precursor and exhibited extensive selectivity towards triazines along with significant thermal and chemical stability. Atrazine was selected as a model template molecule and 3-(trimethoxysilyl)propylmethacrylate (TMSPMA) as a precursor in which the propylmethacrylate moiety was responsible for van der Waals, dipole-dipole, and hydrogen-bond interactions with the template. This moiety plays a key role in creation of... 

This review is mostly focused on the recently emerged methodologies for preparing the appropriate extracting media with enhanced capacity, stability and selectivity, which could be used in capillary microextraction (CME). We particularly consider conductive polymers, sol-gel-based materials, monolithic coatings, molecularly-imprinted polymers and xerogels. Moreover, we discuss recent advances in configuration of CME, array capillaries and unbreakable substrates  

Fluid control, namely pumping and valving, is a critical factor in the performance of micro-fluidic systems. In recent years a variety of micro-fluidic systems are developed for the purpose of miniaturizing fluid handling, and chemical analysis to develop Lab On a Chip (LOC) technology. The mentioned facts resulted in design and fabrication of a novel hydromagnetic flow controller. The idea behind this device is that magnetic particles, mixed and dispersed in a carrier liquid, can be accumulated in the form of a piston. Depending upon dragging speed of these pistons, which itself is a function of switching time, this device can be used to either increase (pumping) or decrease (valving) the... 

The traditional approach to origin-destination (OD) estimation based on data surveys is highly expensive. Therefore, researchers have attempted to develop reasonable low-cost approaches to estimating the OD vector, such as OD estimation based on traffic sensor data. In this estimation approach, the location problem for the sensors is critical. One type of sensor that can be used for this purpose, on which this paper focuses, is vehicle identification sensors. The information collected by these sensors that can be employed for OD estimation is discussed in this paper. We use data gathered by vehicle identification sensors that include an ID for each vehicle and the time at which the sensor... 

Finding the optimal location for sensors is a key problem in flow estimation. There are several location models that have been developed recently for vehicle identification (ID) sensors. However, these location models cannot be applied to large networks because there are many constraints and integer variables. Based on a property of the location problem for vehicle ID sensors, given the initial vehicle ID sensors that are pre-installed and fixed on the network, this article presents a solution that greatly reduces the size of this location problem. An applied example demonstrates that when 8% of the arcs from a real network that are randomly selected have a vehicle ID sensor, the reductions... 

Finding the optimal location for sensors is a key problem in flow estimation. There are several location models that have been developed recently for vehicle identification (ID) sensors. However, these location models cannot be applied to large networks because there are many constraints and integer variables. Based on a property of the location problem for vehicle ID sensors, given the initial vehicle ID sensors that are pre-installed and fixed on the network, this article presents a solution that greatly reduces the size of this location problem. An applied example demonstrates that when 8% of the arcs from a real network that are randomly selected have a vehicle ID sensor, the reductions... 

A novel technique based on image processing inspired by the simple assumption for the first time to assess the roughness of nanofibrous mats based on grayscale variations is proposed. The height of a nanofibrous mat in different regions of the surface is simulated by grayscale variations in the image while the relation between grayscale and height is obtained as a linear function. The roughness is obtained by measuring height variations in the surface profile. Statistical roughness parameters of nanofibrous mats are also obtained from direct measurement with roughness profilometry and atomic force microscopy (AFM) for comparison of the roughness of nanofibrous mats between direct measurement... 

The raising trend both in violent and property crime are of major concern in Iran. Using a panel data modeling (province wide), the paper provides an econometrics assessment of the relationship between crime against properties and violent crimes as functions of deterrent, social, economic and demographic factors in Iran, in the framework of Becker-Ehrlich crime supply theory. The findings indicate that, although deterrence hypothesis is not confirmed for burglary and assault, it explains the variations of murders and threats. Economic factors play key role in burglary and threat explanation, but they do not affect willful murders, however, Literacy explains both murders and threats. Average... 

The results of three cases of two consecutive reactors are studied in two types of co-current and counter-current flow in second reactor where two consecutive reactors are oxidative coupling of methane (OCM) and Fischer-Tropsch (FT) reactors. FT reactor can be fixed bed or membrane fixed bed reactor with a hydrogen perm-selective membrane. Effect of CH4/O2 ratio, contact time, inlet temperature, and amount of N2 in OCM feed on C2 to C5+ hydrocarbons produced in FT reactor were studied. Results show that use of counter-current hydrogen-perm selective membrane FT reactor that sequenced after OCM reactor improves the C5+ yield as a desirable product and reduces the amount of CH4 and CO2 as... 

Due to great commercial application of protease, it is necessary to study kinetic characterization of this enzyme in order to improve design of enzymatic reactors. In this study, mathematical modeling of protease enzyme production kinetics which is derived from Bacillus licheniformis BBRC 100053 was studied (at 37°C, pH 10 after 73 h in stationary phase, and 150 rpm). The aim of the present paper was to determine the best kinetic model and kinetic parameters for production of protease and calculating K i (inhibition constant) of different inhibitors to find the most effective one. The kinetic parameters K m (Michaelis-Menten constant) and V m (maximum rate) were calculated 0.626 mM and... 

The novel idea of the Hydromagnetic Micropump and Flow Controller (HMFC) is used in this paper to construct a laboratory setup capable of bidirectional pumping and controlling the flow in microtubes. A laboratory setup, which contains no moving parts, is integrated with a pressure-driven flow setup to make the presented HMFC device. The device operation is based on controllable motion of magnetic particles, added to the carrier fluid, caused by the magnetic field, produced by solenoids located just next to the microtube. The magnitude of these forces is proportional to the strength and gradient of magnetic field which, in turn, is related to the electrical current and arrangement of the... 

The effects of applied magnetic and electric fields on electrospinning were investigated to produce more efficient nanofibers. Considering the previous extensive studies, polyamide nanofibers were prepared by a conventional approach and under auxiliary electric and magnetic fields. The first sorbent was synthesized by electrospinning of a solution of 18% polyamide in formic acid. The second and third types of polyamide were prepared similarly while the electrospinning processes were assisted by an electric and a magnetic field. The third type of polyamide contained a magnetic ionic liquid (MIL) to induce sufficient magnetic susceptibility in the polymeric solution. The SEM images revealed... 

An on-line extraction/determination set up was designed for micro solid-phase extraction of clodinafop propargyl from water, soil and wheat samples using electrospun polyamide nanofiber mats. The prepared mats were packed in a stainless steel tube which conveniently acted as a high-performance liquid chromatography injection loop. Influential parameters affecting the extraction efficiency were optimized using a distilled water sample fortified with 25 μg L-1 of clodinafop propargyl. An enrichment factor of 440 was achieved for clodinafop propargyl indicating the ability of the whole procedure. Under the optimum conditions, the linearity for the analyte was in the range of 6-700 μg L-1, while...