Sharif Digital Repository

Ruthenium complexes with their wide range of stable but chemically accessible oxidation states have been extensively studied as catalyst of hydrocarbon oxidation. In recent years, these complexes with various ligands have been reported as new catalysts with better selectivity and several co-oxidations. Ruthenium complexes act as oxidation catalyst, often via ruthenium-oxo species as active intermediates in the oxygen transfer process, oxidizing alcohols or alkanes and epoxidizing alkane. Here, we reported the synthesis and catalytic activity of a ruthenium(III) complex with bidentate oxazine ligand. The new synthesized Ru(III)-oxazine complex was characterized by IR and UV-Vis spectra and... 

In this study, Al-20Si-5Fe ribbons produced by melt-spinning method. Nanostructure and growth morphology of rapidly solidified products explored using optical microscope, scanning electron microscope and x-ray diffraction. Microstructural investigations depicted two distinctive zones of featureless (faceted morphology) and dendritic. In addition, no intermetallic phases could be observed in the rapidly solidified ribbons in comparison with coarsed and needle shaped intermetallic phases of as cast alloys which it demonstrates the extension of solid solubility of Si and Fe in the matrix and consequently intermetallics formation was hindered by higher cooling rates. Subsequently, ribbons... 

n the present study, the optimal design of feeding system in steel sand-mold castings is considered. The first part of this research includes fundamental studies on the physics of shrinkage defect formation during the casting process. The results of these studies lead to new findings on the mechanism of shrinkage defect formation, effect of melt quality on the distribution of defects within the castings and the connection between shrinkage and gases defects. The theoretical analysis of thermal criterion functions for the prediction of shrinkage defects in castings and introducing new criterion function with fewer shortcomings can be accounted as the other finding of this part. A new model... 

Grobner bases were introduced by Bruno Buchberger in 1965. The terminology acknowledges the influence of Wolfgang Grobner on Buchberger’s work. He introduced a specific generator for ideals in the ring of polynomials over a field and then gave an algorithm for computing of that generator. It leads to solutions to a large number of algorithmic problems that are related to polynomials in several variables. Most notably, algorithms that involve Grobner basis computations allow exact conclusions on the solutions of systems of nonlinear equations, such as the (geometric) dimension of the solution set,the exact number of solutions in case there are finitely many, and their actual computation with... 

In this research ,Al-20Si-5Fe-3Cu-1Mg-XMn alloys were produced by gas atomizing and melt spinning processes. Microstructure and growth morphology of powder and ribbons were investigated using optical microscopy , scanning electron microscopy. powders were hot pressed at 400ºC/250Mpa and microstractural variations, mechanical properties were evaluated after consolidation. Results show that relatively high cooling rate in gas-atomized powders lead to refinement of microstructure and formation of semi-equilibrium δ intermetallic phase . As the powder particle size decrease , the growth morphology changes from primary silicon + euthectic to euthectic + primary dendritic aluminum . Mn changed the...