Sharif Digital Repository

The effects of addition of an ionic liquid to pure water as a physical absorbent and monoethanolamine (MEA) solutions as a chemical absorbent on carbon dioxide (CO2) absorption through hollow fiber membrane contactors were investigated using a 2D axisymmetric model. A numerical simulation was developed based on finite element method using computational fluid dynamics techniques. Liquid phase flowed in the tube side and gas mixture containing CO2 passed in the shell side of the membrane contactor in co-current and countercurrent modes. The simulation results are consistent with experimental data, and the root-mean-square error was calculated as 9 and 13% for pure water and 25 wt % for ionic... 

In the present work, a simple, green, rapid, and catalyst-free procedure for the synthesis of benzamide derivatives by ring opening of azlactones with diamines such as ethylene diamine and 1,3-propylenediamine is described. The present method offers several advantages such as short reaction times, easy work-up, and mild reaction conditions in the absence of catalyst and any toxic solvent and material. In addition, the structure obtained by X-ray crystallography was compared with the theoretical results obtained by density functional theory using the B3LYP functional and cc-pVDZ basis sets  

In this study, the effect of hydrophobicity of environmentally responsive surface-modified silica nanoparticles on the stability and surface activity of the nanoparticles is examined. To this end, n-propyl, n-hexyl, or n-octyl chains and methoxy poly(ethylene glycol) chains at various quantities were coated covalently on the surface of silica nanoparticles to regulate the hydrophobicity of the responsive nanoparticles. Various experimental tools such as stability analysis, interfacial-tension and contact-angle measurements, and emulsion formation were performed to investigate the effect of hydrophobicity. It became evident that the presence of the hydrophobic agents influences considerably... 

Problems related to the three-dimensional (3D) dynamics of the deploying flexible arms subjected to base angular motions are studied with simulated tip payloads and actual deployment trajectories. To facilitate the solution, an equivalent dynamical system is developed by introducing the inertial reaction forces on the arm, while the equations of motion are derived in the non-Newtonian reference frame attached to the arm. The dynamic behavior of the arm is investigated both by the finite element and assumed Modes methods for the purpose of verification. This study reveals that base angular motions lead to considerable couplings between the two lateral displacements and axial motions.... 

The loads induced on the spacecraft orbiting the Earth by the deploying elastic arm are investigated. The coupled equations of motion of the arm with the vehicle orbital mechanics are used to describe the 3D dynamic behavior of the flexible-appendage and the related disturbing loads induced on the spacecraft. To this end, an equivalent dynamical system is derived for the arm by applying an attached Non-Newtonian Reference Frame which is subjected to the orbital motion and geocentric pointing maneuver of the spacecraft. With the help of the Assumed Modes Method, the behavior of the arm attached to the spacecraft in Keplerian orbits is studied. The results show that deploying the arm in some... 

Deployment inertial effects of a spacecraft appendage on its flexible dynamics are investigated. The Euler-Bernoulli beam theory and the actual deployment profile, in which appendage axial motion accelerates from static state and then decelerates to end at zero velocity and acceleration, are employed. The study is concentrated on the arm dynamic stiffness introduced by inertial effects of the arm deployment, and the resultant effects on the arm flexible motions. Lagrange's equations and some appropriate shape functions in the series approximation method are employed to study the arm lateral elastic displacements. Finally a system of ordinary differential equations with time varying... 

The dynamics of the flexible robot arm subjected to tip mass during an actual deployment is studied. The Euler-Bernoulli beam theory and the real deployment are considered in the simulation. A new real axial velocity profile is developed. This new suggested profile simulates the actual deployment such that the arm movement starts from immovability and after attaining the final required length comes back again to the static state. Using Lagrange's equation, the equations of motion of the system are derived to study the system dynamics in this suggested deployment profile. A series approximation is used to represent the lateral elastic displacements. Using variables separation and also some... 

A thorough investigation of the dynamics of finite-mass satellites with a deployable elastic arm is presented. This work is focused on the interaction between spacecraft rigid body motion and its flexible arm dynamics during the deployment process. The classical Newton–Euler formulation and the Lagrangian approach are applied to the study of the dynamics of spacecraft and its deploying arm. Utilizing a non-Newtonian floating frame to define the arm elastic deformation field, the interactions between the spacecraft and its moving arm have been simulated. Complete equations of motion show that the spacecraft motion induces dynamical stiffness on the arm; in addition, axial and lateral motions... 

A thorough investigation of the dynamics of finite-mass satellites with a deployable elastic arm is presented. This work is focused on the interaction between spacecraft rigid body motion and its flexible arm dynamics during the deployment process. The classical Newton–Euler formulation and the Lagrangian approach are applied to the study of the dynamics of spacecraft and its deploying arm. Utilizing a non-Newtonian floating frame to define the arm elastic deformation field, the interactions between the spacecraft and its moving arm have been simulated. Complete equations of motion show that the spacecraft motion induces dynamical stiffness on the arm; in addition, axial and lateral motions... 

Approximate solutions for vibrations of flexible beam-type appendages subjected to tip mass are studied while uniform and exponential profiles for arm deployment are simulated. Applying an equivalent dynamical system and following Lagrangian approach, the equations of motion of the system are derived as nonlinear ordinary differential equations (ODEs) (with time-varying coefficients), in which the effect of the tip mass can be considered as some nonlinearity added to the 'no tip mass' case dynamics. The approximate closed-form solutions are obtained through a novel methodology using a computer algorithm, in which the solutions of the 'no tip mass' case are expanded by imposing quadratic... 

The influence of the addition of the nonionic surfactants C12DMPO, C14DMPO, C10OH, and C10EO5 at concentrations between 10-5 and 10-1 mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10-5 mmol/L on the dilational surface rheology is studied. A maximum in the viscoelasticity modulus |E| occurs at very low surfactant concentrations (10-4 to 10-3 mmol/L) for mixtures of BCS with C12DMPO and C14DMPO and for mixtures of BLG with C10EO5, while for mixture of BCS with C10EO5 the value of |E| only slightly increased. The |E| values... 

This paper presents synthesis and photophysical investigation of a very rare type of the ReI diimine complexes, [Re(diimine)(CO)3(OPR3)]+, R = Ph, Cy; diimine – phenanthroline and neocuproine, containing monodentate (unsupported) phosphine oxide ligands. The obtained compounds have been structurally characterized in solid phase by using XRD crystallography, which revealed unusual distortions in the pseudo octahedral rhenium environment, which may be ascribed to intramolecular interligand (phosphine oxide – diimine) interaction rather than to crystal packing effect. Optimization of the ground state structure of these molecules with the DFT method also confirmed intramolecular origin of the... 

In the present work we obtained a series of NIR luminescent platinum(II) complexes with a pincer N^N^C ligand based on the conjugated {benzoimidazo[1,2-a]pyrazine} system with the [Pt(N^N^C)L]n+ structural motif (L = phosphine, alkynyl or pyridine-type ligands). We have also synthesized two complexes with bidentate phosphines that demonstrate different types of coordination: 1) as chelating ligand (in case of 1,2-bis(diphenylphosphino)benzene), that led to de-coordination of pyridine ring of N^N^C ligand and formation of a [Pt(N^C)dppb]+ complex; 2) as a bridging ligand (in case of bis(diphenylphosphino)methane) between two {Pt(N^N^C)} fragments in a dimeric complex of type... 

Ultrasonic metal welding is a solid-state welding process being widely employed for joining the interconnections of lithium-ion batteries in hybrid and plug-in hybrid vehicles. Examining the microstructure of the joint is of crucial importance to evaluate the performance. This analysis allows a comprehensive understanding of the phenomena influencing the joint strength. In this study, ultrasonic welding was utilized to join copper to aluminum sheets of 0.3 mm thickness, and then the macro- and microstructural characteristics of the weld cross-section and interface were thoroughly investigated. Finally, the microstructural changes at different values of ultrasonic welding parameters were... 

As a solid-state welding method, ultrasonic welding of metals is widely used in different industries to produce high-performance materials such as lithium-ion batteries. This research aims to investigate and optimize the variables of ultrasonic metal welding to reach a maximum joint strength. The influence of welding time, welding pressure, and oscillation amplitude on the maximum load of tensile-shear and T-peel tests of dissimilar ultrasonic metal welding of aluminum 1050 and copper (purity above 99.9%) having a thickness of 0.3 mm has been investigated. Design Expert software and response surface method (RSM) have been used to obtain the optimal mode of welding parameters and check their... 

The fate of the immobilized actinides of the spent nuclear fuel in mineral-like matrices can be predicted by studying the behavior of uranium isotopes as representatives of the actinides in natural analogues. This work deals with the thermochemical behavior of uranium isotopes, which is accompanied by a redox process within the 25–800 °C temperature range in the metamict natural analogue of polycrase. The pattern of the changes in the relative contents of the U(IV) and U(VI) fractions at various temperatures was determined by a radiochemical analysis. The accuracy of the U(IV) and U(VI) values using the method of the chemical shift of the energy on the Lα1 X-ray emission line was verified....