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Improve Privacy in Trust Management
, M.Sc. Thesis Sharif University of Technology ; Hemmatyar, Ali Mohammad Afshin (Supervisor)
Abstract
Today, with the widespread use of decentralized systems, many people interact with each other and this interaction can endanger their safety. Therefore, the strategy should be to keep people safe. Interaction with a trusted and highly recommended people is essential and this is considered the first step toward security. Privacy preserving is critical in Successful operation of reputation system, in other words, the trust value should not be available. This method can prevent from positive and negative feedback of people because one person (may be due to personal animosity or to lack of commitment or person discomfort) can manipulate the trust value. For this reason, the trust value should be...
Investigation of the corrosion inhibition properties of hexamine (HMTA) for mild steel in NaCl solution
, Article Materials Protection ; Volume 64, Issue 2 , 2023 , Pages 134-152 ; 03519465 (ISSN) ; Ghorbani, M ; Sharif University of Technology
Engineers Society for Corrosion
2023
Abstract
An effective corrosion inhibitor for steel is Hexamine (HMTA). There have been few studies on its corrosion-inhibiting characteristics, particularly in NaCl solution. The electrochemical characteristics of HMTA performance in NaCl 3.5 wt% solution were examined during this study. Additionally, the properties of the HMTA film on the steel surface was investigated. When tested in NaCl solution, electrochemical results revealed that HMTA is a very efficient corrosion inhibitor for mild steel, with an efficacy of 92% at a concentration of 0.08 M. HMTA exhibited mixed type activity in terms of inhibition, according to the findings. Due to the physical adsorption of HMTA compound, as shown by the...
Fabrication of Smart pH-Responsive Nanocontainers for Corrosion Protection of Mild Steel
, Article Protection of Metals and Physical Chemistry of Surfaces ; Volume 59, Issue 4 , 2023 , Pages 763-777 ; 20702051 (ISSN) ; Ghorbani, M ; Sharif University of Technology
Pleiades Publishing
2023
Abstract
Abstract: Intelligent pH-sensitive nanocontainers were successfully constructed employing the Layer by Layer (LbL) approach. FESEM, HRTEM, EDS, elemental mapping, zeta-potential, FTIR, TGA, SIMS, UV–Vis, and Tafel polarization examinations were subsequently performed on the nanocontainers. Following the LbL procedure, imaging evaluation using FESEM and HRTEM revealed a 42 percent increase in the diameter of SiO2 nanoparticles with a halo view. The effective layer implantation was confirmed by EDS, elemental mapping, and zeta potential recording. Electrostatic interactions between Hexamine (HMTA) compounds and distinct layers were discovered using FTIR. Nanocontainers were found to contain...
Manufacturing of a Smart Coating by Using SiO2 Nanoparticles and Hexamine
, Article Corrosion ; Volume 79, Issue 6 , 2023 , Pages 665-682 ; 00109312 (ISSN) ; Ghorbani, M ; Sharif University of Technology
Association for Materials Protection and Performance
2023
Abstract
Recent years have seen a significant increase in interest in smart anticorrosion coatings, which can detect corrosive situations and autonomously discharge corrosion inhibitors. The mild steel surface was coated with pH-sensitive nanocontainers that had been manufactured and doped into an epoxy coating. Elemental mapping, thermogravimetric analysis/differential scanning calorimetry, and electrochemical impedance spectroscopy (EIS) methods were used to examine dispersion homogeneity, thermal durability, and corrosion tolerance. The findings indicated that nanocontainers dispersed uniformly in epoxy and that doping nanocontainers had no effect on the epoxy properties. When immersed in NaCl...
Enhancement of Optical Absorption and Water Oxidation Reaction in One Dimensional Nanostructured Hematite Photoanodes
, M.Sc. Thesis Sharif University of Technology ; Naseri, Naimeh (Supervisor)
Abstract
Hydrogen is known to be a renewable and clean source of energy, which produces water vapor and zero carbon dioxide as a result of its combustion. Photoelectrochemical water splitting (PEC) could be a promising approach in order to generate hydrogen by sunlight. Hematite (α-Fe2O3), as the most abundant naturally occurring form of iron oxide with suitable band gap, low cost, high stability and nontoxicity is considered to be an ideal photoanode. However, intrinsic drawbacks of hematite including low electrical conductivity, limited hole diffusion length, and high recombination rate of electron-hole pairs restrict its photoelectrochemical performance efficiency. In the present research,...
Hydrazine-modified starch coated magnetic nanoparticles as an effective pH-responsive nanocarrier for doxorubicin delivery
, Article Journal of Industrial and Engineering Chemistry ; Volume 39 , 2016 , Pages 203-209 ; 1226086X (ISSN) ; Hosseini, S. H ; Pourjavadi, A ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2016
Abstract
A novel, magnetic nanocarrier was successfully synthesized through a facile and economical producer in which Fe3O4 magnetic nanoparticles were coated by starch-g-poly (methyl methacrylate-co-PEG-acrylamide). The surface of nanocarrier was then modified by hydrazine to preparation of a pH-responsive carrier. The resulted nanocarrier was applied for delivery of doxorubicin (DOX) as an effective anti-cancer drug. DOX was reacted with hydrazine linkage on the surface of nanocarrier to form hydrazone bond. Due to the presence of numerous hydrazine groups on the surface of magnetic nanocarrier large amounts of DOX was loaded onto the carrier (327 mg g−1). © 2016 The Korean Society of Industrial...
Evaluation of differentiation quality of several differentiation inducers of bone marrow-derived mesenchymal stem cells to nerve cells by as-sessing expression of beta-tubulin 3 marker: A systematic review
, Article Current Stem Cell Research and Therapy ; Volume 16, Issue 8 , 2021 , Pages 994-1004 ; 1574888X (ISSN) ; Zahedi, F ; Hashemi, Z. S ; Khalili, S ; Sharif University of Technology
Bentham Science Publishers
2021
Abstract
Neurological diseases have different etiological causes. Contemporary, developing an ef-fective treatment for these diseases is an ongoing challenge. Cell therapy is recognized as one of the promising solutions for the treatment of these diseases. Amongst various types of stem cells, bone marrow-derived mesenchymal stem cells (BM-MSC) are known to be the most widely used stem cells. These cells are endowed with appealing properties such as the ability to differentiate into other cell types, including the muscle, liver, glial, and nerve cells. In this review study, we have systematically evaluated the ability of a variety of chemical compounds used in the last ten years to differentiate...
Smart Coating Incorporated with Inhibitor-Enclosed Nanocontainers for Corrosion Protection of Steel
, Ph.D. Dissertation Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
In this thesis a smart anticorrosive pH-responsive coat was developed with layer by layer (LbL) technique in the assembly of SiO2/CTAB/PSS/HMTA/PSS/PEI/PSS. SiO2 nanoparticles were prepared from Matland Company (Iran) with average size of 24 nm. At first, the corrosion inhibition of HMTA for API 5L Grade B steel in 3.5 wt.% NaCl solution was investigated. Tafel polarization technique showed the optimum concentration of HMTA was 0.08 M with 92% corrosion inhibition efficiency as the morphology of coverage and adsorption on the steel surface was confirmed by SEM and EDS. AFM results showed the roughness of the surface decreased from 241 nm to 56 nm that is attributed to HMTA adsorption on the...
Cross-linked poly (dimethylaminoethyl acrylamide) coated magnetic nanoparticles: a high loaded, retrievable, and stable basic catalyst for the synthesis of benzopyranes in water
, Article RSC Advances ; Vol. 4, issue. 91 , 2014 , p. 50047-50055 ; Hosseini, S. H ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
2014
Abstract
A novel heterogeneous catalyst has been synthesized based on the distillation-precipitation-polymerization of methyl acrylate onto modified magnetic nanoparticles followed by the amidation of the methyl ester groups using N,N-dimethylethylenediamine. The resulting poly(dimethylaminoethyl acrylamide) coated magnetic nanoparticles (MNP@PDMA) catalyst was characterized using an array of sophisticated analytical techniques, including FT-IR, TGA, SEM, TEM, CHN, vibrating sample magnetometer (VSM), and XRD analysis. The resulting heterogeneous base catalyst allowed the performance of a domino Knoevenagel condensation/Michael addition/cycloaddition reaction toward the synthesis of...
Magnetic nanoparticles entrapped in the cross-linked poly(imidazole/imidazolium) immobilized Cu(ii): An effective heterogeneous copper catalyst
, Article RSC Advances ; Volume 4, Issue 87 , 2014 , Pages 46418-46426 ; ISSN: 20462069 ; Hosseini, S. H ; Zohreh, N ; Bennett, C ; Sharif University of Technology
2014
Abstract
Anchoring of copper sulfate in layered poly(imidazole-imidazolium) coated magnetic nanoparticles provided a highly stable, active, reusable, high loading, and green catalyst for the click synthesis of 1,2,3-triazoles via a one-pot cycloaddition of alkyl halide, azide, and alkyne (Cu-A3C). The catalyst was characterized by FTIR, TGA, TEM, SEM, XRD, EDAX, VSM and AAS. High selectivity, broad diversity of alkyl/benzyl bromide/chloride and alkyl/aryl terminal alkynes, and good to excellent yields of products were obtained using 0.7 mol% catalyst. The catalyst was readily recovered and reused up to 6 times without significant loss of activity
Synthesis & Properties of Nd-doped Glass-ceramics in the SiO2-CaO-MgO System from Sol-gel Method Used as Solid Lasers
,
M.Sc. Thesis
Sharif University of Technology
;
Hamnabard, Zohreh
(Supervisor)
;
Nemati, Ali
(Supervisor)
Abstract
In this study, SiO2-CaO-MgO galsses and glass-ceramic powder doped with Nd3+ were synthesized with sol-gel method. Tetraethylorthosilicate (TEOS), Ca(NO3)2.4H2O, Mg(NO3)2.6H2O, Nd(NO3)3.6H2O, ethanol, distilled water, and HNO3 were used as starting materials. The synthesized powder’s properties were examined with STA, XRD, DRS, PL, FTIR and SEM analysis. From XRD patterns of glass samples, the role of dopant was introduced as intermediate oxide in glass matrix. The XRD patterns of glass-ceramic samples indicated that the bredigite and akermanite crystals were formed in glass matrix. The band gap energy of samples were calculated from DRS analysis and were seen with increasing the dopant...
Corrosion inhibition of mild steel with tolyltriazole
, Article Materials Research ; Volume 24, Issue 4 , 2021 ; 15161439 (ISSN) ; Ghorbani, M ; Mokarami Ghartavol, H ; Sharif University of Technology
Universidade Federal de Sao Carlos
2021
Abstract
Tolyltriazole (TTA) is a well-defined corrosion inhibitor for copper and copper alloys. However, there is little literature about its corrosion inhibition performance for mild steels in corrosive environments. This paper studied the electrochemical behavior of TTA in 0.5 M HCl solutions. Also, the morphology and nature of TTA layers on the steel surface were investigated. Electrochemical results showed that TTA is an excellent corrosion inhibitor for mild steel in acidic media with an efficiency of 91% for 0.07 M concentration. The results also indicated that TTA is a mixed-type inhibitor. XRD analysis revealed that the inhibition mechanism of TTA is based on the formation of an organic film...
Synthesis of multilayered pH-responsive nanocapsules by using tolyltriazole as corrosion inhibitor and ZrO2 nanoparticles as core
, Article Nano-Structures and Nano-Objects ; Volume 26 , 2021 ; 2352507X (ISSN) ; Ghorbani, M ; Mokarami Ghartavol, H ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Smart multilayered pH-sensitive nanocapsules were successfully fabricated using a Layer by Layer (LbL) process. The obtained products were characterized using FESEM, TEM, EDS and elemental mapping, zeta-potential, FTIR, TGA, SIMS and the Tafel polarization techniques. A 55% enhancement in ZrO2 particle size was detected in FESEM and TEM images with a corona view after the LbL process. EDS and elemental mapping analysis and measurements of zeta potential indicated the well-defined layered deposition. FTIR showed the electrostatic bonding between tolyltriazole (TTA) molecules and different overlapping layers. The thermal analysis and SIMS confirmed that 2.7% TTA loaded in nanocapsules. Tafel...
Immobilized copper(II) on nitrogen-rich polymer-entrapped Fe3O4 nanoparticles: A highly loaded and magnetically recoverable catalyst for aqueous click chemistry
, Article Applied Organometallic Chemistry ; Volume 30, Issue 2 , 2016 , Pages 73-80 ; 02682605 (ISSN) ; Hosseini, S. H ; Pour Javadi, A ; Bennett, C ; Sharif University of Technology
John Wiley and Sons Ltd
2016
Abstract
A heterogeneous magnetic copper catalyst was prepared via anchoring of copper sulfate onto multi-layered poly(2-dimethylaminoethyl acrylamide)-coated magnetic nanoparticles and was characterized using various techniques. The catalyst was found to be active, effective and selective for one-pot three-component reaction of alkyl halide, sodium azide and alkyne, known as copper-catalyzed click synthesis of 1,2,3-triazoles. As little as 0.3 mol% of catalyst was found to be effective under the optimum conditions. The catalyst could also be recycled and reused up to seven times without significant loss of activity. Thermal stability, high loading level of copper on catalyst, broad diversity of...
Covalent immobilization of cellulase using magnetic poly(ionic liquid) support: improvement of the enzyme activity and stability
, Article Journal of Agricultural and Food Chemistry ; Volume 66, Issue 4 , 2018 , Pages 789-798 ; 00218561 (ISSN) ; Hosseini, A ; Zohreh, N ; Yaghoubi, M ; Pourjavadi, A ; Sharif University of Technology
American Chemical Society
2018
Abstract
A magnetic nanocomposite was prepared by entrapment of Fe3O4 nanoparticles into the cross-linked ionic liquid/epoxy type polymer. The resulting support was used for covalent immobilization of cellulase through the reaction with epoxy groups. The ionic surface of the support improved the adsorption of enzyme, and a large amount of enzyme (106.1 mg/g) was loaded onto the support surface. The effect of the presence of ionic monomer and covalent binding of enzyme was also investigated. The structure of support was characterized by various instruments such as FT-IR, TGA, VSM, XRD, TEM, SEM, and DLS. The activity and stability of immobilized cellulase were investigated in the prepared support. The...
Rating EFL Learner's Interlanguag Pragmatic Competence by Native and Non-native English Speaking Teachers
, M.Sc. Thesis Sharif University of Technology ; Alemi, Minoo (Supervisor) ; Eslami Rasekh, Zohreh (Co-Advisor)
Abstract
Pragmatic assessment and consistency in rating are among the subject matters which are still in need of more in-depth investigations. The significance of the issue is highlighted when remembering that inconsistency in ratings would surely damage the test fairness issue in assessment and lead to much diversity in ratings. The purpose of this study was investigating the criteria that native (American) and non-native (Iranian) English speaking teachers considered while rating the pragmatic productions of Iranian EFL learners regarding the two speech acts of compliment and compliment response. Overall, a hundred and twenty teachers (sixty native and sixty non-native raters) participated in this...
Immobilized tungstate on magnetic poly(2-ammonium ethyl acrylamide): A high loaded heterogeneous catalyst for selective oxidation of sulfides using H2O2
, Article Journal of Industrial and Engineering Chemistry ; Volume 44 , 2016 , Pages 73-81 ; 1226086X (ISSN) ; Hosseini, S. H ; Pourjavadi, A ; Soleyman, R ; Bennett, C ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2016
Abstract
A heterogeneous tungstate-based catalyst has been prepared for selective oxidation of sulfides to sulfoxides in the presence of 30% H2O2. The catalyst was prepared via immobilization of high amounts of WO4 2− onto the cross-linked poly(ammonium ethyl acrylamide) coated magnetic nanoparticles (MNP). FT-IR, TEM, TGA, VSM, XRD, EDX, and CHN analysis were used for characterization of catalyst. Variety of sulfides successfully converted to the related sulfoxides using 1 mol% of catalyst at room temperature in high yields. The catalyst was easily recovered and reused up to 6 times without loss of activity
Tungstate-loaded triazine-based magnetic poly(Bis-imidazolium ionic liquid): An effective bi-functional catalyst for tandem selective oxidation/Knoevenagel condensation in water
, Article Polymer (United Kingdom) ; Volume 112 , 2017 , Pages 342-350 ; 00323861 (ISSN) ; Tavakolizadeh, M ; Hosseini, S. H ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
A novel bi-functional polymeric catalyst was synthesized by immobilization of tungstate anions onto the nitrogen rich poly(ionic liquid)/magnetic nanocomposite. The resulting catalyst has two types of catalytic sites: (i) immobilized WO4 anions with bis-imidazolium ionic liquid cation for selective oxidation of alcohols and (ii) basic amine groups for Knoevenagel condensation between produced aldehyde and malononitrile. Due to the polymeric nature of the catalyst, large amounts of tungstate and basic nitrogen groups were presented on the solid surface which led to a decrease in the applied catalyst mass for catalytic reaction. High catalytic activity and excellent selectivity of catalyst in...
Comparison of Performance of Trading Transaction Algorithms: Evidence from Tehran Stock Exchange
, M.Sc. Thesis Sharif University of Technology ; Zamani, Shiva (Supervisor) ; Ebrahimnezhad, Ali (Supervisor)
Abstract
One of the issues that has always been paid attention to financial markets is that the use of mathematical relations and formulas for the better estimation of the forecasts made by the process of indicators that are of great importance in financial markets. In financial markets, algorithms have been developed to help reduce the cost of executing transactions from a variety of factors, in order to impose less costs on traders. In these algorithms, a market order and a limited order are used in such a way that the cost of executing transactions can eventually be minimized. Under a limited order, traders determine how much their stake will be at what price they are willing to trade, but in the...
Electromagnetic Devices Based on Virtually Rotating Discontinuities
, Ph.D. Dissertation Sharif University of Technology ; Rejaei Salmasi, Behzad (Supervisor) ; Memarian, Mohammad (Supervisor)
Abstract
Metasurfaces offer unique capabilities for the unconventional scattering and control of electromagnetic waves. By using metasurfaces, one can arbitrarily manipulate the amplitude, phase, and polarization of incident waves, enabling devices such as flat lenses, holograms, and electromagnetic wave beam deflectors. In recent years, time-varying electromagnetic structures, including time-modulated metasurfaces, have provided enhanced possibilities for controlling electromagnetic waves. By modulating the properties of metasurfaces over time, phenomena such as nonreciprocity, frequency shifts, and parametric amplification can be achieved, which traditionally require magnetic materials or nonlinear...