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Magnesium nanopowder for hydrogen absorption and ammonium perchlorate decomposition
, Article Materials Letters ; Volume 85 , 2012 , Pages 128-131 ; 0167577X (ISSN) ; Sadrnezhaad, S. K ; Sharif University of Technology
2012
Abstract
Magnesium nanopowder (MgNP) of 17 nm average size was produced by planetary ball milling of Mg (φ=229 μm) with 10 wt% NaCl (φ=406 μm) for 50 h. NaCl was omissible by dissolution in saturated KOH. Partial oxidation of MgNP occurred, however, in presence of KOH. MgNP-NaCl mixture was, therefore, used for transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), differential scanning calorimetry (DSC) and Sieverts equilibrium investigation. DSC analysis of ammonium perchlorate showed one endothermic and three exothermic reactions. MgNP did not noticeably affect on the initial endothermic reaction. But it decreased transformation temperatures of the...
Breakage mechanism of mg during ball milling with NaCl, KCl and urea for nanopowder Production
, Article Transactions of the Indian Institute of Metals ; 2016 , Pages 1-11 ; 09722815 (ISSN) ; Sadrnezhaad, S. K ; Sharif University of Technology
Springer India
2016
Abstract
In this research, ball milling of magnesium fillings with NaCl, KCl and urea was investigated as a simple way to produce Mg nanoparticles. Effects of feed geometry and milling time on crush mechanism and product size were determined. Optical, scanning and transmission electron microscopes were used to study the morphology of the products. Spherical charge particles were milled under argon atmosphere with 10 wt% cuboidal NaCl at 250 rpm for 50 h. With ball to powder ratio of 10:1, the average diameter of the product was 17 nm. Addition of NaCl changed the breakage mechanism from ductile–ductile to ductile–brittle, reduced particle size, stopped agglomeration and prevented the undesirable...
Breakage mechanism of mg during ball milling with NaCl, KCl and urea for nanopowder production
, Article Transactions of the Indian Institute of Metals ; Volume 70, Issue 7 , 2017 , Pages 1783-1793 ; 09722815 (ISSN) ; Sadrnezhaad, S. K ; Sharif University of Technology
2017
Abstract
In this research, ball milling of magnesium fillings with NaCl, KCl and urea was investigated as a simple way to produce Mg nanoparticles. Effects of feed geometry and milling time on crush mechanism and product size were determined. Optical, scanning and transmission electron microscopes were used to study the morphology of the products. Spherical charge particles were milled under argon atmosphere with 10 wt% cuboidal NaCl at 250 rpm for 50 h. With ball to powder ratio of 10:1, the average diameter of the product was 17 nm. Addition of NaCl changed the breakage mechanism from ductile–ductile to ductile–brittle, reduced particle size, stopped agglomeration and prevented the undesirable...
Synthesis of Magnesium Nanoparticles with Ball Mill
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhaad, Khatiboleslam (Supervisor)
Abstract
In recent years magnesium nanoparticles due to their noticeable differences from bulk and their wide applications in various branches including the ability to absorb hydrogen, application in batteries, activation of propellant, different applications in biochemistry and strengthening secondary phase in composites, are well under investigation. The objective of this study is to find an easy, economical and high purity method to obtain magnesium nanoparticles and to introduce an innovative approach of magnesium nanoparticles synthesis in an industrial scale. To achieve this goal, milling process is applied. Micron-sized magnesium powders with different amounts of sodium chloride salt powders...
Corrosion behavior of aluminum 6061 alloy joined by friction stir welding and gas tungsten arc welding methods
, Article Materials and Design ; Volume 39 , 2012 , Pages 329-333 ; 02641275 (ISSN) ; Sadrnezhaad, S. K ; Karimzadeh, F ; Sharif University of Technology
2012
Abstract
Wrought aluminum sheets with thickness of 13. mm were square butt-welded by friction stir welding (FSW) and gas tungsten arc welding (GTAW) methods. Corrosion behavior of the welding zone was probed by Tafel polarization curve. Optical metallography (OM) and scanning electron microscopy together with energy dispersive spectroscopy (SEM-EDS) were used to determine morphology and semi-quantitative analysis of the welded zone. FSW resulted in equiaxed grains of about 1-2 μm, while GTAW caused dendritic structure of the welded region. Resistance to corrosion was greater for the FSW grains than the GTAW structure. In both cases, susceptibility to corrosion attack was greater in the welded region...
Microstructure and mechanical property change during FSW and GTAW of Al6061 alloy
, Article Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science ; Volume 44, Issue 5 , 2013 , Pages 2187-2195 ; 10735623 (ISSN) ; Sadrnezhaad, S. K ; Karimzadeh, F ; Sharif University of Technology
2013
Abstract
The variation of morphology and mechanical properties of Al6061 automotive aluminum alloy due to friction stir welding (FSW) and gas tungsten arc welding (GTAW) was investigated by optical metallography, scanning electron microscopy, microhardness measurement, X-ray diffraction, tensile testing, and fractography. The center-line dendrite emergence and microhardness reduction in the heat-affected zone were observed in the GTAW process. Although similar microhardness reduction with respect to the base metal was observed in the FSW samples, higher HVs were obtained for the FSW rather than the GTAW process at almost all heat-affected locations. Ultimate tensile strengths of the FSW and the GTAW...
Morphology of nanodroplets on structured surfaces
, Article Journal of Physics D: Applied Physics ; Volume 46, Issue 21 , May , 2013 ; 00223727 (ISSN) ; Moosavi, A ; Sharif University of Technology
2013
Abstract
We report different morphologies of nanodroplets over various topographical features of the supporting substrates. The effects of different parameters such as the profile of the disjoining pressure, droplet size and the geometrical parameters are studied and discussed. Also, the effects of a coating layer on the surface of the substrate are determined. It is demonstrated that the nanodroplets at some positions are not stable and gradually move to more stable positions so that the system has less energy. For grooves this results in a series of morphology diagrams of the nanodroplets over the grooves as a function of the grooves' width and the liquid volume
Study of the P-^ Effects on the Behavior of Split-Level Steel Structures
, M.Sc. Thesis Sharif University of Technology ; Khansari, Vahid (Supervisor)
Abstract
Due to unusual response of structures of buildings with irregularity in their architecture to dynamic excitations, to have a comprehensive knowledge of their behavior during earthquakes is of utmost importance. Building irregularities are in general divided into two major categories, namely Irregularity in Plane and Irregularity in Elevation, and one of the forms of the latter is where there is a split in the levels of the building. In this work, through a series of case studies, the effects of P- phenomenon on the behavior of steel split-level building structures were studied. 5, 10 and 15 story buildings with 5 and 6 bays, and level splitting of 30, 60, 90, 120 and 150 cm were studied. All...
Three Dimensional Simulation of Morphology of Nanodroplets Near and on Structured Substrates
, M.Sc. Thesis Sharif University of Technology ; Moosavi, Ali (Supervisor)
Abstract
Mesoscopic hydrodynamic equations are solved employing a VOF based method to investigate the equilibrium shape of nanodroplets positioned over various topographic geometries of the supporting substrate for three-dimensional systems. By taking into account liquid-liquid and liquid-solid interactions a complex distribution for inter-molecular forces over the substrates (the disjoining pressure) is observed. In this research we show that motion of nanodroplets not only caused by contact angle difference in drplets two sides, but also depend on disjoining pressure parameters.Geometries with increasing complexities, from wedges to three dimensional edges and wedges, were explored with the main...
Investigating the Seismic Behaviour of Split-Level Building Structures
, M.Sc. Thesis Sharif University of Technology ; Khonsari, Vahid (Supervisor)
Abstract
Observations made after previous earthquakes have shown the crucial role of irregularities in initiating damage in buildings with irregularity, either in Plan or in Elevation. Since in existing Building Codes, there is no provision for the distribution of the Equivalent Static Loads for such buildings, designers have no option but to resort to Dynamic Analysis. In this work, the seismic behaviour of a group of two-dimensional steel building structures with irregularity in elevation, namely Split-Level buildings, was studied. The studied structures consist of a series of 5- and 15-storey frames having two parts with splitting distance of 150 cm. Both, moment-resisting and braced frames were...
Use of Life Cycle Analysis to Compare Various Vehicle Technologies on Energy Consumption and External Cost for Semi-Public Applications: Case Study, City of Tehran
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
With the road transportation vehicles being widely used, concerns have been increased regarding their unwanted effects. Air pollution, climate change, and oil supply security are among these effects. Many alternative fuels and propulsion systems have been proposed to be used instead of conventional ICE vehicles in recent decades. This project intends to conduct a Techno-Economic comparison between different vehicle powertrains so as to select the suitable choice to substitute conventional ICE vehicles. The vehicle options are ICE vehicles using both gasoline and CNG as fuels, Hybrid Electric Vehicles (HEVs), Plug-in Hybrid Electric Vehicles (PHEVs), and Electric Vehicles (EVs). The amount of...
Numerical Study of Base Plates under Biaxial Bending
, M.Sc. Thesis Sharif University of Technology ; Khonsari, Vahid (Supervisor)
Abstract
Base plates as the connecting components of steel structures to their foundations, have a crucial role in the behavior of these structures. In order to limit the thickness of base plates hence their cost within reasonable values, various types of attachments (stiffeners) are normally added to them. In this project 6 different configurations, Models, for the base plate and its attachments were considered and studied through finite element analysis. Each Model was studied under the combination of biaxial moments and a range of compressive loads including 0, 0.05 P/Py, 0.10 P/Py and 0.15 P/Py, where Py is the plastic load of the column. The moment-rotation curves of all models under various...
Factorial Design of Experiments to Identify Effective Factors on Domestic Vehicle Emissions and Fuel Consumption
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
Reducing air pollutant emissions from vehicles is a difficult and time consuming procedure which needs utilizing of modern emission control equipment and setting strict regulations for car factories and drivers as well. How efficient these policies are and proposing operative solutions for air quality improvement depend on developing a sustainable model which is used in vehicle emission predictions and their share in total emissions. Emission factors are not constant values as they can be affected by various operational and ambient parameters. Development of Emission inventories calls for a huge number of measurements using different vehicles in diverse conditions. Thus, recognition of...
Micro-modeling of Tehran 4-stroke Gasoline Motorcycle Fleet Emission and Investigating the Effects of Increasing Fueling System and Engine Technology Level
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
The city of Tehran is dealing with air pollution problems for years. Providing a solution for this problem requires information about different pollutants emission sources. In this subjects, emission factors and emission models are essential tools for decision makers. Among different mobile emission sources in Tehran, motorcycles are of high importance. In this project, for the first time in Iran, exhaust gas pollutants emission of 66 motorcycles with different ages and engine displacement volumes were measured according to Euro-3 standard certification procedure. Measurement results showed that none of the tested motorcycles passed the Euro-3 certification limit on CO emission. Calculations...
Partially Homogenous HCCI Combustion Chemical Kinetics Model Initial Conditions Development by CFD Modeling
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
Homogeneous Charge Compression Ignition (HCCI) engines are the new generation of internal combustion engines which have diesel-like thermal efficiency, while they have low nitrogen oxide and soot emission. One of the major problems of HCCI engines is combustion timing control due to its dependence on reactivity of the charge and chemical kinetics. Moreover, limiting operation range between knock and misfiring is the other drawback of using these kind of engines. In the present work, partially homogeneous HCCI combustion in a single cylinder diesel engine is modeled using Computational Fluid Dynamics (CFD) coupled with chemical kinetics. Simulation includes the engine cycle from exhaust valve...
Traffic Source Particle Pollution Distribution Using Micro-scale Simulation
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
Today air pollution has become one of the major urban management concerns. Air pollution could have dangerous effects on human health in short time or long time in many situations. Numerical modelling is one of the most applicable among different ways for predicting pollutant concentration like field measurement, physical model in wind tunnel, and simulation. Modelling of pollutant dispersion is a way for estimating concentration and aggregation of the pollutant near the surface and with different distances from pollution source. In different dispersion models, one of simplest is the Gaussian model. In this approach it is supposed that emission plume obeys from Gaussian distribution and is...
Numerical Modeling of the Behavior of Base Plates with Various Degrees of Rigidity Under Cyclic Loads
, M.Sc. Thesis Sharif University of Technology ; Khonsari, Vahid (Co-Advisor)
Abstract
Due to the important role of base plates, both in transferring forces from the structure to the foundation, and also in transferring vibrations from soil to the structure, it is necessary to have sufficient knowledge on their behaviour and performance under monotonic and cyclic loading regimes. In fact, the behaviour of the supports of any structure cannot be identified without identifying the behaviour of its base plates. Numerous configurations with/without various types of attachments have been proposed and used for base plates. In this work, altogether six commonly-used types of base plates were studied and their behaviour under monotonic and cyclic loadings was obtained using commercial...
Studying the Behaviour of Split-Level Structures with Semi-Rigid Connections
, M.Sc. Thesis Sharif University of Technology ; Khonsari, Vahid (Supervisor)
Abstract
Past earthquakes show that irregular structures have been more vulnerable than their regular counterparts. One of the common types of irregular buildings in urban areas is split-level ones. On the other hand, beam-to-column connections in steel structures are mostly of "semi-rigid" type. In this work, effects of different levels of rigidity of connections, 100%, 75%, 50% and 25%, on the behavior of a number of two-dimensional split-level steel structures, with 1.5 m difference in levels of floors, 2, 3, 5 and 6 bays, and 5, 10 and 15 stories, were studied. All frames were analyzed “with” and “without” considering the P-∆ phenomenon, with two methods, ‘equivalent static load,’ and ‘modal...
Homogeneous Charge Compression Ignition (HCCI) Combustion Simulation using a Multi-Zone Chemical kinetics Model
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
In recent years, the idea of Homogenous charge compression ignition (HCCI) engines has been in the center of attention as a new generation of internal combustion engines. Intense decrease in pollutant emission rate like NOx, low fuel consumption and high thermal efficiency are the main reasons of why these engines are in center of attention, however, some drawbacks, which the main one combustion control which happens in limited operation range between knock and misfiring has limited the use of these engines. Hence approaches like adding synthesis gas, using exhaust gas recirculation, controling effective comperession ratio by using variable valve timing, changing the input conditions...
Development and Application of Mobile Source Emission Factor Matrix for Use in Wrf/Camx Air Dispersion Model of Tehran
, M.Sc. Thesis Sharif University of Technology ; Hosseini, Vahid (Supervisor)
Abstract
Tehran, with approximately 750 km2 of land area, a population of more than 8 million people with about 4 million active on-road vehicles, is dealing with serious air pollution problems. To model the environmental phenomenon precisely, this study aims to develop on-road air pollutant emission factor matrices based on existing traffic in Tehran routes and to run air quality modelling within Tehran geographic boundaries. We developed emission factor matrices using SMOKES-MOVES emission modeling system. To do so, we calculated on-road emission factors from actual traffic-related data and run MOVES emission model. And use use them for different pollutants considered in air quality models. Then,...