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    Investigation of Performance and Improvement of the Activity of MOF-based Catalysts in CO Oxidation Reaction

    , Ph.D. Dissertation Sharif University of Technology Abbasi, Fatemeh (Author) ; Ghotbi, Cyrus (Supervisor) ; Karimi Sabet, Javad (Supervisor)
    Abstract
    Different catalysts have been proposed for CO oxidation reaction and still many researches are performed to obtain a catalyst with high activity and stability. In this study, MOFs of CuBTC, MIL-101(Cr), and NH2-MIL-101(Cr) and active metal of Pd have been selected and their performances have been investigated in CO oxidation reaction. MOFs have been synthesized by hydrothermal method. Pd loading has been performed by impregnation method in various pH and in aqeous palladium nitrate solution and palladium nitrate solution in nitric acid. To reveal the effect of the nature of noble metal, activity of 1% Pt/MIL has been investigated. Amine-functionalized MIL-101(Cr) has been synthesized by... 

    Synthesis of Graphene Oxide and Graphene Oxide Membrane for Separation of Gas Mixtures

    , M.Sc. Thesis Sharif University of Technology Abbasi, Fateme (Author) ; Ghotbi, Sirus (Supervisor) ; Karimi Sabet, Javad (Supervisor) ; Mousavi, Abbas (Co-Advisor)
    Abstract
    Thin film graphene oxide(GO) membranes have been promising potential for gas purification due to thin lamellar microstructure, stable a few atom thick layers and very short intersheet distances. In this research, the nanoporous graphene oxide membranes have been prepared by vacuum and pressurized ultrafiltration on the modified polyacrylonitryle(mPAN) sublayer for helium separation from Nitrogen and carbon dioxide gas mixture. The separation performance of synthesized GO membrane was controlled by varying parameters such as concentration of stabilized aqueous GO solution, pores size range of support and its surface properties, centrifuge time, applied pressure after synthesis, humidity,... 

    Numerical investigation of effects of uniform magnetic field on heat transfer around a sphere

    , Article International Journal of Heat and Mass Transfer ; Volume 114 , 2017 , Pages 703-714 ; 00179310 (ISSN) Abbasi, Z ; Molaei Dehkordi, A ; Abbasi, F ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    In this article, ferrohydrodynamic forced-convection heat transfer from a heated sphere embedded in a ferrofluid in the presence of the uniform external magnetic field has been studied numerically for the first time over a wide range of Reynolds number value, nanoparticle diameter, particle volume fraction, and magnetic field intensity. Despite the uniform external magnetic field applied, the internal magnetic field near the sphere could be nonuniform due to the considerable difference between the relative magnetic permeability of the sphere and the surrounding medium. Kelvin body force arises from this nonuniformity and induces vortexes near the sphere. These vortexes disturb the boundary... 

    A fuzzy random minimum cost network flow programming problem [electronic resource]

    , Article Journal of Industrial and Systems Engineering (JISE)-Iranian Institute of Industrial Engineering ; Article 3, Volume 6, Issue 1, Spring 2012, Page 34-47 Nematian, J. (Javad) ; Eshghi, Kourosh ; Sharif University of Technology
    Abstract
    In this paper, a fuzzy random minimum cost flow problem is presented. In this problem, cost parameters and decision variables are fuzzy random variables and fuzzy numbers respectively. The object of the problem is to find optimal flows of a capacitated network. Then, two algorithms are developed to solve the problem based on Er-expected value of fuzzy random variables and chance-constrained programming. Furthermore, the results of two algorithms will be compared. An illustrative example is also provided to clarify the concept  

    Special classes of mathematical programming models with fuzzy random variables [electronic resource]

    , Article Journal of Intelligent and Fuzzy Systems, Published In: IOS Press ; Volume 19, Number 2, 2008 Eshghi, K. (Kourosh) ; Nematian, Javad ; Sharif University of Technology
    Abstract
    In this paper, we will discuss two special classes of mathematical programming models with fuzzy random variables. In the first model, a linear programming problem with fuzzy decision variables and fuzzy random coefficients is introduced. Then an algorithm is developed to solve the model based on fuzzy optimization method and fuzzy ranking method. In the second model, a fuzzy random quadratic spanning tree problem is presented. Then the proposed problem is formulated and solved by using the scalar expected value of fuzzy random variables. Furthermore, illustrative numerical examples are also given to clarify the methods discussed in this paper  

    A special class of fuzzy integer programming model with all different constraints [electronic resource]

    , Article Scientia Iranica ; Vol. 16, No. 1, pp. 1-10, 2009 Eshghi, K. (Kourosh) ; Nematian, Javad ; Sharif University Of Technology
    Abstract
    In this paper, a fuzzy approach is applied to special classes of integer programming problems with all diierent constraints. In the rst model, a fuzzy integer programming model is developed to represent the all-diierent constraints in mathematical programming. In order to solve the proposed model, a new branching scheme for the Branch and Bound algorithm is also presented. In the second model, a special class of large-scale multi-objective fuzzy integer programming problems with all-diierent constraints is introduced. A solution method for the proposed model is also developed by using the decomposition technique, weighting method and Branch and Bound algorithm. An illustrative numerical... 

    Fuzzy random minimum cost network problem [electronic resource]

    , Article Journal of Industrial and Systems Engineering ; Vol. 6, No. 1, pp 34-47, 2012 Nematian, J. (Javad) ; Eshghi, Kourosh ; Sharif University of Technology
    Abstract
    In this paper, a fuzzy random minimum cost flow problem is presented. In this problem, cost parameters and decision variables are fuzzy random variables and fuzzy numbers respectively. The object of the problem is to find optimal flows of a capacitated network. Then, two algorithms are developed to solve the problem based on Er-expected value of fuzzy random variables and chance-constrained programming. Furthermore, the results of two algorithms will be compared. An illustrative example is also provided to clarify the concept  

    A method for simulation of vapour cloud explosions based on computational fluid dynamics (CFD)

    , Article Journal of Loss Prevention in the Process Industries ; Volume 24, Issue 5 , 2011 , Pages 638-647 ; 09504230 (ISSN) Tauseef, S. M ; Rashtchian, D ; Abbasi, T ; Abbasi, S.A ; Sharif University of Technology
    2011
    Abstract
    The effectiveness of the application of CFD to vapour cloud explosion (VCE) modelling depends on the accuracy with which geometrical details of the obstacles likely to be encountered by the vapour cloud are represented and the correctness with which turbulence is predicted. This is because the severity of a VCE strongly depends on the types of obstacles encountered by the cloud undergoing combustion; the turbulence generated by the obstacles influences flame speed and feeds the process of explosion through enhanced mixing of fuel and oxidant. In this paper a CFD-based method is proposed on the basis of the author's finding that among the various models available for assessing turbulence, the... 

    Thin film graphene oxide membrane: challenges and gas separation potential

    , Article Korean Journal of Chemical Engineering ; Volume 35, Issue 5 , May , 2018 , Pages 1174-1184 ; 02561115 (ISSN) Abbasi, F ; Karimi Sabet, J ; Ghotbi, C ; Abbasi, Z ; Sharif University of Technology
    Springer New York LLC  2018
    Abstract
    Graphene oxide membranes were prepared by vacuum and pressurized ultrafiltration methods on the 12% modified Polyacrylonitrile (12mPAN) substrate to specify challenges, salient features, future directions, and potential of GO membrane for separation fields using characterization techniques and gas separation test (studied gases are CO2, He and N2), which is an efficient tool for better understanding of GO membrane behavior. GO membrane structure was examined over a wide range of parameters, such as pore size range of substrate and its surface properties, pH of GO dispersion, GO content, synthesis pressure, operating pressure and temperature. The results show that the GO content does not hold... 

    Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework

    , Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) Abbasi, F ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
    Higher Education Press Limited Company  2021
    Abstract
    The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution... 

    Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework

    , Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) Abbasi, F ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
    Higher Education Press Limited Company  2021
    Abstract
    The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution... 

    Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework

    , Article Frontiers of Chemical Science and Engineering ; Volume 16, Issue 7 , 2022 , Pages 1139-1148 ; 20950179 (ISSN) Abbasi, F ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
    Higher Education Press Limited Company  2022
    Abstract
    The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution... 

    Improved method for increasing accessible pores of MIL-101(Cr) by encapsulation and removal of Phosphotungstic acid (PTA): Pd/PTA-MIL-101(Cr) as an effective catalyst for CO oxidation

    , Article Journal of Cleaner Production ; Volume 347 , 2022 ; 09596526 (ISSN) Abbasi, F ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    This study forwards a novel and simple approach for encapsulation of Phosphotungstic acid (PTA) into MIL-101(Cr) cavities to develop PTA-MIL-101(Cr) with a high surface area. In this method, the resulting surface area of PTA-MIL-101(Cr) (3563 m2/g) is 1.72 times that of MIL-101(Cr) due to the existence of more accessible pores which are formed by leaching of PTAs incorporated inside MIL-101(Cr) pores during the intense washing. Catalysts are investigated in CO oxidation under atmospheric pressure and feed composition of 1%CO, 20%O2, and 79%He. 3%Pd/PTA-MIL-101(Cr) shows 100%CO conversion at T = 145 °C and outperforms PTA, PTA-MIL-101(Cr), Pd/PTA, 1–3%Pd/MIL-101(Cr), Pd-PTA/MIL-101(Cr), and... 

    Investigation into the effects of weld zone and geometric discontinuity on the formability reduction of tailor welded blanks

    , Article Computational Materials Science ; Volume 59 , 2012 , Pages 158-164 ; 09270256 (ISSN) Abbasi, M ; Ketabchi, M ; Ramazani, A ; Abbasi, M ; Prahl, U ; Sharif University of Technology
    2012
    Abstract
    Numerous advantages of application of tailor welded blanks (TWBs) in automobile industry, namely reduction of weight, fuel consumption and air pollution, have made the manufacturers eager to investigate in this field. On the other hand, while experiments generally provide valuable information in regard with mechanical behaviors, but utilization of simulation methods has extended vastly due to time and cost saving issues. One challenging issue in numerically analyzing the forming behavior of transversely welded TWBs, welded by laser welding methods, has been the presence of weld zone. While some researchers believe that during simulation, the weld zone can be neglected due to its minority and... 

    A neural network applied to estimate process capability of non-normal processes

    , Article Expert Systems with Applications ; Volume 36, Issue 2 PART 2 , 2009 , Pages 3093-3100 ; 09574174 (ISSN) Abbasi, B ; Sharif University of Technology
    2009
    Abstract
    It is always crucial to estimate process capability index (PCI) when the quality characteristic does not follow normal distribution, however skewed distributions come about in many processes. The classical method to estimate process capability is not applicable for non-normal processes. In the existing methods for non-normal processes, probability density function (pdf) of the process or an estimate of it is required. Estimating pdf of the process is a hard work and resulted PCI by estimated pdf may be far from real value of it. In this paper an artificial neural network is proposed to estimate PCI for right skewed distributions without appeal to pdf of the process. The proposed neural... 

    Application of the GTN model to predict the forming limit diagram of IF-Steel

    , Article Journal of Mechanical Science and Technology ; Volume 26, Issue 2 , February , 2012 , Pages 345-352 ; 1738494X (ISSN) Abbasi, M ; Shafaat, M. A ; Ketabchi, M ; Haghshenas, D. F ; Abbasi, M ; Sharif University of Technology
    2012
    Abstract
    Forming limit diagrams (FLDs) are extensively used in industries, particularly the auto industry. The establishment of these diagrams using a predictive approach can lead to reduction in both cost and time. In the present work, Gurson-Tvergaard-Needleman (GTN), a porosity-based model, was used to predict the FLD of an interstitial-free steel via finite element simulation. Optimum values of the GTN model were obtained by applying a response surface methodology (RSM) based on central composite design. Results show that RSM is a good method for an appropriate determination of the GTN model parameters, such as initial void volume fraction, effective void volume fraction, critical void volume... 

    Production of Uranium Dioxide Nano Powder With Hydrothermal Method in Supercritical Water Reactor

    , M.Sc. Thesis Sharif University of Technology Golzary, Abooali (Author) ; Outokesh, Mohammad (Supervisor) ; Ahmadi, Javad (Supervisor) ; Karimi Sabet, Javad (Co-Advisor)
    Abstract
    Hydrothermal supercritical method is one of the most suitable methods for metal oxide nano powder, ceramics and mineral catalyst synthesis. Metal oxides nanopowder in its pure or mixed form has wide potential application as chemical industrial catalyst, hot Superconductors, magnetic material, gas sensors and car catalyst convertors. One of the most important metal oxides aspects of application is uranium oxide as nuclear reactor fuel is used. In addition, UO2 is selective catalyst for converting methane to methanol process and Decomposition of organic Chlorine material. In Supercritical hydrothermal method done in high pressure reactor with critical to fluid, is new method for the... 

    Experimental Study of Pendulum Grinding of Superalloys

    , M.Sc. Thesis Sharif University of Technology Yazdani, Majid (Author) ; Akbari, Javad (Supervisor)
    Abstract
    Superalloys are widely used in aerospace and power industries due to the good performance at high temperatures for examples gas turbines, steam turbines and aircraft components. In addition to the turbines cobalt-base superalloys are used in medical implants such as knee and hip joints. The main strengths of the superalloys are heat-resistant, retaining their high mechanical and chemical properties at high temperatures, high melting temperatures, high corrosion resistance, resistance to thermal fatigue, thermal shock, creep, and erosion. Because of difficult to machine properties of superalloys, grinding is one of the effective methods for machining superalloys. The surface integrity of the... 

    Ultrasonic Assisted Deep Drilling of Super-Alloy and Comparison With Electro Discharge Drilling Method

    , M.Sc. Thesis Sharif University of Technology Baghlani, Valid (Author) ; Akbari, Javad (Supervisor)
    Abstract
    Drilling super alloys with a good hole quality and acceptable surface finish is a constant challenge in modern industries dealing with such materials. Ultrasonic assisted drilling is a modern and nonconventional method of drilling which has attracted many researchers attention recently. In this study deep drilling on Inconel 738 LC is done using ultrasonic assisted drilling technique and the results are compared with those of Electro Discharge Machininng or EDM method. The results show that Ultrasonic Assisted Drilling or UAD is an appropriate alternative for EDM of Inconel. The whole process time is decrease dimensional accuracy is improved and surface roughness is decreased significantly.... 

    Security Evaluation of Public Key Based Key Management in MANET

    , M.Sc. Thesis Sharif University of Technology Jamshidi, Farzad (Author) ; Mohajeri, Javad (Supervisor)
    Abstract
    Due to popularity of mobile wireless devices, security of mobile ad hoc networks (MANETs) being more important than before. Traditional key management schemes based on symmetric key cryptography are became ineffective because of dynamic and infrastructureless nature of these networks.Recent studies are mainly based on traditional public key cryptography schemes and ID-based cryptography schemes. On the other hand, Contributory schemes seem suitable for MANETs because of their inherent self-organize property. Key update and Key revocation are the fundamental issues of key management schemes in mobile ad hoc networks. Certificateless public key cryptography, in addition to solve those issues,...